Abstract:
Verfahren zur Umsetzung einer organischen Verbindung in Gegenwart eines Katalysators, der als Aktivmetall Ruthenium alleine oder zusammen mit mindestens einem Metall der I., VII. oder VIII. Nebengruppe des Periodensystems in einer Menge von 0,01 bis 30 Gew.-%, bezogen auf das Gesamtgewicht des Katalysators, aufgebracht auf einem Träger, umfaßt, dadurch gekennzeichnet, daß 10 bis 50% des Porenvolumens des Trägers von Makroporen mit einem Porendurchmesser im Bereich von 50 nm bis 10.000 nm und 50 bis 90% des Porenvolumens des Trägers von Mesoporen mit einem Porendurchmesser im Bereich von 2 bis 50 nm gebildet werden, wobei sich die Summe der Porenvolumina zu 100% addiert, sowie den Katalysator an sich.
Abstract:
Impact resistant thermoplastic moulding compound (I) containing (A) \- 50 wt% copolymer of 15-63 wt% 1,1-diphenylethylene (DPE) and 37-85 wt% styrene; (B) 5-35 wt% of a tri-block copolymer of (b 1) a block consisting mainly of the comonomer units in copolymer (A), (b 2) an elastomeric block and (b 3) a polystyrene block; (C) \- 5 wt% polystyrene and/or a polymer which is miscible with polystyrene; and (D) 0-40 wt% rubber.
Abstract:
Thermoplastic elastomer moulding compounds based on a rubber elastic block copolymer are obtained by hydrogenating a styrene-butadiene block copolymer composed of at least one block A that forms a hard phase and contains polymerised styrene units and of at least one elastomer block (B/S) that forms a soft phase and contains polymerised styrene and butadiene units. The glass transition temperature Tg of block A of the styrene-butadiene block copolymer lies above 25 DEG C and that of its block (B/S) lies below 25 DEG C. The phase volume ratio between blocks A and B/S is selected so that the proportion of hard phase in the total block copolymer equals 1 to 40 vol % and the weight percentage of diene is lower than 50 wt %.
Abstract:
The foam is based on a copolymer (I) of styrene with 2-50 mole-% 1,1-diphenylethene (II). Also claimed are methods for making the foam in various forms. The beads are produced by impregnating (I) granulate having an average diameter of 0.1-3 mm with a volatile blowing agent in aqueous suspension at 100-180 degrees C and then either (a) cooling the suspension, separating the granulate and foaming by supplying energy in a separate stage or (b) depressurising the hot suspension and hence foaming the granulate directly. Mouldings are made by from the prefoamed beads by foaming and welding in a mould. Boards and sheets are made by plasticising (I) in an extruder, mixing with a volatile blowing agent and extrusion through a wide slit die, with foaming.
Abstract:
A process for the preparation of polymers of isobutene having tertiary chloride groups by reaction of appropriate polymers which have been prepared by cationic polymerization of isobutene with hydrogen chloride.
Abstract:
A process for the preparation of polymers of isobutene having tertiary chloride groups by reaction of appropriate polymers which have been prepared by cationic polymerization of isobutene with hydrogen chloride.
Abstract:
Moulding materials (MM) are claimed, containing (P1) 5-95 wt% block copolymer with block(s) (A) based on (a1) vinylaromatic monomers and (a2) 1,1-diphenylethylene (DPE) or DPE derivatives with 1-22C alkyl substituents on the benzene ring and optionally hydrogenated block(s) (B) derived from (b) dienes, (P2) 5-95 wt% polyolefin and (P3) 0-90 wt% additives. Also claimed are fibres, film and moulded products obtained from MM.