Abstract:
The invention is related to a coating delivery system that includes at least one pressure vessel operable in sealed and unsealed conditions, a deliverable substance including a coating component interspersed with at least one of liquefied carbon dioxide and supercritical carbon dioxide, and a pressurizing fluid. The deliverable substance is disposed in a first pressure vessel of the at least one pressure vessel, and the pressurizing fluid directly exerts a pressure on the deliverable substance to effect transport thereof when the pressure vessel is in the unsealed condition. The deliverable substance may be spray discharged.
Abstract:
A method for forming a continuous film on a substrate surface that involves depositing particles onto a substrate surface and contacting the particle-deposited substrate surface with a supercritical fluid under conditions sufficient for forming a continuous film from the deposited particles. The particles may have a mean particle size of less 1 micron. The method may be performed by providing a pressure vessel that can contain a compressible fluid. A particle-deposited substrate is provided in the pressure vessel and the compressible fluid is maintained at a supercritical or sub-critical state sufficient for forming a film from the deposited particles. The Tg of particles may be reduced by subjecting the particles to the methods detailed in the present disclosure.
Abstract:
A sprayable liquid coating composition, particularly for application to foodstuffs and pharmaceuticals, utilizes gaseous carbon dioxide to reduce the viscosity of a concentrated solution comprising an edible polymer and a solvent, such as ethyl alcohol or isopropyl alcohol. The addition of the gaseous carbon dioxide in the concentrated solution permits a sprayable composition to be produced using a significantly reduced level of solvent in the edible polymer/solvent solution. By reducing the amount of solvent used in the solution, the level of VOCs emission during the coating process also is reduced. Either supercritical carbon dioxide or subcritical carbon dioxide can be used as the gaseous carbon dioxide in the present invention.
Abstract:
A method for the patterned deposition of a material comprises the steps of dissolving or suspending said material in a solvent phase comprising compressed carbon dioxide, and depositing the solution or suspension onto a surface, evaporation of the solvent phase leaving a patterned deposit of said material. This method is particularly suitable for the patterned deposition of polymers and small organic molecules in organic light emitting diodes and organic transistors.
Abstract:
Systems and apparatus combinations for producing a coating powder are provided wherein a stream of a powder coating precursor including at least one resin and at least one additional powder coating ingredient is contacted with a process fluid effective to reduce the viscosity of the powder coating precursor to allow processing of the powder coating precursor at a lower temperature.
Abstract:
The present invention provides composition for treating a substrate comprising a homogeneous mixture of: (a) a fluorinated silane of the formula: Rff1-null-Q-SiY3-xR1xnully nullnull(I) wherein Rf1 represents a monovalent or divalent perfluorinated group, Q represents an organic divalent linking group, R1 represents a C1-C4 alkyl group, Y represents a hydrolysable group; x is 0 or 1 and y is 1 or 2; (b) compressed fluid carbon dioxide; and (c) optionally an organic or inorganic acid. The invention further provides a method of making such a composition and the use thereof to treat substrates to render them oil and water repellent.
Abstract:
A sprayable liquid coating composition, particularly for application to foodstuffs and pharmaceuticals, utilizes gaseous carbon dioxide to reduce the viscosity of a concentrated solution comprising an edible polymer and a solvent, such as ethyl alcohol or isopropyl alcohol. The addition of the gaseous carbon dioxide in the concentrated solution permits a sprayable composition to be produced using a significantly reduced level of solvent in the edible polymer/solvent solution. By reducing the amount of solvent used in the solution, the level of VOCs emission during the coating process also is reduced. Either supercritical carbon dioxide or subcritical carbon dioxide can be used as the gaseous carbon dioxide in the present invention.
Abstract:
Systems, apparatus combinations and methods for producing a powder coating are provided wherein a stream of a powder coating precursor including at least one resin and at least one additional powder coating ingredient is contacted with a process fluid effective to reduce the viscosity of the powder coating precursor to allow processing of the powder coating precursor at a lower temperature.
Abstract:
A method of protecting a civil infrastructure substrate from the damaging effects of pollution, noxious fumes, weather, and the like. The method comprises (a) providing a composition comprising carbon dioxide and a fluorocarbon such as a fluoropolyether (preferably a perfluoropolyether) or a fluorocarbon elastomer, optionally having at least one anchoring group such as an amide covalently joined thereto, and then (b) applying that composition to the civil infrastructure substrate to form a protective coating thereon. The applying step is preferably carried out by spraying. Compositions useful for carrying out the process of the invention are also disclosed.
Abstract:
This invention relates to methods for spraying liquid compositions containing volatile solvent by using compressed fluids, such as carbon dioxide or ethane, to form solid particulates, coating powders, and catalyst materials, which can be produced with narrow particle size distributions and can be sprayed at higher solids levels, in ambient air or with heated air applied to just the spray instead of a spray chamber. Novel catalyst supports can be produced having a beneficial morphology such as for olefin catalysis. Drier water-borne coatings can be applied to substrates by using compressed fluids to spray water-borne coating compositions having conventional water levels, thereby reducing runs and sags and shortening dry times.