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公开(公告)号:DE3877654D1
公开(公告)日:1993-03-04
申请号:DE3877654
申请日:1988-08-06
Applicant: BASF AG
Inventor: SEILER ERHARD DR , MCKEE GRAHAM EDMUND DR , SCHARF BERNHARD DR
Abstract: Reinforced thermoplastic moulding compsn. consists of (A) 40-94 (wt.) copolymer of (a1) 90-50% styrene (IA), alpha-methylstyrene (IB) and/or a ring alkyl-substd. styrene deriv. (IC) and (a2) 10-50% (meth)acrylonitrile (IIA) and/or methyl (meth)acrylate (IIB), (B) 20-0.5% terpolymer of (B1) 90-50% (I), (b2) 5-40% (II) and (b3) 2-30% of another monomer (III) and (C) 5-50% reinforcement (IV). The novelty is that (III) is t-butyl (meth)acrylate. The compsn. may also contain, w.r.t. A + B + C, (D) 1-50% graft copolymer(s) of (d1) 50-90% tubber(s) with Tg below 0 deg.C, (d2) 10-49% vinyl-aromatic monomer(s) with max. 12C atoms and (d3) 49-1% (IIA) and/or 1-8C-alkyl (meth)acrylate(s); and/or (E) up to 20% usual additives. The pref. compsn. is (A) 50-87% copolymer of 80-60% (I) and 20-40% (II), (B) 10-0.5% terpolymer of 90-50% (I), 5-40% (II) and 5-15% (III) and (C) 15-40% (IV); partic. (A) 55-65% copolymer of 80-20% (IA) and 20-40% acrylontrile (IIA-1), (B) 10-0.5% terpolymer of 85-60% (IA), (IIA-1) and 5-15% (III) and (C) 20-40% glass fibres.
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公开(公告)号:DE3778267D1
公开(公告)日:1992-05-21
申请号:DE3778267
申请日:1987-08-20
Applicant: BASF AG
Inventor: MITULLA KONRAD DR , OSTERMAYER BERTRAM DR , SEILER ERHARD DR , SCHMITT BURGHARD PROF DR , HAMBRECHT JUERGEN DR , SIEBEL HANS PETER DR
IPC: C08F279/02 , C08F285/00 , C08L25/02 , C08L25/12 , C08L51/04 , C08L55/02
Abstract: Compsns. (I) contain, on wt. (all pts. wt.) A + B + C A) 3-40% at least one graft mixed polymer B) 7-70% at least one further graft mixed polymer C) 20-90% copolymer of at least one 8-12C vinyl aromatic monomer (II) and at least one monoethylenically unsatd. monomer (III). A comprises a1) 50-80%, on A, elastomer based on polybutadiene or butadiene copolymer as core polymer and a2) 20-50%, on A, shell polymer, average particle size 0.2-1 micron (d50 value of integral mass distribution), made in 2 stages from at least one (II) and at least one (III) by grafting in first stage only (II) in amt. of 5-50% a2) then, in presence of this prod., grafting in second stage 50-95% mixt. of (II) and (III) in ratio 90:10-60:40. B comprises b1) 40-70%, on B, elastomer based on homopolybutadiene.
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公开(公告)号:DE3869261D1
公开(公告)日:1992-04-23
申请号:DE3869261
申请日:1988-07-21
Applicant: BASF AG
Inventor: TAUBITZ CHRISTOF DR , SCHLEMMER LOTHAR , SEILER ERHARD DR , BOEHLKE KLAUS DR , GAUSEPOHL HERMANN DR
IPC: C08F257/02 , C08F283/08
Abstract: Practically uncrosslinked graft polymers (I) consist of (A) a base polymer of 40-100(wt.)% polyphenylene ether and 0-60% vinyl-aromatic polymer, (B) a monomer with a C=C double bond, in which the double bond C atoms are substd. by only one CO gp. and (C) opt. other olefinically unsatd. monomers. The novelty is that (B) also contains 2 CO gps. linked through a C=C double bond, with the structure (i). Pref. (B) is mono-2-acryloxyethyl maleate (B1) or mono-2-methacryloxyethyl maleate (B2). The graft polymer contains 80-99.9, pref. 90-99.9% (A), 0.1-20, pref. 0.1-10% (B) and 0-20, pref. 0% (C). Graft polymerisation is carried out at 170-350 deg.C (practically) in the absence of a free radical initiator.
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公开(公告)号:DE3676413D1
公开(公告)日:1991-02-07
申请号:DE3676413
申请日:1986-08-21
Applicant: BASF AG
Inventor: SEILER ERHARD DR , MCKEE GRAHAM EDMUND DR , THEYSOHN RAINER DR
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125.
公开(公告)号:AT47686T
公开(公告)日:1989-11-15
申请号:AT86100543
申请日:1986-01-17
Applicant: BASF AG
Inventor: SEILER ERHARD DR , KAISER UWE , WELZ MARTIN , GIESEN KLAUS , THEYSOHN RAINER DR , SCHLAG JOHANNES DR , GRZESITZA JOHANNES
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公开(公告)号:DE3571246D1
公开(公告)日:1989-08-03
申请号:DE3571246
申请日:1985-10-18
Applicant: BASF AG
Inventor: TAUBITZ CHRISTOF DR , SEILER ERHARD DR , HAMBRECHT JUERGEN DR , BLINNE GERD DR
IPC: C08G81/02
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公开(公告)号:DE3760218D1
公开(公告)日:1989-07-13
申请号:DE3760218
申请日:1987-03-20
Applicant: BASF AG
Inventor: KOCK HANS-JAKOB DR , SEILER ERHARD DR , ERHARD GUNTER DR
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公开(公告)号:DE3733857A1
公开(公告)日:1989-04-27
申请号:DE3733857
申请日:1987-10-07
Applicant: BASF AG
Inventor: LAUSBERG DIETRICH DR , SEYDL WOLFGANG DR , KNOLL MANFRED , SEILER ERHARD DR , GUTSCHE HERBERT , KOLM PETER
Abstract: Thermoplastic molding composition based on thermoplastic polyesters (a1), graft polymers incorporating acrylate rubbers as grafting base (a2), copolymers of aromatic vinyl monomers and acrylonitrile or methacrylonitrile (a3) and glass fibers (B) have particularly good mechanical properties if the (meth)acrylonitrile content in component (a3), based on the total weight of (a3), is less than the (meth)acrylonitrile content of component (a22).
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129.
公开(公告)号:DE3733839A1
公开(公告)日:1989-04-20
申请号:DE3733839
申请日:1987-10-07
Applicant: BASF AG
Inventor: SEILER ERHARD DR , LAUSBERG DIETRICH DR , GUTSCHE HERBERT , KNOLL MANFRED
Abstract: Thermoplastic moulding compositions based on thermoplastic polyesters (a1), graft polymers with acrylate rubbers having a bimodal particle-size distribution as graft base (a2), copolymers of vinylaromatic monomers and acrylonitrile or methacrylonitrile (a3), polymeric components containing carboxyl, carboxyl derivative, hydroxyl or epoxy groups (B) and glass fibres (C) exhibit a balanced property profile.
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公开(公告)号:DE3732529A1
公开(公告)日:1989-04-06
申请号:DE3732529
申请日:1987-09-26
Applicant: BASF AG
Inventor: TAUBITZ CHRISTOF DR , SEILER ERHARD DR , THEYSOHN RAINER DR , RUPPMICH KARL
IPC: C08F285/00 , C08L51/00 , C08L77/00
Abstract: Thermoplastic moulding compositions comprising A) from 31 to 95 parts by weight of an ABS and/or ASA polymer, of which at least 10% by weight of the ABS and/or ASA polymer from A has been modified by reaction in the melt with a monoethylenically unsaturated compound X containing an amide or imide group, B) from 5 to 65 parts by weight of polyamide, C) from 0 to 40 parts by weight of an impact modifier and D) conventional additives in conventional amounts, where the parts by weight are based on 100 parts by weight of the total of A, B, C and D, their preparation and their use.
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