PIPERAZINE COMPOUNDS WITH A HERBICIDAL ACTION

    公开(公告)号:HRP20100077T1

    公开(公告)日:2010-04-30

    申请号:HRP20100077

    申请日:2010-02-15

    Applicant: BASF SE

    Abstract: The present invention relates to piperazine compounds of the general formula I defined below and to their use as herbicides. Moreover, the invention relates to compositions for crop protection and to a method for controlling unwanted vegetation. R1 is selected from the group consisting of halogen, cyano, nitro, Z—C(═O)—R12, phenyl and a 5- or 6-membered heterocyclic radical which has 1, 2, 3 or 4 heteroatoms selected from the group consisting of O, N and S as ring atoms, where phenyl and the heterocyclic radical are unsubstituted or may have 1, 2, 3 or 4 substituents R1a; Z is a covalent bond or a CH2 group; R12 is hydrogen, C1-C6-alkyl, C3-C6-cycloalkyl, C2-C6-alkenyl, C5-C6-cycloalkenyl, C2-C6-alkynyl and the like; R2 is hydrogen, halogen, nitro, cyano, C1-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, C1-C4-alkoxy, C1-C4-haloalkoxy, benzyl or a group S(O)nR21 in which R21 is C1-C4-alkyl or C1-C4-haloalkyl and n is 0, 1 or 2; R3 is hydrogen or halogen; R4 is C1-C4-alkyl, C3-C4-alkenyl or C3-C4-alkynyl; R5 is hydrogen, C1-C4-alkyl, C3-C4-alkenyl, C3-C4-alkynyl or a group C(═O)R51 in which R51 is hydrogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy or C1-C4-haloalkoxy; R6 is C1-C4-alkyl, C1-C4-hydroxyalkyl or C1-C4-haloalkyl; R7, R8 independently of one another are hydrogen, OH, C1-C4-alkoxy, C1-C4-haloalkyloxy, C1-C4-alkyl or C1-C4-haloalkyl; R9, R10 independently of one another are selected from the group consisting of hydrogen, halogen, CN, NO2, C1-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, C1-C4-alkoxy and C1-C4-haloalkoxy; and R11 is hydrogen or C1-C4-alkyl; and the agriculturally useful salts of these compounds.

    Piperazine compounds with a herbicidal action

    公开(公告)号:AU2008263902A1

    公开(公告)日:2008-12-18

    申请号:AU2008263902

    申请日:2008-06-11

    Applicant: BASF SE

    Abstract: The present invention relates to piperazine compounds of the general formula I defined below and to their use as herbicides. Moreover, the invention relates to compositions for crop protection and to a method for controlling unwanted vegetation. In formula I, the variables have the following meanings: R1 is selected from the group consisting of halogen, cyano, nitro, Z—C(═O)—R11, phenyl and a 5- or 6-membered heterocyclic radical which has 1, 2, 3 or 4 heteroatoms selected from the group consisting of O, N and S as ring atoms, where phenyl and the heterocyclic radical are unsubstituted or may have 1, 2, 3 or 4 substituents R1a; Z is a covalent bond or a CH2 group; R11 is hydrogen, C1-C6-alkyl, C3-C6-cycloalkyl, C2-C6-alkenyl, C5-C6-cycloalkenyl, C2-C6-alkynyl and the like; R2 is hydrogen, halogen, nitro, cyano, C1-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, C1-C4-alkoxy, C1-C4-haloalkoxy, benzyl or a group S(O)nR21 in which R21 is C1-C4-alkyl or C1-C4-haloalkyl and n is 0, 1 or 2; R3 is hydrogen or halogen; R4 is C1-C4-alkyl, C3-C4-alkenyl or C3-C4-alkynyl; R5 is hydrogen, C1-C4-alkyl, C3-C4-alkenyl, C3-C4-alkynyl or a group C(═O)R51 in which R51 is hydrogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy or C1-C4-haloalkoxy; R6 is C1-C4-alkyl, C1-C4-hydroxyalkyl or C1-C4-haloalkyl; R7, R8 independently of one another are hydrogen, OH, C1-C4-alkoxy, C1-C4-haloalkyloxy, C1-C4-alkyl or C1-C4-haloalkyl; and R9, R10 independently of one another are selected from the group consisting of hydrogen, halogen, CN, NO2, C1-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, C1-C4-alkoxy and C1-C4-haloalkoxy.

    Piperazine compounds with a herbicidal action

    公开(公告)号:AU2008263901A1

    公开(公告)日:2008-12-18

    申请号:AU2008263901

    申请日:2008-06-11

    Applicant: BASF SE

    Abstract: The present invention relates to piperazine compounds of the general formula I defined below and to their use as herbicides. Moreover, the invention relates to compositions for crop protection and to a method for controlling unwanted vegetation. R1 is selected from the group consisting of halogen, cyano, nitro, Z—C(═O)—R12, phenyl and a 5- or 6-membered heterocyclic radical which has 1, 2, 3 or 4 heteroatoms selected from the group consisting of O, N and S as ring atoms, where phenyl and the heterocyclic radical are unsubstituted or may have 1, 2, 3 or 4 substituents R1a; Z is a covalent bond or a CH2 group; R12 is hydrogen, C1-C6-alkyl, C3-C6-cycloalkyl, C2-C6-alkenyl, C5-C6-cycloalkenyl, C2-C6-alkynyl and the like; R2 is hydrogen, halogen, nitro, cyano, C1-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, C1-C4-alkoxy, C1-C4-haloalkoxy, benzyl or a group S(O)nR21 in which R21 is C1-C4-alkyl or C1-C4-haloalkyl and n is 0, 1 or 2; R3 is hydrogen or halogen; R4 is C1-C4-alkyl, C3-C4-alkenyl or C3-C4-alkynyl; R5 is hydrogen, C1-C4-alkyl, C3-C4-alkenyl, C3-C4-alkynyl or a group C(═O)R51 in which R51 is hydrogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy or C1-C4-haloalkoxy; R6 is C1-C4-alkyl, C1-C4-hydroxyalkyl or C1-C4-haloalkyl; R7, R8 independently of one another are hydrogen, OH, C1-C4-alkoxy, C1-C4-haloalkyloxy, C1-C4-alkyl or C1-C4-haloalkyl; R9, R10 independently of one another are selected from the group consisting of hydrogen, halogen, CN, NO2, C1-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, C1-C4-alkoxy and C1-C4-haloalkoxy; and R11 is hydrogen or C1-C4-alkyl; and the agriculturally useful salts of these compounds.

    Uracilpiridina herbicida
    118.
    发明专利

    公开(公告)号:ES2900867T3

    公开(公告)日:2022-03-18

    申请号:ES17724093

    申请日:2017-05-22

    Applicant: BASF SE

    Abstract: Uracilpiridinas de fórmula (I) **(Ver fórmula)** donde las variables tienen los siguientes significados: R1 hidrógeno, NH2, alquilo-C1-C6 o alquinilo-C3-C6; R2 hidrógeno, alquilo-C1-C6 o haloalquilo-C1-C6; R3 hidrógeno o alquilo-C1-C6; R4 H o halógeno; R5 halógeno, CN, NO2, NH2, CF3 o C(=S) NH2; R6 H, halógeno, CN, alquilo-C1-C3, haloalquilo-C1-C3, alcoxi-C1-C3, haloalcoxi-C1-C3, alquiltio-C1-C3, (alquilo-C1-C3) amino, di(alquilo-C1-C3)amino, alcoxi-C1-C3- alquilo-C1-C3, alcoxicarbonilo-C1-C3; R7 H, halógeno, alquilo-C1-C3, alcoxi-C1-C3; R8 OR9, SR9, NR10R11, NR9O9, NR9S(O)2R10 o NR9S(O)2NR10R11, en donde R9 es hidrógeno, alquilo-C1-C6, alquenilo-C3-C6, alquinilo-C3-C6, haloalquilo-C1-C6, haloalquenilo-C3-C6, haloalquinilo-C3- C6, cianoalquilo-C1-C6, alcoxi-C1-C6-alquilo-C1-C6, alcoxi-C1-C6-alcoxi-C1-C6-alquilo-C1-C6, di(alcoxi-C1-C6)-alquilo- C1-C6, haloalcoxi- C1-C6-alquilo-C1-C6, alqueniloxi-C3-C6-alquilo-C1-C6, haloalqueniloxi-C3-C6-alquilo-C1-C6, alqueniloxi-C3-C6- alcoxi-C1-C6 alquilo-C1-C6, alquiltio-C1-C6-alquilo-C1-C6, alquilsulfinilo-C1-C6 alquilo-C1-C6, alquilsulfonil-C1-C6-alquilo-C1- C6, alquilcarbonil-C1-C6-alquilo-C1-C6, alcoxicarbonilo-C1-C6-alquilo-C1-C6, haloalcoxicarbonil-C1-C6-alquilo-C1-C6, alqueniloxicarbonil-C3-C6 alquilo-C1-C6, alquiniloxicarbonil-C3-C6-alquilo-C1-C6, amino, (alquilo-C1-C6) amino, di(alquilo- C1-C6)amino, (alquilcarbonil-C1-C6) amino, amino- alquilo-C1-C6, (alquilo-C1-C6) amino-alquilo-C1-C6, di(alquilo-C1- C6)amino-alquilo-C1-C6, aminocarbonilo-alquilo-C1-C6, (alquilo-C1-C6) aminocarbonil- alquilo-C1-C6, di(alquilo-C1-C6) aminocarbonil-alquilo-C1-C6, -N = CR12R13, donde R12 y R13 independientemente entre sí son H, alquilo-C1-C4 o fenilo; cicloalquilo-C3-C6, cicloalquilo-C3-C6-alquilo-C1-C6, heterociclilo-C3-C6, heterociclilo-C3-C6-alquilo-C1-C6, fenilo, fenilo- alquilo-C1-C4 o un heteroarilo de 5 o 6 miembros, en donde cada anillo de cicloalquilo, heterociclilo, fenilo o heteroarilo puede estar sustituido con uno a cuatro sustituyentes seleccionados de R14 o un carbociclo de 3 a 7 miembros, cuyo carbociclo tiene opcionalmente además de los átomos de carbono uno o dos miembros del anillo seleccionados del grupo que consiste en -N(R12)-, -N = N-, -C (=O) -O- y -S-, y cuyo carbociclo está opcionalmente sustituido con uno a cuatro sustituyentes seleccionados de R14; donde R14 es halógeno, NO2, CN, alquilo-C1-C4, haloalquilo-C1-C4, alcoxi-C1-C4 o alcoxicarbonilo-C1-C4; R10, R11 independientemente el uno del otro son R9, o juntos forman un carbociclo de 3 a 7 miembros, cuyo carbociclo tiene opcionalmente además de los átomos de carbono uno o dos miembros del anillo seleccionados del grupo que consiste en -N(R12)-, -N=N-, -C(=O) -, -O- y -S-, y qué carbociclo está opcionalmente sustituido con uno a cuatro sustituyentes seleccionados de R14; n 1 to 3; Q CH2, O, S, SO, SO2, NH o (alquilo-C1-C3)N; W O o S; X NH, NCH3, 0 o S; Y O o S Z fenilo, piridilo, piridazinilo, pirimidinilo o pirazinilo, cada uno de los cuales está opcionalmente sustituido con 1 a 4 sustituyentes seleccionados del grupo que consiste en halógeno, CN, alquilo-C1-C6, haloalquilo-C1-C6, alcoxi-C1-C6, haloalcoxi-C1-C6; incluyendo sus sales, amidas, ésteres o tioésteres agrícolas aceptables, siempre que los compuestos de fórmula (I) tengan un grupo carboxilo.

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