公开(公告)号：EP2621922A1

公开(公告)日：2013-08-07

申请号：EP11760799.4

申请日：2011-09-27

Applicant: BASF SE

Inventor： DOCHNAHL, Maximilian ,  KEIL, Michael ,  GEBHARDT, Joachim ,  VOGELBACHER, Uwe Josef ,  RACK, Michael

IPC: C07D405/06 ,  C07F3/02 ,  C07B45/06

CPC classification number: C07D405/02 ,  C07D249/10 ,  C07D405/06 ,  C07F3/02 ,  Y02P20/582

Abstract: The present invention relates to a process using specific magnesium reagents for providing thio-triazolo group-containing compounds and for the synthesis of precursors therefor. The invention furthermore relates to intermediates and to their preparation.

Abstract translation: 本发明涉及使用特定的镁试剂来提供含硫代三唑基化合物并用于合成其前体的方法。 本发明还涉及中间体及其制备。

公开(公告)号：EP2297111B1

公开(公告)日：2012-06-20

申请号：EP09738223.8

申请日：2009-04-30

Applicant: BASF SE

Inventor： ZIERKE, Thomas ,  MAYWALD, Volker ,  RACK, Michael ,  SMIDT, Sebastian Peer ,  KEIL, Michael ,  WOLF, Bernd ,  KORADIN, Christopher

IPC: C07D231/14 ,  C07D295/145

CPC classification number: C07D295/145 ,  C07D231/14

Abstract: The present invention relates to a method for producing 2- (aminomethylidene)-4,4dihalo-3-oxobutyric acid esters of the formula (I), where R
1 , R
2 , R
3 are C
1 -C
6 -alkyl, C
1 -C
6 -haloalkyl, C
2 -C
6 -alkenyl, C
3 -C
10 -cycloalkyl or benzyl and/or R
2 together with R
3 and the nitrogen atom, to which both radicals are bound, are a heterocyclic radical, wherein a corresponding 3-aminoacrylic acid ester is reacted with a halogen-substituted acetyl fluoride in the presence of at least one alkali or earth alkali metal fluoride. The invention also relates to the further reaction of halogen-substituted 2-(aminomethylidene)-3-oxobutyric acid esters of the formula (1) into halomethyl-substituted pyrazole-4-ylcarboxylic acids and the esters thereof.

公开(公告)号：EP2307384B1

公开(公告)日：2012-04-25

申请号：EP09780455.3

申请日：2009-07-10

Applicant: BASF SE

Inventor： WOLF, Bernd ,  SMIDT, Sebastian, Peer ,  MAYWALD, Volker ,  KORADIN, Chistopher ,  RACK, Michael ,  KEIL, Michael ,  ZIERKE, Thomas

IPC: C07D233/90

CPC classification number: C07D233/90

Abstract: A process for preparing 1,3-disubstituted pyrazolecarboxylic esters of the formula (I); where X, Y, Z = hydrogen or halogen and R
1 = C
1 -C
6 -alkyl, by metering an enol ether of the formula (III); where R
2 is C
1 -C
6 -alkyl at from (-41) to (-8O)°C into an alkyl hydrazine of the formula II H
2 N-NH-lower alkyl (II).

公开(公告)号：EP1904475B1

公开(公告)日：2011-08-17

申请号：EP06764009.4

申请日：2006-06-30

Applicant: BASF SE

Inventor： SCHMIDT, Thomas ,  PUHL, Michael ,  DICKHAUT, Joachim ,  BASTIAANS, Henricus Maria Martinus ,  RACK, Michael ,  CULBERTSON, Deborah L. ,  ANSPAUGH, Douglas D. ,  BRAUN, Franz-Josef ,  BUCCI, Toni ,  COTTER, Henry Van Tuyl ,  KUHN, David G. ,  OLOUMI-SADEGHI, Hassan

IPC: C07D401/04 ,  A01N43/56

CPC classification number: C07D401/04 ,  A01N43/56 ,  A01N43/84 ,  C07D401/14 ,  C07D409/14 ,  C07D413/14

Abstract: N-Thio-anthranilamid compounds of Formula (I) wherein A is a group selected from A1 and A2 wherein the variables and the indices are as defined per the description, processes for preparing the compounds (I), pesticidal compositions comprising compounds (I), use of compounds (I) for the control of insects, acarids or nematodes, and methods for treating, controlling, preventing or protecting animals against infestation or infection by parasites by use of compounds of Formula (I).

Abstract translation: （I）的N-硫代邻氨基苯甲酰胺化合物，其中A是选自A1和A2的基团，其中变量和指数如说明书所定义，制备化合物（I）的方法，包含化合物（I）的杀虫组合物， ，化合物（I）用于防治昆虫，螨或线虫的用途，以及通过使用式（I）化合物治疗，控制，预防或保护动物免受寄生虫侵染或感染的方法。

公开(公告)号：EP2318379A1

公开(公告)日：2011-05-11

申请号：EP09781280.4

申请日：2009-07-30

Applicant: BASF SE

Inventor： ZIERKE, Thomas ,  HUPE, Eike ,  RACK, Michael ,  PARRA RAPADO, Liliana ,  FRASSETTO, Timo

IPC: C07D241/08

CPC classification number: C07D241/08

Abstract: Method for preparation of piperazindione derivates of formula I, wherein R
1 stands for hydrogen, alkyl, alkenyl, alkinyl and alkylcarbonyl, R
2 stands for hydrogen, alkyl, alkenyl, C
3 -C
4 -alkinyl and C(=O)R
11 , R
3 ,R
4 stand for hydrogen, alkyl and halogen-alkyl, wherein the groups can be substituted, characterized in that amines of formula II, in which R
1 stands for hydrogen and alkyl, which likewise can be substituted, are reacted under basic conditions in an aqueous solvent with N-acylated amino acid derivates of formula II, wherein X stands for halogen, Y halogen, alkoxy or phenyloxy, which can be substituted, and R
2 , R
3 and R
4 have the meaning above.

公开(公告)号：EP2315760A1

公开(公告)日：2011-05-04

申请号：EP09780999.0

申请日：2009-07-23

Applicant: BASF SE

Inventor： PARRA RAPADO, Liliana ,  HUPE, Eike ,  WITSCHEL, Matthias ,  SEITZ, Thomas ,  SIMON, Anja ,  REINHARD, Robert ,  SIEVERNICH, Bernd ,  GROßMANN, Klaus ,  EHRHARDT, Thomas ,  NEWTON, Trevor William ,  STELZER, Frank ,  QU, Tao ,  MOBERG, William Karl ,  SONG, Dschun ,  RACK, Michael ,  FRASSETTO, Timo ,  KREUZ, Klaus ,  MAJOR, Julia

IPC: C07D401/06 ,  C07D403/06 ,  A01N43/60

CPC classification number: C07D401/06 ,  A01N43/60 ,  A01N43/78 ,  A01N43/80 ,  A01N43/82 ,  A01N43/84 ,  A01N43/90 ,  C07D403/06 ,  A01N33/18 ,  A01N43/54 ,  A01N2300/00

Abstract: Piperazine compounds of formula (I), where the variables are defined according to the description, agriculturally suitable salts of said piperazine compounds, a method and intermediate products for the production of the piperazine compounds of formula (I), means comprising said compounds and use thereof as herbicides, i.e. to combat weeds, and a method for combating undesired plant growth wherein an amount of at least one piperazine compound of formula (I) large enough to have an herbicidal effect is allowed to take effect on plants, seeds and/or habitats thereof.

Abstract translation: 其中变量根据说明书定义的式（I）的哌嗪化合物，所述哌嗪化合物的农业上合适的盐，用于制备式（I）的哌嗪化合物的方法和中间产物，包括所述化合物和用途的方法 其作为除草剂，即用于防治杂草，以及防治不希望的植物生长的方法，其中使至少一种足够大以具有除草效果的式（I）哌嗪化合物对植物，种子和/或 栖息地。

公开(公告)号：EP2297111A2

公开(公告)日：2011-03-23

申请号：EP09738223.8

申请日：2009-04-30

Applicant: BASF SE

Inventor： ZIERKE, Thomas ,  MAYWALD, Volker ,  RACK, Michael ,  SMIDT, Sebastian Peer ,  KEIL, Michael ,  WOLF, Bernd ,  KORADIN, Christopher

IPC: C07D231/14 ,  C07D295/145

CPC classification number: C07D295/145 ,  C07D231/14

Abstract: The present invention relates to a method for producing 2- (aminomethylidene)-4,4dihalo-3-oxobutyric acid esters of the formula (I), where R
1 , R
2 , R
3 are C
1 -C
6 -alkyl, C
1 -C
6 -haloalkyl, C
2 -C
6 -alkenyl, C
3 -C
10 -cycloalkyl or benzyl and/or R
2 together with R
3 and the nitrogen atom, to which both radicals are bound, are a heterocyclic radical, wherein a corresponding 3-aminoacrylic acid ester is reacted with a halogen-substituted acetyl fluoride in the presence of at least one alkali or earth alkali metal fluoride. The invention also relates to the further reaction of halogen-substituted 2-(aminomethylidene)-3-oxobutyric acid esters of the formula (1) into halomethyl-substituted pyrazole-4-ylcarboxylic acids and the esters thereof.

公开(公告)号：EP1888533B1

公开(公告)日：2010-12-15

申请号：EP06777225.1

申请日：2006-05-18

Applicant: BASF SE

Inventor： KORDES, Markus ,  GÖTZ, Norbert ,  RACK, Michael ,  KORADIN, Christopher ,  TEDESCHI, Livio ,  CULBERTSON, Deborah L.

IPC: C07D233/48 ,  A01N43/54

CPC classification number: A01N43/50 ,  C07D233/48

Abstract: The present invention relates to 1-(imidazolin-2-yl)amino-1,2-diphenylethane compounds of the formula I and their agriculturally acceptable salts, wherein A is a radical of the formula A1 or A2. The invention relates also to agricultural compositions and to seed comprising at least one compound I and/or a salt thereof, as well as a method of combating animal pests, a method for protecting crops from attack or infestation by animal pests and a method for protecting non-living materials from attack or infestation by animal pests, a method for the protection of seeds from animal pests and of the seedlings' roots and shoots from animal pests by applying a pesticidally effective amount of at least one 1-(imidazolin-2-yl)amino-1 ,2- diphenylethane compound I and/or a salt thereof.

公开(公告)号：EP1458675B1

公开(公告)日：2010-02-24

申请号：EP02795204.3

申请日：2002-12-17

Applicant: BASF SE

Inventor： PLATH, Peter ,  GÖTZ, Norbert ,  RACK, Michael ,  LANDES, Andreas ,  ZAGAR, Cyrill ,  WITSCHEL, Matthias ,  GROSSMAN, Klaus

IPC: C07C255/30 ,  C07C323/12 ,  C07C323/60 ,  C07C327/22 ,  C07D307/22 ,  C07D307/20 ,  C07D305/08 ,  C07D331/04

CPC classification number: C07D295/185 ,  A01N37/44 ,  A01N43/08 ,  A01N43/16 ,  C07C255/30 ,  C07C323/60 ,  C07C327/22 ,  C07C2601/02 ,  C07C2601/08 ,  C07C2601/14 ,  C07D305/08 ,  C07D307/18 ,  C07D307/20 ,  C07D307/22 ,  C07D309/14 ,  C07D319/06 ,  C07D331/04

Abstract: α-Cyanoacrylates of the formula (I), where: R1 is ORa wherein Ra is hydrogen, substituted alkyl, branched alkyl, branched alkenyl, cycloloalkyl, heterocyclyl, aryl, phenylalkyl or alkyl­imino; is NRbRc wherein Rb is hydrogen, alkyl which may be substituted, alkenyl, alkynyl; Rc is hydrogen, alkyl which may be substituted alkenyl, alkynyl, cycloalkyl, heterocyclyl, aryl, phenylalkyl or alkylimino; or Rb and Rc form an alkandiyl-chain which may be substituted; or is SRd wherein Rd is hydrogen, alkyl which may be substituted, alkenyl, alkynyl, cycloalkyl, heterocyclyl, aryl, phenylalkyl or alkylimino; R2 is alkyl which may be substituted; is alkenyl or alkynyl; R3 is alkyl may be substituted; is alkenyl or alkynyl; R4 is hydrogen, halogen, cyano or alkyl; and their agriculturally useful salts, processes and intermediates for their preparation; and the use of these compounds or of compositions comprising these compounds for controlling undesirable plants are described.

Abstract translation: 式I的α-氰基丙烯酸酯，其中：R1是ORa，其中Ra是氢，取代的烷基，支链烷基，支链烯基，环烷基，杂环基，芳基，苯基烷基或烷基亚氨基; 是NRbRc，其中Rb是氢，可以被取代的烷基，烯基，炔基; Rc是氢，可以被取代的烯基，炔基，环烷基，杂环基，芳基，苯基烷基或烷基亚氨基的烷基; 或R b和R c形成可被取代的烷撑二链; 或者是其中Rd是氢的SRd，可以被取代的烷基，烯基，炔基，环烷基，杂环基，芳基，苯基烷基或烷基亚氨基; R2是可被取代的烷基; 是烯基或炔基; R3是烷基可以被取代; 是烯基或炔基; R4是氢，卤素，氰基或烷基; 及其农业上有用的盐，其制备方法和中间体; 并描述了这些化合物或包含这些化合物的组合物用于防治不期望的植物的用途。

公开(公告)号：EP2137136A2

公开(公告)日：2009-12-30

申请号：EP08717156.7

申请日：2008-02-27

Applicant: BASF SE

Inventor： ZIERKE, Thomas ,  RACK, Michael

IPC: C07C241/02

CPC classification number: C07C319/20 ,  C07C241/02 ,  C07C323/48 ,  C07C243/22

Abstract: This invention relates to a process for preparing substituted phenylhydrazines of the formula I wherein R has the meaning as indicated in the description, comprising reacting a dichlorofluorobenzene of the formula Il with a hydrazine source selected from hydrazine, hydrazine hydrate and acid addition salts of hydrazine and optionally being carried out in the presence of at least one organic solvent.