公开(公告)号：DE59309231D1

公开(公告)日：1999-02-04

申请号：DE59309231

申请日：1993-05-07

Applicant: BASF AG

Inventor： FISCHER WOLFGANG DR ,  GUENTHERBERG NORBERT DR ,  NIESSNER NORBERT DR ,  RUPPMICH KARL ,  SEITZ FRIEDRICH DR

IPC: C08F265/04 ,  C08F279/02 ,  C08L25/12 ,  C08L51/00 ,  C08L51/06 ,  C08L55/02

公开(公告)号：DE59502211D1

公开(公告)日：1998-06-25

申请号：DE59502211

申请日：1995-03-21

Applicant: BASF AG

Inventor： NIESSNER NORBERT DR ,  GUENTHERBERG NORBERT DR ,  FISCHER WOLFGANG DR ,  ROSENAU BERNHARD DR

IPC: C08J5/00 ,  C08F265/04 ,  C08J5/18 ,  C08L23/00 ,  C08L23/02 ,  C08L23/08 ,  C08L25/00 ,  C08L25/04 ,  C08L25/12 ,  C08L51/00

Abstract: New thermoplastic moulding material contains the following components: (A) 20-99 wt.,% at least one graft copolymer comprising 30-90 wt.% core (a1) prepd. by polymerisation of a mixt. of 80-99.9 wt.% at least one acrylic acid 1-10C alkyl ester (a11), 20 - 0.01 wt.% copolymerisable, polyfunctional, cross-linking monomer (a12) and 0 - 40 wt.% additional copolymerisable, monoethylenic unsatd. monomer (a13), with 70 - 10 wt.% graft component (a2) prepd. by polymerisation in the presence of (a1) of a monomer mixt. comprising 50 - 100 wt.% styrene cpd. of formula (I) and/or (meth)acrylic acid 1-8C alkyl ester (a21) and 50 - 0 wt.% monofunctional comonomer (a22); (B) 80 - 1 wt.% copolymer prepd. from at least one alpha-olefin and at least one polar comonomer, except vinyl acetate or vinyl aromatic monomers; and (C) 0 - 50 wt.% thermoplastic polymer prepd. by the polymerisation of 50 - 100 wt.% vinyl aromatic monomer and/or (meth)acrylic acid 1-8C alkyl ester (c1) and 50 - 0 wt.% monofunctional comonomer (c2), all wrt. sum of (A), (B) and (C); R1, R2 = H or 1-8C alkyl. Also claimed are (i) prepn. of the moulding material by mixing (A), (B) and (C), (ii) use of the material for the prepn. of moulded articles or films, (iii) films or moulded articles prepd. from the material, and (iv) films with a leather-like appearance.

公开(公告)号：DE59501796D1

公开(公告)日：1998-05-14

申请号：DE59501796

申请日：1995-01-19

Applicant: BASF AG

Inventor： GUENTHERBERG NORBERT DR ,  HOFMANN JUERGEN ,  OHLIG HILMAR ,  MAILAHN ELMAR ,  SEITZ FRIEDRICH DR ,  GAUSEPOHL HERMANN DR ,  KOCH JUERGEN DR ,  DECKERS ANDREAS DR

IPC: B29B7/20 ,  B29B7/26 ,  B29B7/46 ,  B29B13/06 ,  B29C47/78 ,  B29C48/76 ,  B29K21/00 ,  B29C47/76

公开(公告)号：DE19638255A1

公开(公告)日：1998-03-26

申请号：DE19638255

申请日：1996-09-19

Applicant: BASF AG

Inventor： GUENTHERBERG NORBERT DR ,  KNOLL KONRAD DR ,  WEBER MARTIN DR ,  LINDENSCHMIDT GERHARD DR

IPC: C08F297/04 ,  C08L25/12 ,  C08L51/00 ,  C08L53/02 ,  C08J5/18 ,  C08L51/06 ,  C08L25/06 ,  C08L33/20 ,  C08L33/08 ,  C08K5/05 ,  C08K5/56 ,  C08L9/06 ,  C08J5/00 ,  C08G81/00

Abstract: Thermoplastic moulding compounds contain: (A) 30 to 98 wt % of a graft polymer which consists of (ak) 30 to 90 wt % of a cross-linked acrylic rubber graft nucleus; (as) 10 to 70 wt % of a graft shell made of (as/1) 50 to 100 wt % of a styrene compound, of an acrylic or methacrylic acid (C1-C8-alkyl)ester, or of a mixture of the styrene compound and the acrylic or methacrylic acid (C1-C8-alkyl)ester; and (as/2) 0 to 50 wt % of one or several other monomers; (B) 1 to 50 wt % of a thermoplastic polymer; and (C) 1 to 70 wt % of a rubber elastic block copolymer.

公开(公告)号：DE19635078A1

公开(公告)日：1998-03-05

申请号：DE19635078

申请日：1996-08-30

Applicant: BASF AG

Inventor： WEBER MARTIN DR ,  GUENTHERBERG NORBERT DR

IPC: C08K5/521 ,  C08K13/08 ,  C08L51/00 ,  C08L69/00 ,  D01F6/92 ,  C08J5/18 ,  C08L51/04 ,  C08L25/12 ,  C08L83/04 ,  C08L33/04 ,  C08J5/00

Abstract: The invention concerns moulding compounds comprising as essential components an aromatic polycarbonate, a graft polymer based on alkylacrylates, styrenes and unsaturated nitriles, a copolymer based on styrenes and unsaturated nitriles, a siloxane reticular rubber, a copolymer comprising at least two different esters of acrylic acid, methacrylic acid or mixtures thereof, optionally halogen-free phosphorus compounds and additives. The invention further concerns moulded bodies, foils or fibres produced from these moulding compounds.

公开(公告)号：DE19547975A1

公开(公告)日：1997-06-26

申请号：DE19547975

申请日：1995-12-21

Applicant: BASF AG

Inventor： GUENTHERBERG NORBERT DR ,  HOFMANN JUERGEN ,  MAILAHN ELMAR ,  OHLIG HILMAR

IPC: B29C48/76 ,  C08L55/02 ,  B29B7/84 ,  B29B7/48

Abstract: Prepn. of deep draw-modified thermoplastics (T) by mechanical dewatering of a wet elastomer component (A) contg. up to 50 wt.% residual water and mixing dewatered (A) with a thermoplastic polymer (B) in a screw - by adding (A) to a twin-screw extruder with 3-way rotating screws. This extruder contains the following sections (in the direction of flow): (1) feed for adding (A) to the extruder; (2) at least one crusher for dewatering (A) that contains one or more barriers each with an opening through which at least some of the water passes as a liq.; (3) at least one section to which molten (B) is added; (4) one or more sections with mixing, kneading and/or plasticising devices; (5) at least one degassing section with one or more gas outlets through which water is removed as steam; and (6) an exit zone. Also claimed are deep draw-modified moulding materials prepd. by this process.

公开(公告)号：DE59306113D1

公开(公告)日：1997-05-15

申请号：DE59306113

申请日：1993-12-08

Applicant: BASF AG

Inventor： FISCHER WOLFGANG DR ,  GUENTHERBERG NORBERT DR

IPC: C08F2/22 ,  C08F265/04 ,  C08F279/02 ,  C08F291/08 ,  C08L25/12 ,  C08L51/00 ,  C08L51/04 ,  C08L55/02 ,  C08L69/00 ,  C08L71/12 ,  C08L101/00

Abstract: Particulate graft polymer composed of 30 to 90% by weight of at least one elastomeric grafting base A having a weight average particle size from 30 to 1000 nm, based on A, 85 to 99.8% by weight of at least one alkyl acrylate A11 having 1-8 carbon atoms in the alkyl radical, 0.1 to 5% by weight of at least one polyfunctional, crosslinking monomer A12 and 0.1 to 10% by weight of at least one hydroxyalkyl acrylate or methacrylate A13 or at least 50% by weight of one or more dienes A111, up to 50% by weight of one or more ethylenically unsaturated monomers A112 and 0.1 to 10% by weight of at least one hydroxyalkyl acrylate or methacrylate A113 and 10 to 70% by weight of a graft sheath B composed of, based on B, up to 99.9% by weight of at least one vinylaromatic monomer B1, up to 99.9% by weight of at least one polar, copolymerisable, ethylenically unsaturated monomer B2 and 0.1 to 20% by weight of at least one monomer B3 containing one or more basic or acid groups.

公开(公告)号：DE19527579A1

公开(公告)日：1997-01-30

申请号：DE19527579

申请日：1995-07-28

Applicant: BASF AG

Inventor： TIEFENSEE KRISTIN DR ,  GUENTHERBERG NORBERT DR

IPC: C08J3/20 ,  C08F285/00 ,  C08L25/06 ,  C08L25/12 ,  C08L33/12 ,  C08L51/00 ,  C08L51/04

Abstract: Thermoplastic moulding compounds containing a mixture of (A) a methacrylate polymer; (B) a copolymer of vinyl aromatic monomers and vinyl cyanide; (C) a graft copolymer of a core and a graft shell; and (D) a further graft copolymer of a core and a graft shell; in which the mean particle size (d50)-C of the graft copolymer (C) is 25 to 60 nm and that of the graft copolymer (D) is up to 300 nm and in which the ratio of the mean particule size (d50)-C to (d50)-D is kept within the range from 2:1 to 5:1.

公开(公告)号：ES2091543T3

公开(公告)日：1996-11-01

申请号：ES93120270

申请日：1993-12-16

Applicant: BASF AG

Inventor： DECKERS ANDREAS DR ,  GUENTHERBERG NORBERT DR ,  TIEFENSEE KRISTIN DR

IPC: C08K5/00 ,  C08L25/02 ,  C08L25/12 ,  C08L33/00 ,  C08L33/04 ,  C08L33/06 ,  C08L33/24 ,  C08L35/00 ,  C08L51/00 ,  C08L51/02 ,  C08L51/04 ,  C08L51/06 ,  C08L73/00 ,  C08L79/08

Abstract: Transparent and impact-resistant moulding compounds containing essentially A) 5 to 50% by weight of a polymer obtainable by polymerisation of a C1-C20-alkyl ester of methacrylic or acrylic acid or mixtures of such esters, B) 5 to 50% by weight of a polymer obtainable by polymerisation of a monomer mixture of b1) 75 to 82% by weight of an aromatic vinyl monomer and b2) 18 to 25% by weight of acrylonitrile or methacrylonitrile or a mixture thereof, C) 10 to 40% by weight of a polymer containing c1) 10 to 90% by weight of units of the general formula I where R is hydrogen or C1-C4-alkyl and R is C1-C18-alkyl, C5-C12-cycloalkyl, C6-C10-aryl or C6-C10-aryl-C1-C4- alkyl, which radicals, with the exception of the C1-C4-alkyl groups, can be substituted by up to three radicals selected from the group consisting of C1-C4-alkyl, C1-C4-alkoxy and halogen, c2) 10 to 90% by weight of a C1-C20-alkyl ester of methacrylic or acrylic acid or mixtures of such esters, D) 5 to 60% by weight of a graft copolymer having a weight average particle diameter of less than 200 nm and obtainable by polymerisation of 20 to 70% by weight of a monomer mixture of d1) 30 to 100% by weight of a C1-C20-alkyl ester of methacrylic or acrylic acid or mixtures of such esters and d2) 0 to 70% by weight of an aromatic vinyl monomer in the presence of 30 to 80% by weight of a grafting base obtainable by polymerisation of at least one monomer of the group consisting of butadiene, isoprene, aromatic vinyl monomers and C4-C20-alkyl esters of acrylic acid and E) 0 to 20% by weight of components A) to D), of customary additives, the percentages of components A) to D) adding to 100 and the difference between the refractive index of component D) and that of the mixture of components A), B) and C) and if desired E) being less than 0.01.

公开(公告)号：DE19509514A1

公开(公告)日：1996-09-19

申请号：DE19509514

申请日：1995-03-16

Applicant: BASF AG

Inventor： MAC KEE GRAHAM EDMUND DR ,  KOCH JUERGEN DR ,  FISCHER WOLFGANG DR ,  GOTTSCHALK AXEL DR ,  GUENTHERBERG NORBERT DR ,  ROSENAU BERNHARD DR

IPC: C08L51/06 ,  C08F265/04 ,  C08F291/02 ,  C08L33/02 ,  C08L35/06 ,  C08L51/00 ,  C08L51/04 ,  C08L55/00 ,  C08L55/02 ,  C08L71/00 ,  C08L71/02 ,  C08L71/12 ,  C08L77/00 ,  C08L101/00 ,  C08L35/00 ,  C08L25/00 ,  C08L23/00

Abstract: Thermoplastic moulding materials (I) contg. (A) 50-99 wt% impact-modified polymer, (B) 1-20 wt% of a mixt. of (B1) a copolymer contg. units derived from a polymerisable carboxylic acid or deriv.. and (B2) a polyamide, (C) 0-40 wt% fibrous and/or particulate fillers, and (D) 0-20 wt% conventional additives and processing aids.