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公开(公告)号：US09828488B2
公开(公告)日：2017-11-28
申请号：US15227038
申请日：2016-08-03
Applicant: RIKEN TECHNOS CORPORATION
Inventor： Koji Sakai
IPC: C08K5/12 , A61L31/14 , A61L29/04 , A61L31/04 , A61L29/14 , C08K5/00 , C08K5/04 , C08K5/1515 , A61J1/10 , A61L29/12 , C08L27/06 , B29K27/06 , C08L91/00
CPC classification number: C08K5/12 , A61J1/10 , A61L29/04 , A61L29/041 , A61L29/126 , A61L29/141 , A61L29/143 , A61L31/04 , A61L31/048 , A61L31/141 , A61L31/143 , B29K2027/06 , C08K5/0016 , C08K5/005 , C08K5/04 , C08K5/1515 , C08L27/06 , C08L91/00 , Y10T428/1334 , Y10T428/1352 , Y10T428/139 , Y10T428/1393 , Y10T428/1397
Abstract: PURPOSE: The present invention provides a polyvinyl chloride resin composition which is superior in heat stability and processability and has less elution from the composition.CONSTITUTION: a polyvinyl chloride resin composition comprising 100 parts by weight of a polyvinyl chloride resin, 10 to 120 parts by weight of di(2-ethylhexyl)terephthalate, and 0.5 to 20 parts by weight of epoxidized vegetable oil having a peroxide number of 5 or less.
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公开(公告)号：US20170306188A1
公开(公告)日：2017-10-26
申请号：US15516312
申请日：2015-09-11
Applicant: RIKEN TECHNOS CORPORATION
Inventor： Jun FUJIMOTO , Nozomu WASHIO
Abstract: Embodiments provide a pressure-sensitive adhesive film having (α) a poly(meth)acrylimide-based resin film layer and (γ) a pressure-sensitive adhesive agent layer in that order from the surface layer side and having a total light transmittance of 80% or higher. The pressure-sensitive adhesive film may further have (δ) a hard coat layer on the surface layer side of the poly(meth)acrylimide-based resin film layer (α). This hard coat layer (δ) may comprise an active energy ray-curable resin composition that contains (A) 100 parts by mass of a polyfunctional (meth)acrylate; (B) 0.2-4 parts by mass of a compound having an alkoxysilyl group and a (meth)acryloyl group; (C) 0.05-3 parts by mass of organic titanium; and (D) 5-100 parts by mass of fine particles having an average particle diameter of 1-300 nm. This active energy ray-curable resin composition may further contain (E) 0.01-7 parts by mass of a water-repelling agent.
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公开(公告)号：US20170056921A1
公开(公告)日：2017-03-02
申请号：US15109407
申请日：2015-06-19
Applicant: RIKEN TECHNOS CORPORATION
Inventor： Nozomu WASHIO , Taketo HASHIMOTO
CPC classification number: B05D3/06 , B05D3/002 , B05D3/0209 , B05D3/067 , B05D7/04 , B05D7/536 , B32B27/08 , B32B27/281 , B32B27/308 , B32B27/365 , B32B2255/10 , B32B2255/26 , B32B2307/412 , B32B2307/518 , B32B2307/536 , B32B2307/554 , B32B2307/581 , B32B2307/732 , B32B2307/736 , B32B2457/20 , C08J7/042 , C08J7/123 , C08J2379/08 , C08J2433/08 , C08J2433/10 , C08J2471/00 , C09D133/14
Abstract: Embodiments of the invention provide a hard coat laminated film including a first hard coat, a second hard coat, and a transparent resin film layer in order from the outermost surface layer side, wherein the first hard coat is formed of a coating material containing no inorganic particles; the second hard coat is formed of a coating material containing inorganic particles; and the hard coat laminated film satisfies the following requirements: (i) the total light transmittance is 85% or more; and (ii) the pencil hardness of the surface of the first hard coat is 5H or higher. According to another embodiment, a hard coat laminated film is provided, which includes a first hard coat, a second hard coat, and a transparent resin film layer in order from the outermost surface layer side, wherein the first hard coat is formed of a coating material containing predetermined amounts of (A) a polyfunctional (meth)acrylate; (B) a water repellant; and (C) a silane coupling agent and containing no inorganic particles; and the second hard coat is formed of a coating material containing (A) 100 parts by mass of a polyfunctional (meth)acrylate; and (D) 50 to 300 parts by mass of inorganic fine particles having an average particle size of 1 to 300 nm.
Abstract translation: 本发明的实施方案从最外表层提供包括第一硬涂层，第二硬涂层和透明树脂膜层的硬涂层压薄膜，其中第一硬涂层由不含无机材料的涂料形成 粒子; 第二硬涂层由含有无机颗粒的涂料形成; 硬涂层层膜满足以下要求：（i）总透光率为85％以上; 和（ii）第一硬涂层的表面的铅笔硬度为5H以上。 根据另一实施例，提供一种硬涂层层叠膜，其从最外表面层一侧开始包括第一硬涂层，第二硬涂层和透明树脂膜层，其中第一硬涂层由涂层形成 含有预定量的（A）多官能（甲基）丙烯酸酯的材料; （B）防水剂; 和（C）硅烷偶联剂，不含无机颗粒; 第二硬涂层由含有（A）100质量份多官能（甲基）丙烯酸酯的涂料形成; 和（D）50〜300质量份的平均粒径为1〜300nm的无机微粒。
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公开(公告)号：US20160355666A1
公开(公告)日：2016-12-08
申请号：US15227038
申请日：2016-08-03
Applicant: RIKEN TECHNOS CORPORATION
Inventor： KOJI SAKAI
CPC classification number: C08K5/12 , A61J1/10 , A61L29/04 , A61L29/041 , A61L29/126 , A61L29/141 , A61L29/143 , A61L31/04 , A61L31/048 , A61L31/141 , A61L31/143 , B29K2027/06 , C08K5/0016 , C08K5/005 , C08K5/04 , C08K5/1515 , C08L27/06 , C08L91/00 , Y10T428/1334 , Y10T428/1352 , Y10T428/139 , Y10T428/1393 , Y10T428/1397
Abstract: PURPOSE: The present invention provides a polyvinyl chloride resin composition which is superior in heat stability and processability and has less elution from the composition.CONSTITUTION: a polyvinyl chloride resin composition comprising 100 parts by weight of a polyvinyl chloride resin, 10 to 120 parts by weight of di(2-ethylhexyl)terephthelate, and 0.5 to 20 parts by weight of epoxidized vegetable oil having a peroxide number of 5 or less.
Abstract translation: 构成：包含100重量份的聚氯乙烯树脂，10至120重量份的对苯二甲酸二（2-乙基己基）酯和0.5至20重量份的过氧化物数为5的环氧化植物油的聚氯乙烯树脂组合物 或更少。
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公开(公告)号：US20160194500A1
公开(公告)日：2016-07-07
申请号：US14902832
申请日：2014-06-17
Applicant: RIKEN TECHNOS CORPORATION
Inventor： Ryoichi TANABE , Nozomu WASHIO
CPC classification number: C09D4/00 , B05D3/06 , B32B15/09 , B32B27/36 , B32B2439/66 , C08K5/541 , C09D7/40 , C09D7/47 , C09D7/66 , G06F3/041 , G06F2203/04103
Abstract: Embodiments of invention provide a method for producing a hard coat film which has a hard coat that is formed from an active energy ray-curable resin composition on at least one surface of a film base. According to at least one embodiment, the active energy ray-curable resin composition used in this method contains (P) 100 parts by mass of a urethane (meth)acrylate compound, (Q) 0.02-5 parts by mass of organic fine particles having an average particle diameter of 10-300 nm, and (R) 0.0002-2 parts by mass of an acrylic silicone-based leveling agent. The method according to at least one embodiment includes the steps of (1) forming a wet coating film by applying the active energy ray-curable resin composition to the film base, (2) forming a dry coating film by drying the wet coating film, and (3) forming a hard coat film by curing the dry coating film by means of active energy ray irradiation at a temperature of 50-90° C.
Abstract translation: 本发明的实施方式提供一种制备硬涂层的方法，该硬涂膜具有由活性能量射线固化树脂组合物形成在硬质基底上的至少一个表面上的硬涂层。 根据至少一个实施方案，该方法中使用的活性能量射线固化性树脂组合物含有（P）100质量份的氨基甲酸酯（甲基）丙烯酸酯化合物，（Q）0.02〜5质量份的具有 平均粒径为10-300nm，（R）0.0002-2质量份丙烯酸硅氧烷类流平剂。 根据至少一个实施方案的方法包括以下步骤：（1）通过将活性能量射线固化树脂组合物施加到膜基底上形成湿涂膜，（2）通过干燥湿涂膜形成干燥涂膜， 和（3）通过在50-90℃的温度下通过活性能量射线照射固化干涂膜来形成硬涂膜。
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Patent Agency Ranking
116.发明申请POLY(METH)ACRYLIMIDE FILM, EASY-ADHESION FILM USING SAME, AND METHOD FOR MANUFACTURING SUCH FILMS 审中-公开聚（甲基）丙烯酰胺薄膜，使用它的易粘合薄膜和制造这种薄膜的方法公开(公告)号：US20160159995A1
公开(公告)日：2016-06-09
申请号：US14904025
申请日：2014-06-11
Applicant: RIKEN TECHNOS CORPORATION
Inventor： Kohei NAKASHIMA , Kazutaka YAMADA , Hidemasa SUGIMOTO , Yoshihiro ZENNYOJI
Abstract: Embodiments of the invention relate to a poly(meth)acrylimide film and a method for manufacturing such a film. At least one embodiment provides a poly(meth)acrylimide film that has (i) a total light transmittance of over 90% and (ii) haze of 2.0% or less. This film preferably has retardation of less than 50 nm. The method for manufacturing this film includes the following steps: (A) using a device provided with an extruder and a T die, a poly(meth)acrylimide molten film is continuously extruded from the T die; and (B) the poly(meth)acrylimide molten film is loaded by being fed between a rotating or circulating first mirrored-surface body and a rotating or circulating second mirrored-surface body, and then the film is pressed. During these steps, (C) the surface temperature of the first mirrored-surface body is in the range 100-200° C., and (D) the surface temperature of the second mirrored-surface body is in the range 20-200° C.
Abstract translation: 本发明的实施方案涉及聚（甲基）丙烯酰亚胺膜及其制造方法。 至少一个实施方案提供聚（甲基）丙烯酰亚胺膜，其具有（i）总透光率超过90％，（ii）雾度为2.0％以下。 该膜优选具有小于50nm的延迟。 制造该膜的方法包括以下步骤：（A）使用具有挤出机和T模头的装置，从T模头连续挤出聚（甲基）丙烯酰亚胺熔融膜; 和（B）聚（甲基）丙烯酰亚胺熔融膜通过馈送在旋转或循环的第一镜面体和旋转或循环的第二镜面体之间被加载，然后将膜压制。 在这些步骤中，（C）第一镜面体的表面温度在100-200℃的范围内，（D）第二镜面体的表面温度在20-200°的范围内 C。
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117.发明申请公开(公告)号：US20160152780A1
公开(公告)日：2016-06-02
申请号：US14904624
申请日：2014-06-26
Applicant: RIKEN TECHNOS CORPORATION
Inventor： Tomohiro TAKAHASHI , Hidemasa SUGIMOTO , Motoi HIUGANO
CPC classification number: C08J3/203 , A01G9/1407 , C08J5/18 , C08J2327/06 , C08K9/02 , C08K2003/2231 , C08L23/0853 , C08L27/06 , C08L51/04 , C08L2205/03
Abstract: Embodiments of the invention relate to a method for manufacturing a heat-shielding film in which a heat-shielding material has been well dispersed in a polyvinyl chloride resin. According to at least one embodiment, the method for manufacturing the heat-shielding film includes the steps of (1) mixing a polyvinyl chloride resin composition (P) containing the polyvinyl chloride resin (A) using a blender, and (2) adding and further mixing the heat-shielding material with the mixture obtained in step (1). According to at least one embodiment, the heat-shielding material contains at least antimony-doped tin oxide micro-particles (B) in an amount in which the mass ratio of the polyvinyl chloride resin (A) to antimony-doped oxidized tin micro-particles (B) is 100 parts by mass to 1.5 to 15 parts by mass. According to at least one embodiment, the heat-shielding material is composed of antimony-doped oxidized tin micro-particles (B) alone. In this case, all components other than the antimony-doped oxidized tin micro-particles (B) may be mixed in step (1).
Abstract translation: 本发明的实施例涉及一种制造其中隔热材料已经很好地分散在聚氯乙烯树脂中的热屏蔽膜的制造方法。 根据至少一个实施方案，制造该热屏蔽膜的方法包括以下步骤：（1）使用混合器混合含有聚氯乙烯树脂（A）的聚氯乙烯树脂组合物（P），和（2） 进一步将隔热材料与步骤（1）中获得的混合物混合。 根据至少一个实施方案，热屏蔽材料至少含有锑掺杂的氧化锡微粒（B），其中聚氯乙烯树脂（A）与锑掺杂的氧化锡微粒子的质量比， 颗粒（B）为100质量份至1.5至15质量份。 根据至少一个实施例，隔热材料仅由锑掺杂氧化锡微粒（B）组成。 在这种情况下，在锑掺杂氧化锡微粒（B）以外的所有成分可以在步骤（1）中混合。
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公开(公告)号：TW201821274A
公开(公告)日：2018-06-16
申请号：TW106126870
申请日：2017-08-09
Applicant: 日商理研科技股份有限公司 , RIKEN TECHNOS CORPORATION
Inventor： 善如寺芳弘 , ZENNYOJI, YOSHIHIRO , 紗由里 , INOMATA, SAYURI
Abstract: 本發明之課題係提供一種與裸銅之接著性為優異，即使是長期間被暴露於高溫多濕的環境中亦可保持與裸銅之接著性、且能以無交聯步驟而得到適合於高額定溫度之規格或該規格之認證的樹脂組成物，及提供使用該樹脂組成物的可適合作為撓性扁平電纜的被覆材使用的層合體。 本發明之解決手段為一種層合體的接著層用樹脂組成物，其係包含（A）酸改性聚丙烯系樹脂55~85質量%、及（B）乙烯與選自由乙酸乙烯酯、甲基丙烯酸烷基酯、及丙烯酸烷基酯所成之群之1種以上的共聚單體的共聚物45~15質量%；於此上述成分（A）與上述成分（B）之和為100質量%；上述成分（A）的酸改性量為0.5~10莫耳%。
Abstract in simplified Chinese: 本发明之课题系提供一种与裸铜之接着性为优异，即使是长期间被暴露于高温多湿的环境中亦可保持与裸铜之接着性、且能以无交联步骤而得到适合于高额定温度之规格或该规格之认证的树脂组成物，及提供使用该树脂组成物的可适合作为挠性扁平电缆的被覆材使用的层合体。 本发明之解决手段为一种层合体的接着层用树脂组成物，其系包含（A）酸改性聚丙烯系树脂55~85质量%、及（B）乙烯与选自由乙酸乙烯酯、甲基丙烯酸烷基酯、及丙烯酸烷基酯所成之群之1种以上的共聚单体的共聚物45~15质量%；于此上述成分（A）与上述成分（B）之和为100质量%；上述成分（A）的酸改性量为0.5~10莫耳%。
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公开(公告)号：TW201730312A
公开(公告)日：2017-09-01
申请号：TW105106732
申请日：2016-03-04
Applicant: 理研科技股份有限公司 , RIKEN TECHNOS CORPORATION
Inventor： 中島尚子 , NAKAJIMA, SHOKO , 猪股仁美 , INOMATA, HITOMI
IPC: C09J133/04 , C08K5/5419 , C08K5/1515 , B32B7/12 , B32B17/06 , B32B27/06 , C03C27/10 , F25D23/02
CPC classification number: B32B27/00 , C09J7/20 , C09J11/04 , C09J133/00 , C09J163/00
Abstract: 本發明之一種形態，係一種黏著劑包含有：(A)玻璃轉移溫度為-50~-25℃之丙烯酸聚合物100質量部；(B)具有環氧基之矽烷偶聯劑(silane coupling)0.01~3質量部；(C)於1分子中具有2個以上之環氧基之化合物0.01~9質量部；及(D)有機多價金屬化合物0.01~0.5質量部。本發明之另一種形態，係一種化妝薄片，係具有包含該黏著劑之層。本發明之另一種形態，係一種面板，可開關物品本體之前面部之門體之前面面板，從物品之前面側依序具有：(α)玻璃或透明樹脂薄片之層；(β)包含有上述黏著劑之層；及(γ)樹脂薄膜之層；及一種面板，可開關物品本體之前面部之門體之前面面板，從物品之前面側依序具有：(γ)樹脂薄膜之層；(β)包含有上述黏著劑之層；及(α)玻璃或透明樹脂薄片之層。
Abstract in simplified Chinese: 本发明之一种形态，系一种黏着剂包含有：(A)玻璃转移温度为-50~-25℃之丙烯酸聚合物100质量部；(B)具有环氧基之硅烷偶联剂(silane coupling)0.01~3质量部；(C)于1分子中具有2个以上之环氧基之化合物0.01~9质量部；及(D)有机多价金属化合物0.01~0.5质量部。本发明之另一种形态，系一种化妆薄片，系具有包含该黏着剂之层。本发明之另一种形态，系一种皮肤，可开关物品本体之前面部之门体之前面皮肤，从物品之前面侧依序具有：(α)玻璃或透明树脂薄片之层；(β)包含有上述黏着剂之层；及(γ)树脂薄膜之层；及一种皮肤，可开关物品本体之前面部之门体之前面皮肤，从物品之前面侧依序具有：(γ)树脂薄膜之层；(β)包含有上述黏着剂之层；及(α)玻璃或透明树脂薄片之层。
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公开(公告)号：TW201718781A
公开(公告)日：2017-06-01
申请号：TW105136889
申请日：2016-11-11
Applicant: 理研科技股份有限公司 , RIKEN TECHNOS CORPORATION
Inventor： 鹫尾望 , WASHIO, NOZOMU , 橋本岳人 , HASHIMOTO, TAKETO , 中島尚子 , NAKAJIMA, SHOKO , 猪股仁美 , INOMATA, HITOMI
Abstract: 本發明之一態樣係一種門體，其係開關物品本體之正面部者，並且具有構成正面之正面板、支持正面板之外側端部之至少一部分的框體、及構成背面之背面板；正面板含有硬塗層積層片材；硬塗層積層片材自正面側之表層側起依序具有第1硬塗層、第2硬塗層、及透明樹脂片材之層；第1硬塗層係由含有(A)多官能(甲基)丙烯酸酯100質量份、(B)撥水劑0.01~7質量份、及(C)矽烷偶合劑0.01~10質量份且不含無機粒子之塗料所形成；第2硬塗層係由含有(A)多官能(甲基)丙烯酸酯100質量份、及(D)平均粒徑1~300nm之無機微粒子50~300質量份之塗料所形成。該門體亦可於正面之至少一部分具有顯示器。
Abstract in simplified Chinese: 本发明之一态样系一种门体，其系开关物品本体之正面部者，并且具有构成正面之正皮肤、支持正皮肤之外侧端部之至少一部分的框体、及构成背面之背皮肤；正皮肤含有硬涂层积层片材；硬涂层积层片材自正面侧之表层侧起依序具有第1硬涂层、第2硬涂层、及透明树脂片材之层；第1硬涂层系由含有(A)多官能(甲基)丙烯酸酯100质量份、(B)拨水剂0.01~7质量份、及(C)硅烷偶合剂0.01~10质量份且不含无机粒子之涂料所形成；第2硬涂层系由含有(A)多官能(甲基)丙烯酸酯100质量份、及(D)平均粒径1~300nm之无机微粒子50~300质量份之涂料所形成。该门体亦可于正面之至少一部分具有显示器。
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