公开(公告)号：DE10317929A1

公开(公告)日：2004-11-11

申请号：DE10317929

申请日：2003-04-17

Applicant: BASF AG

Inventor： BARTSCH MICHAEL ,  BAUMANN ROBERT ,  HADERLEIN GERD ,  FLORES MIGUEL ,  JUNGKAMP TIM ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  SIEGEL WOLFGANG ,  KUNSMANN-KEITEL DAGMAR PASCALE ,  BASLER PETER

IPC: C01C3/02 ,  C01C3/14

Abstract: A process for dewatering hydrocyanic acid by distillation, which includes distilling crude hydrocyanic acid containing from 50 to 99.9% by weight of HCN, from 0.1 to 40% by weight of water, from 0 to 15% by weight of carbon oxides and optionally from 0.01 to 1% by weight of an involatile stabilizer, at a pressure of from 1 bar to 2.5 bar, a bottom temperature of from 100° C. to 130° C. and a top temperature of from 25° C. to 54° C., in the absence of a volatile stabilizer, in a distillation column to obtain a top draw stream containing purified, anhydrous hydrocyanic acid and carbon oxides and a bottom draw stream including water and, optionally, the involatile stabilizer.

公开(公告)号：CA2522799A1

公开(公告)日：2004-11-04

申请号：CA2522799

申请日：2004-04-16

Applicant: BASF AG

Inventor： JUNGKAMP TIM ,  FLORES MIGUEL ANGEL ,  HADERLEIN GERD ,  BARTSCH MICHAEL ,  BAUMANN ROBERT ,  SCHEIDEL JENS ,  LUYKEN HERMANN ,  KUNSMANN-KEITEL DAGMAR PASCALE ,  SIEGEL WOLFGANG

IPC: C07C253/30 ,  C07C255/07

Abstract: The invention relates to a method for the isomerization of 2-pentenenitrile to form trans-3-pentenenitrile in the presence of aluminium oxide as a catalyst . The invention is characterised in that the BET surface of the aluminium oxid e is at least 50 m2/g.

公开(公告)号：DE10240012A1

公开(公告)日：2004-03-11

申请号：DE10240012

申请日：2002-08-27

Applicant: BASF AG

Inventor： JUNGKAMP TIM ,  SCHEIDEL JENS ,  LUYKEN HERMANN ,  BARTSCH MICHAEL ,  BAUMANN ROBERT ,  HADERLEIN GERD

IPC: C07C253/10 ,  C07C255/07 ,  C07C253/34 ,  C07C253/08

Abstract: A process for the recovery of a Lewis acid from a reaction mixture prepared by hydrocyanation of an olefinically unsaturated compound to form a nitrile that under certain conditions of quantities, pressure and temperature exhibit a miscibility gap with water, in the presence of a catalyst system containing a Lewis acid and a complex compound comprises phase separation and distillation. A process for the recovery of a Lewis acid from a reaction mixture (I), prepared by hydrocyanation of an olefinically unsaturated compound to form a nitrile that under certain conditions of quantities, pressure and temperature exhibit a miscibility gap with water, in the presence of a catalyst system containing a Lewis acid and a complex compound comprising a phosphorous containing ligand and a central atom is characterized in that: (a) the complex compound is separated from the mixture (I) to yield a mixture (II); (b) mixing of the mixture (II) with water under pressure and temperature to form a phase (III) that contains a higher water content than the nitrile and a phase (IV) having a higher nitrile content than water whereby the phase (III) has a higher content of Lewis acid than phase (IV); (c) mixing of the phase (III) with a liquid diluent (V) that does not form an azeotrope with water and whose b.pt. is higher than that of water or under certain conditions of pressure forms an azeotrope or a heteroazeotrope with water; (d) distillation of the mixture of (III) and (V) to yield a mixture (VI) having a higher water content than the diluent (V) and a mixture (VII) having a higher diluent (V) content than water whereby the mixture (VII) has a higher Lewis acid content than the mixture (VI) and; (e) addition of the mixture (VII) to a hydrocyanation of an olefinically unsaturated compound to form a nitrile that under certain conditions of quantities, pressure and temperature exhibit a miscibility gap with water, in the presence of a catalyst system containing a Lewis acid and a complex compound comprising a phosphorous containing ligand and a central atom.

公开(公告)号：DE10207165A1

公开(公告)日：2003-08-21

申请号：DE10207165

申请日：2002-02-20

Applicant: BASF AG

Inventor： BARTSCH MICHAEL ,  BAUMANN ROBERT ,  KUNSMANN-KEITEL DAGMAR PASCA ,  HADERLEIN GERD ,  JUNGKAMP TIM ,  ALTMAYER MARCO ,  SIEGEL WOLFGANG ,  MOLNAR FERENC

IPC: B01J31/12 ,  C07C253/10 ,  C07C253/30 ,  C07C255/04 ,  C07C255/07 ,  C07F9/48 ,  C07F15/04

Abstract: Novel phosphonite compounds are claimed. Phosphonite compounds (I) of formula (1) or (2) are claimed as are processes for their production, their use as ligands in transition metal complexes, novel transition metal complexes, processes for their production, their use as catalysts and processes in the presence of such transition metal complexes as catalysts. R1,R2,R5-R9 = H, 1-8C alkyl, alkenyl or alkoxy; R3 = H or methyl; R4 = i-propyl or t-butyl; X = F, Cl or CF3 n = 1 or 2 Independent claims are included for: (1) Transition metal complexes (II) containing a phosphonite ligand of formula (1) or (2). (2) Processes for the production of transition metal complexes by reaction of a transition metal or tranisition metal compound with a phosphonite of formula (1) or (2). (3) A process for the addition of hydrocyanic acid to an olefinic double bond in the presence of a catalyst comprising a transition metal complex (II). (4) A process for the isomerization of organic nitriles in the presence of a catalyst comprising a complex (II).

公开(公告)号：DE10156292A1

公开(公告)日：2003-05-28

申请号：DE10156292

申请日：2001-11-19

Applicant: BASF AG

Inventor： BARTSCH MICHAEL ,  BAUMANN ROBERT ,  KUNSMANN-KEITEL DAGMAR PASCA ,  HADERLEIN GERD ,  JUNGKAMP TIM ,  ALTMAYER MARCO ,  SIEGEL WOLFGANG

IPC: C07F9/48

Abstract: Preparation of organodiphosphonites comprises reaction of one mole of an organo phosphorous chloride with one mole of an alcohol in the absence of an organic base at -25 to +10 deg C, treatment of the product with at least one equivalent of an organic base, and addition of a (hetero)aryl diol. A process for the production of organodiphosphonites of formula (I) comprises: (a) reaction of one mole of R PCl2 with one mole of R OH in the absence of an organic base at -25 to +10 deg C; (b) treatment of the product from step (a) with at least one equivalent of an organic base (with respect to (w.r.t.) R PCl2) to yield (R -O)R PCl and an essentially insoluble salt of the organic base with HCl, at -25 to +10 deg C; and (c) reaction of (R -O)R PCl) with a compound HO-Z-OH, where in the case that less than two equivalents of base were added in step (b), further base is added in an amount such that at least two equivalents (w.r.t. one mole of R PCl2) are added in steps (a), (b) and (c) at -25 to +10 deg C. (R -O)R P-O-Z-O-PR (O-R ) (I) R , R = optionally substituted aryl, heteroaryl, 4-8C cycloalkyl or 1-10C alkyl; Z = optionally substituted arylene, heteroarylene, 4-8C cycloalkylene or 1-10C alkylene.

公开(公告)号：DE10150281A1

公开(公告)日：2003-04-30

申请号：DE10150281

申请日：2001-10-12

Applicant: BASF AG

Inventor： BARTSCH MICHAEL ,  BAUMANN ROBERT ,  KUNSMANN-KEITEL DAGMAR PASCA ,  HADERLEIN GERD ,  JUNGKAMP TIM ,  ALTMAYER MARCO ,  SIEGEL WOLFGANG ,  MOLNAR FERENC

IPC: B01J31/18 ,  C07C253/10 ,  C07C255/04 ,  C07C255/07 ,  C07F9/48 ,  C07F15/04 ,  B01J31/12 ,  C07C253/30 ,  C07C255/06

Abstract: Novel phosphonite compounds are claimed. Phosphonite compounds (I) of formula (1) or (2) are claimed as are processes for their production, their use as ligands in transition metal complexes, novel transition metal complexes, processes for their production, their use as catalysts and processes in the presence of such transition metal complexes as catalysts. R ,R ,R -R = H, 1-8C alkyl, alkenyl or alkoxy; R = H or methyl; R = i-propyl or t-butyl; X = F, Cl or CF3 n = 1 or 2 Independent claims are included for: (1) Transition metal complexes (II) containing a phosphonite ligand of formula (1) or (2). (2) Processes for the production of transition metal complexes by reaction of a transition metal or tranisition metal compound with a phosphonite of formula (1) or (2). (3) A process for the addition of hydrocyanic acid to an olefinic double bond in the presence of a catalyst comprising a transition metal complex (II). (4) A process for the isomerization of organic nitriles in the presence of a catalyst comprising a complex (II).

公开(公告)号：CA2389608A1

公开(公告)日：2001-05-25

申请号：CA2389608

申请日：2000-10-25

Applicant: BASF AG

Inventor： BAUMANN ROBERT ,  SIEGEL WOLFGANG ,  FISCHER JAKOB ,  KUNSMANN-KEITEL DAGMAR PASCALE ,  JUNGKAMP TIM

IPC: B01J31/22 ,  B01J31/02 ,  B01J31/18 ,  C07B61/00 ,  C07C253/10 ,  C07C253/30 ,  C07C255/03 ,  C07C255/07 ,  C07C255/19 ,  C07F9/145 ,  C07F15/04

Abstract: The invention relates to phosphites of the formula (I) P (O-R1)x (O-R2)y (O- R3)z (O-R4)p where R1= an aromatic group with a C1-C18-alkyl substituent ort ho to the O atom, or an aromatic substituent ortho to the O atom, or a fused aromatic system ortho to the O atom; R2= an aromatic group with a C1-C18 alk yl substituent meta to the O atom, or an aromatic substituent meta to the O ato m, or a fused aromatic system meta to the O atom, whereby the aromatic residue ortho to the O atom has a hydrogen atom; R3 = an aromatic group with a C1-C1 8 alkyl substituent para to the O atom, or an aromatic substituent para to the O atom, whereby the aromatic group ortho to the O atom has a hydrogen atom; R4 = an aromatic group with substituents ortho, meta and para to the o atom which are different to those defined for R1, R2 and R3, whereby the aromatic group ortho to the O atom has a hydrogen atom; x = 1 or 2; y, z and p, independent of each other = 0, 1 or 2 with the proviso, that x+y+z+p =3.

公开(公告)号：BRPI0507193B1

公开(公告)日：2015-07-07

申请号：BRPI0507193

申请日：2005-01-27

Applicant: BASF AG

Inventor： BARTSCH MICHAEL ,  BAUMANN ROBERT ,  HADERLEIN GERD ,  SCHEIDEL JENS ,  JUNGKAMP TIM ,  LUYKEN HERMANN

IPC: C07C253/10 ,  C07C255/07

公开(公告)号：ES2284977T3

公开(公告)日：2007-11-16

申请号：ES02801302

申请日：2002-10-01

Applicant: BASF AG

Inventor： BARTSCH MICHAEL ,  BAUMANN ROBERT ,  KUNSMANN-KEITEL DAGMAR PASCALE ,  HADERLEIN GERD ,  JUNGKAMP TIM ,  ALTMAYER MARCO

IPC: B01J31/18 ,  B01J31/22 ,  C07B61/00 ,  C07C253/10 ,  C07C253/30 ,  C07C255/04 ,  C07C255/07 ,  C07F9/48

Abstract: Fosfonito I de la fórmula 1 o la fórmula 2 Fórmula 1 Fórmula 2 en donde R1, R2 significan, independientemente, hidrógeno, un grupo alquilo o alquileno con 1 a 8 átomos de carbono, o un grupo alcoxi con 1 a 8 átomos de carbono, con la condición de que R1 y R2 no signifiquen simultáneamente H R3 significa H o metilo, R4 t-butilo, R5, R6, R7, R8, R9 significan, independientemente, H o un grupo alquilo o alquileno con 1 a 8 átomos de carbono.

公开(公告)号：ES2284020T3

公开(公告)日：2007-11-01

申请号：ES04739502

申请日：2004-06-02

Applicant: BASF AG

Inventor： FLORES MIGUEL ANGEL ,  BARTSCH MICHAEL ,  BAUMANN ROBERT ,  HADERLEIN GERD ,  JUNGKAMP TIM ,  SCHEIDEL JENS

IPC: C07C37/60 ,  C07C37/11 ,  C07C39/15

Abstract: Procedimiento para la obtención de un 2, 2''-dihidroxibifenilo mediante copulado por oxidación de dos moléculas de fenol, que presentan un átomo de hidrógeno en una posición o, por medio de un peróxido en presencia de agua a una temperatura en el intervalo de 0ºC a 100ºC, caracterizado porque la obtención se lleva a cabo en presencia de un polímero insoluble en agua, que contiene a) un 0, 1 a un 99, 9 % en peso de al menos un heterocíclico vinílico, b) un 0, 1 a un 10 % en peso de al menos un componente reticulante difuncional, c) un 0 a un 99, 8 % en peso de estireno, o al menos un derivado de estireno monoinsaturado, o sus mezclas, sumándose los datos de % en peso de componentes aislados a), b) y c) para dar un 100 %.