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    BENCILHIDROXILAMINAS Y PRODUCTOS INTERMEDIOS PARA SU PREPARACION.
    122.
    发明专利
    BENCILHIDROXILAMINAS Y PRODUCTOS INTERMEDIOS PARA SU PREPARACION. 未知

    公开(公告)号：MX9800081A

    公开(公告)日：1998-11-29

    申请号：MX9800081

    申请日：1998-01-07

    Applicant: BASF AG

    Inventor： KLINTZ RALF ,  HAMPRECHT GERHARD ,  HEISTRACHER ELISABETH ,  SCHAEFER PETER ,  ZAGAR CYRILL ,  WESTPHALEN KARL-OTTO ,  WALTER HELMUT ,  MISSLITZ ULF ,  MENKE OLAF

    IPC: A01N43/54 ,  A01N47/12 ,  A01N47/24 ,  A01N47/30 ,  A01N53/00 ,  C07C239/08 ,  C07C239/10 ,  C07C239/16 ,  C07C239/20 ,  C07C265/12 ,  C07C271/22 ,  C07C271/28 ,  C07C271/54 ,  C07C271/58 ,  C07C275/32 ,  C07C275/40 ,  C07D239/54 ,  C07D405/12

    Abstract: Bencilhidroxilamina I: ver formula (I): (x = -N(R7)-O-; Y = O, S; R1 = halogeno, CN, NO2, CF3; R2 = H, halogeno ; R3 = H, NH2, CH3; R4 ¿ H, halogeno, alquilo C1-C6, haloalquilo C1-C6, alquiltio C1-C6, alquilsulfinilo C1-C6 o bien alquilsulfonilo C1-C6; R5 = H, halogeno, alquilo C1-C6; R6 = H, alquilo C1-C6, haloalquilo C1-C6, cicloalquilo C3-C6, alquenilo C2-C6; R7 = H, alquilo C1-C6, cicloalquilo C3-C8, haloalquilo C1-C6, alquenilo C3-C6, alquinilo C3-C6, alquilcarbonilo C1-C6, alquenilcarbonilo C3-C6, alquinilcarbonilo C3-C6, alcoxicarbonilo C1-C6, alqueniloxicarbonilo C2-C8, alquiniloxicarbonilo C2-C6, alquiltiocarbonilo C1-C6, alquilsulfonilo C1-C6, alquilcarbamoilo C1-C6, siendo posible que los 14 radicales mencionados en ultima instancia tengan fijados sobre ellos 1-3 sustituyentes: -NO2, CN, halogeno, cicloalquilo C3-C8, OH, alcoxi C1-C6, cicloalcoxi C3-C8, alqueniloxi C3-C6, alquiniloxi C3-C6, alcoxi C1-C6-alcoxi C1-C6, alquiltio C1-C6, alquilcarbonilo C1-C6, alquilcarboniloxi C1-C6, alquilsulfinilo C1-C6, alquilsulfonilo C1-C6, alquilidenaminoxi C1-C6, alquilacarbamoilo C1-C6, -fenilo, fenoxi, o bien fenilsulfonilo no sustituido o bien sustituido, -un grupo de heterociclilo o heterocicliloxi de 3 a 7 miembros que tiene 1-3 heteroátomos, siendo posible que este grupo esté saturado, insaturado o bien aromático y tenga fijado sobreél 1-3 sustituyentes; --CO-Z1R9, -OCO-Z1R9, -N(R9)R10 o bien R7 = cicloalquilcarbonilo, fenilcarbonilo, fenilsulfonilo, fenilcarbamoilo sustituido o no sustituido; R8 = H, alquilo C1-C6, cicloalquilo C3-C8, haloalquilo C1-C6, alquenilo C3-C6 o bien alquinilo, C3-C6, siendo posible que cada uno de los 5 radicales mencionados en ultima instancia tengan fijados sobre ellos 1-3 sustituyentes: -NO2, CN, halogeno, cicloalquilo C3-C8, OH, alcoxi C1-C6, cicloalcoxi C3-C8, alqueniloxi C3-C6, alquiniloxi C3-C6, alcoxi C1-C6-alcoxi C1-C6, alquiltio C1-C6, alquilsulfinilo C1-C6, alquilsulfonilo C1-C6, alquilidenaminoxi C1-C6, - fenil- (sic), fenoxi- (sic) o bien fenilsulfonilo sustituido o no sustituido, - un grupo de heterociclilo o heterocicliloxi de 3 a 7 miembros que tiene 1-3 heteroátomos, siendo posible que este grupo este saturado, insaturado o bien aromático y tenga fijado sobre el 1-3 sustituyentes. - -CO-Z2R11, -OCO-Z2R11, -N(R11)R12; irais Z1 es un enlace químico, oxígeno, azufre o bien -N(R10)-; Z2 es un enlace químico, oxígeno, azufre o bien -N(R12)-; R9, R11, alquilo C1-C6, haloalquilo C1-C6, cicloalquilo C3-C8, alquenilo C3-C6, alquinilo C3-C6, alcoxi C1-C6-alquilo C1-C6, (alcoxi C1-C6)carbonilalquilo C1-C6, fenilo o bien fenilalquilo C1-C6, sustituido o no sustituido o bien Z1 y R9 y/o R11 juntos = un heterociclo de 3 a 7 miembros que tiene de 1 a 3 heteroátomos y unido a través de nitrogeno, siendo posible que el heterociclo esté saturado, parcial o totalmente insaturado o bien aromático y, si se desea, tenga fijado sobre él de 1 a 3 sustituyentes, R10, R12 = H, OH, alquilo C1-C6, cicloalquilo C3-C8, alcoxi C1-C6 y las sales de I donde R3, R7 y/o R8 = hidrogeno se emplean como herbicidas y para la desecacion/defoliacion de plantas.

    SUBSTITUTED 2-BENZ(O)YLPYRIDINES, THEIR PREPARATION AND THEIR USE AS HERBICIDES
    123.
    发明专利
    SUBSTITUTED 2-BENZ(O)YLPYRIDINES, THEIR PREPARATION AND THEIR USE AS HERBICIDES 未知

    公开(公告)号：CA2283981A1

    公开(公告)日：1998-10-01

    申请号：CA2283981

    申请日：1998-03-09

    Applicant: BASF AG

    Inventor： WALTER HELMUT ,  HAMPRECHT GERHARD ,  SCHAEFER PETER ,  MENGES MARKUS ,  MISSLITZ ULF ,  ZAGAR CYRILL ,  WESTPHALEN KARL-OTTO ,  RACK MICHAEL ,  MENKE OLAF

    IPC: A01N43/40 ,  C07D213/61 ,  C07D401/12 ,  C07D405/12

    Abstract: Substituted 2-benz(o)ylpyridines of formula (I) and the salts thereof, wherein n = 0, 1; x = CO, CH2, CH(C1-C4-alkyl), CH-OH, CH-CN, CH-halogen, C(halogen)2, CH-CONH2, CH-CO-O(C1-C4-alkyl), CH-O(C1-C4-alkyl), C(CN) (C1-C4-alkyl); R1 = halogen, C1-C4-halogen alkane, C1-C4-alkylthio, C1-C4-alkyl sulfinyl, C1-C4-alkyl sulfonyl; R2 = H, halogen; R3 = H, NO2, OH, halogen, C1-C4-alkoxy; R4 = H, NO2, OH, halogen, C1-C4-alkyl, C1-C4 halogen alkane, C1-C4-alkoxy; R5 = H, NO2, CN, halogen, C1-C8-alkyl, C3-C8-alkenyl,C3-C8-alkinyl, C3-C8-cycloalkyl, C1-C8-halogen alkane, C2-C8-halogen alkenyl, C2-C8-halogen alkane, C1-C4-alkoxy-C1-C4-alkyl, C2-C4-alkenyloxy-C1-C4-alkyl, C2-C4-alkinyloxy-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkyl, C1-C4-alkylsulfinyl-C1-C4-alkyl, C1-C4-alkylsulfonyl-C1-C4-alkyl, cyano-C1-C8-alkyl, cyano-C2-C8-alkenyl, cyano-C3-C8-alkinyl, optionally substituted OH, SH, SO-H, -SO2-H, COOH or NH-COOH, -SO2Cl, -N(R9, R10), -NH-SO2-(C1-C8-alkyl), -N¢-SO2-(C1-C8-alkyl)!2, -N(C1-C8-alkyl) ¢SO2-(C1-C8-alkyl)!, -SO2-N(R9, R10), -O-CO-NH-R9, optionally substituted CHO, O-CHO or -NH-CHO, NH-CO-NH-R9, -O-CS-NH2, -OCS-N(C1-C8-alkyl)2, -CO-N(R9, R10), -CS-N (R9, R10), -CO-NH-SO2-(C1-C4-alkyl), -CO-N(C1-C4-alkyl), -SO2-(C1-C4-alkyl), hydroxycarbonyl-C1-C8-alkyl, (C1-C8-alkoxy)carbonyl-C1-C6-alkyl, CH2-CH(halogen)-CO-N(R9, R10), -CH2-CH(halogen)-CN, -CH2-CH(halogen)-CO-(C1-C4-alkyl), optionally substituted -CH2-CH(halogen-COOH, -CH=C(halogen)-COOH or CH=C(C1-C4-alkyl)-COOH, optionally substituted -CH=N-OH or -CH(-Y-R15, -Z-R15), (II) or (III); R9, R10 = H, C1-C8-alkyl, C3-C8-cycloalkyl, C2-C8-alkenyl, C3-C8-alkinyl, C1-C8-halogen alkane, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkyl, C1-C4-alkylsulfinyl-C1-C4-alkyl, C1-C4-alkylsulfonyl-C1-C4-alkyl, cyano-C1-C8-alkyl, hydroxycarbonyl-C1-C4-alkyl, (C1-C4-alkoxy)carbonyl-C1-C4-alkyl, (C3-C6-cycloalkoxy)carbonyl-C1-C4-alkyl, (C1-C4-alkoxy)carbonyl-C3-C7-cycloalkyl, C1-C4-alkoxy-(C1-C4)alkoxy)-carbonyl-C1-C4-alkyl, C1-C6-alkoxy, optionally substituted phenyl or phenyl-C1-C4-alkyl or R9 + R10 together = optionally substituted tetramethylene, pentamethylene or ethylene oxyethylene chain; Y, Z = O, S; R15 = C1-C8-alkyl, C1-C8 halogen alkane, C1-C4-alkoxy-C1-C4-alkyl; R16-R21 = H, CN, C1-C8-alkyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C8-alkoxy, C1-C4-alkoxy-C1-C4-alkoxy, COOH, (C1-C8-alkoxy)carbonyl, CONH2, (C1-C8-alkyl)aminocarbonyl, di(C1-C8-alkyl)aminocarbonyl; R6 = H, NO2, halogen, optionally substituted OH or COOH; R7 = H, NO2, halogen, optionally substituted OH; excluding those compounds in (I) in wherein X = CH2 and R5 = optionally substituted OH as well as R3, R7 = H or R1 = halogen as well as R3, R4, R6, R7 = H. The invention further relates to the use of said substances as herbicides and for dessication/defoliation of plants.

    1-AMINO-3-BENZYLURACILS
    125.
    发明专利
    1-AMINO-3-BENZYLURACILS 未知

    公开(公告)号：BG102184A

    公开(公告)日：1998-08-31

    申请号：BG10218498

    申请日：1998-01-14

    Applicant: BASF AG

    Inventor： MENKE OLAF ,  KLINTZ RALF ,  HAMPRECHT GERHARD ,  HEISTRACHER ELISABETH ,  SCHAEFER PETER ,  ZAGAR CYRILL ,  GOETZ NORBERT ,  WESTPHALEN KARL-OTTO ,  MISSLITZ ULF ,  WALTER HELMUT

    IPC: A01N43/54 ,  C07C275/24 ,  C07C281/02 ,  C07C281/06 ,  C07D239/54 ,  C07D413/12 ,  C07D419/12

    Abstract: The invention relates to 1-amino-3-benzyluracils and to theirsalts finding application as herbicides, for desiccation anddefoliation of plants. The compounds have the formulawhere R1 is halogen, R2 & R3 are H, CN, SCH, halogen, C1-C4halogenalkyl, C1-C4 halogenalkoxy or C1-C4 halogenalkylthio, R4matches R3 and can include C1-C4 alkyl, C1-C4 alkyl, C1-C4 alkoxy,C1-C4-alkyl-NHCO-, R5 is H, CN, NO2, OH, halogen, optionallysubstituted NH2, optionally substituted C1-C6 halogenalkoxy, C1-C6halogenalkylthio, C1-C4 alkoxy, C1-C6 alkylthio, C3-C8cycloalkoxy, C3-C8 cycloalkylthio, C3-C6 alkenyloxy, C3-C6alkyenylthio, C3-C6 alkynyloxy, C3-C6 alkynylthio,C1-C6-alkyl-COO, C1-C6-alkyl-COS-, C3-C6-alkenyl-COO,C3-C6-alkenyl-COS, C3-C6-alkynyl-COO-, C3-C6-alkynyl COS-, C1-C6alkyl-SO2-0- or C1-C6-alkyl-SO2, R6 is H, OH, SH, halogen, C1-C6halogenalkoxy, C1-C6 halogen alkylthio,C1-C6-alkylthio-(C1-C6-alkyl)carbonyl, (C1-C6)iminooxy-CO-;optionally substituted C1-C6 alkoxy, C1-C6 alkylthio, C3-C8cyloalkoxy, C3-C8 cycloalkylthio, C2-C6 alkenyloxy, C2-C6alkenylthio, C2-C6 alkynyloxy, C2-C6 alkynyilthio,C1-C6-alkyl-COO-, C2-C6-alkyl-COS-, C1-C6-alkoxy-COO-,C2-C6-alkyenyl-COO-, C2-C6-alkyenyl-COS-, C2-C6 alkynyl-COO-,C2-C6-alkynyl-COS-, 1-C6-SO2-0-, or C1-C6-alkyl-SO2; -CY-R11 {Y =-O-, -S-, optionally substituted -NH-}, -C-(R11)(Z1R12)(Z2R13)[{Z1and Z2 = -O-, -S-}, -C(R11 = C(R14)-CN, -C(R11) = C(R14)-CO-R15,-CH(R11)-CH(R12)-CO-R15, -C(R11) = C(R14)-CH2-CO-R15,-C(R11)=C(R14)-C(R16)=C(R17)-CO-R15-C(R11)=C(R14)-CH2-CH(R18)-CO-R15, -CO-OR19, -CO-SR19,-CO-N(R19)-OR20, -C=C-CO-NH-OR20,-C=C-CO-N(R19)-OR20,-C=C-CS-NH-OR20, -C=C-CS-N(R19)-OR20, -C(R11)=C(R14)-CO-NH-OR20,-C(R11)=C(R14)-CO-N(R19)-OR20, -C(R11)=C(R14)-CS-NH-OR20,-C(R11)=C(R14)-CS-N(R19)-OR20, -C(R11)=C(R14)-C(R21)=N-OR20,-C(R21)-N-OR20, -C=C-C(R21)=N-OR20, -C(Z1R12)(Z2R13)-OR19,-C(Z1R12) (Z2R13), -C(Z1R12)(Z2R13)-N(R23)R24, optionallysubstituted amino or -CONH2, azaheterocyclyl, -CO-azaheterocyclyl,or a chain containing (N + O or N + O + S) heterocyclyl.14 claims

    BENZOTIAZOLES SUBSTITUIDOS COMO AGENTES DE PROTECCION DE CULTIVOS.
    127.
    发明专利
    BENZOTIAZOLES SUBSTITUIDOS COMO AGENTES DE PROTECCION DE CULTIVOS. 未知

    公开(公告)号：MX9801334A

    公开(公告)日：1998-07-31

    申请号：MX9801334

    申请日：1998-02-18

    Applicant: BASF AG

    Inventor： HEISTRACHER ELISABETH ,  HAMPRECHT GERHARD ,  MENKE OLAF ,  SCHAFER PETER ,  ZAGAR CYRILL ,  WESTPHALEN KARL-OTTO ,  MISSLITZ ULF ,  WALTER HELMUT

    IPC: C07D277/64 ,  A01N43/78 ,  C07D277/68 ,  C07D277/76 ,  C07D417/04

    Abstract: Los benzotiazoles I substituidos y sus sales (Ver Formula) en donde X1 y X2, cada uno es 0 o S; R1 es H, NH2, alquilo de 1 a 6 átomos de carbono o haloalquilo de 1 a 6 átomos de carbono; R2 es H, halogeno, alquilo de 1 a 6 átomos de carbono, haloalquilo de 1 a 6 átomos de carbono, alquiltio de 1 a 6 átomos de carbono, alquilsulfinilo de 1 a 6 átomos de carbono o alquilsulfonilo de 1 a 6 átomos de carbono, R3 es H, halogeno o alquilo de 1 a 6 átomos de carbono; R4 es H o halogeno; R5 es CN, halogeno, alquilo de 1 a 6 átomos de carbono, haloalquilo de 1 a 6 átomos de carbono, alcoxi de 1 a 6 átomos de carbono o haloalcoxi de 1 a 6 átomos de carbono, Y es un enlace químico, -O-, -S-, -SO- o -SO2- y R6 es hidrogeno, CN, halogeno, cicloalquilo de 3 a 6 átomos de carbono, haloalquilo de 1 a 6 átomos de carbono, alquenilo de 3 a 6 átomos de carbono, haloalquenilo de 3 a 6 átomos de carbono alquenilo de 3 a 6 átomos de carbono o alquilo de 1 a 6 átomos de carbono, siendo posible que los radicales de cicloalquilo, alquilo, alquenilo y alquinilo mencionados se substituyen mediante CN, alcoxi de 1 a6átomos de carbono, alquiltio de 1 a 6 átomos de carbono, alcoxicarbonilo de 1 a 6 átomos de carbono, alquilaminocarbonilo de 1 a 6 átomos de carbono, di(alquilo de 1 a 6 átomos de carbono)aminocarbonilo, alquilcarboniloxi de 1 a 6 átomos de carbono, haloalcoxi de 1 a 6 átomos de carbono, haloalquiltio de 1 a 6 átomos de carbono o cicloalquilo de 3 a 6 átomo de carbono, con la salvedad de que R6 pude ser ciano solamente cuando Y es un enlace químico, oxígeno o azufre y R6 puede ser halogeno solamente cuando Y es un enlace químico, se usan como herbicidas y para la desecacion/abscision de las plantas.

    SUBSTITUTED PYRAZOLE-3-YL BENZAZOLES
    128.
    发明专利
    SUBSTITUTED PYRAZOLE-3-YL BENZAZOLES 未知

    公开(公告)号：CA2275611A1

    公开(公告)日：1998-06-25

    申请号：CA2275611

    申请日：1997-12-01

    Applicant: BASF AG

    Inventor： MENKE OLAF ,  SCHAEFER PETER ,  WESTPHALEN KARL-OTTO ,  ZAGAR CYRILL ,  WALTER HELMUT ,  MISSLITZ ULF ,  HAMPRECHT GERHARD ,  MENGES MARKUS

    IPC: A01N43/56 ,  A01N43/74 ,  C07D413/04 ,  C07D413/10 ,  C07D417/04 ,  C07D417/10

    Abstract: The invention concerns substituted pyrazole-3-yl benzazoles of formula (I) and salts thereof, in the formula R1 designating H, C1-C4 alkyl, C1-C4 alkyl halide; R2 designating CN, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkylsulphinyl, C1-C4-haloalkylsulphinyl, C1-C4-alkylsulphonyl, C1-C4-haloalkylsulphonyl; R3 = H, CN, NO2, halogen, C1-C4-alkyl, C1-C4-haloalkyl; R4 designating H, halogen; R5 designating H, CN, halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy or C1C4-haloalkoxy; Z designating -N=C(XR6)-O- or -N=C(XR6)-S-, bonded to .alpha. by the nitrogen, oxygen or sulphur; X designating a chemical bond, oxygen, sulphur, -S(O)-, -SO2-, -NH- or -N(R7); R6, R7 designating C1-C6-alkyl, C1-C6-haloalkyl, cyano-C1-C4-alkyl, hydroxy-C1-C4-alkyl, C3-C6-alkenyl, cyano-C3-C6-alkenyl, C3-C6-haloalkenyl, C3-C6-alkinyl, cyano-C3-C6-alkinyl, C3-C6-haloalkinyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-haloalkoxy-C1-C4-alkyl, C3-C4-alkenyloxy-C1-C4-alkyl, C3-C4-alkinyloxy-C1-C4-alkyl, C3-C8-cycloalkyloxy-C1-C4-alkyl, amino-C1-C4-alkyl, C1-C4-alkylamino-C1-C4-alkyl, di(C1-C4-alkyl)amino-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkyl, C1-C4-haloalkylthio-C1-C4-alkyl, C3-C4-alkenylthio- C1-C4-alkyl, C3-C4-alkinylthio-C1-C4-alkyl, C1-C4-alkyl-sulphinyl-C1-C4-alkyl, C1-C4-haloalkylsulphinyl-C1-C4-alkyl, C3-C4-alkenylsulphinyl-C1-C4-alkyl, C3-C4-alkinylsulphinyl-C1-C4-alkyl, C1-C4-alkylsulphonyl-C1-C4-alkyl, C1-C4-haloalkylsulphonyl-C1-C4-alkyl, C3-C4-alkenylsulphonyl-C1-C4-alkyl, C3-C4-alkinylsulphonyl-C1-C4-alkyl, hydroxycarbonyl-C1-C4-alkyl, C1-C4-alkoxycarbonyl-C1-C4-alkyl, which can carry a CN oder C1-C4-alkoxycarbonyl group, C1-C4-alkylthiocarbonyl-C1-C4-alkyl, aminocarbonyl-C1-C4-alkyl, C1-C4-alkylaminocarbonyl-C1-C4-alkyl, di(C1-C4-alkyl)aminocarbonyl-C1-C4-alkyl, di(C1-C4-alkyl)-phosphonyl-C1-C4-alkyl, C1-C4-alkoxyimino-C1-C4-alkyl, C3-C4-alkenyloxyimino-C1-C4-alkyl, optionally substituted C3-C8-cycloalkyl, C3-C8-cycloalkyl-C1-C4-alkyl, phenyl, phenyl-C1-C4-alkyl, 3- to 7-member heterocyclic or heterocyclyl-C1-C4-alkyl, wherein each cycloalkyl ring and each heterocyclyl ring contain a CO or CS ring member; if X is a chemical bond, -O-, -S-, -NH- or -N(R7)-, R6 also being C1C4 alkylcarbonyl, C1-C4 haloalkylcarbonyl, C1-C4 alkoxycarbonyl, C1-C4 alkylsulphonyl or C1-C4 haloalkylsulphonyl; if X is a chemical bond, R6 additionally designating CN, SH, NH2, halogen, -CH2-CH(halogen)-R8, -CH=CH-R8 or -CH=C(halogen)-R8, R8 designating COOH, C1-C4 alkoxycarbonyl, C1-C4 alkylthiocarbonyl, CONH2, C1-C4 alkylaminocarbonyl, di(C1-C4 alkyl)aminocarbonyl or di(C1-C4 alkyl)phosphonyl; or R6 plus R7 designating an optionally substituted 1,3-propylene, tetramethylene, pentamethylene or ethylene oxyethylene chain. The invention alsoEncerns the use of these substances as herbicides and for the desiccation and/or defoliation of plants.

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