Copolyether ester polyol process
    133.
    发明授权

    公开(公告)号:US09840580B2

    公开(公告)日:2017-12-12

    申请号:US15108486

    申请日:2015-01-05

    Abstract: Disclosed is a process for manufacturing copolyether ester polyol comprising: (1) providing feedstock comprising polytetramethylene ether glycol having a number average molecular weight of 350 g/mol or less and an oligomeric cyclic ether content of 4.0% by weight or more and a diacid composition selected from alpha-omega alkanedioic acids of formula HO2C—(CH2)n—CO2H, where n is from 2 through 16 to a reaction zone maintained at reaction conditions to produce a crude polyol product; (2) feeding the crude polyol product of step (1) to a separation zone at separation conditions to produce a first separation product having an oligomeric cyclic ether content of 2.0% by weight or greater, and a second separation product comprising copolyether ester polyol having an oligomeric cyclic ether content of less than 2.0% by weight; and (3) recovering the second separation product.

    IMPROVED POLYTETRAMETHYLENE ETHER GLYCOL MANUFACTURING PROCESS
    134.
    发明申请
    IMPROVED POLYTETRAMETHYLENE ETHER GLYCOL MANUFACTURING PROCESS 审中-公开
    改进聚对苯二甲酸乙二醇制造工艺

    公开(公告)号:US20160326316A1

    公开(公告)日:2016-11-10

    申请号:US15105781

    申请日:2014-12-19

    Inventor: Suri N. DORAI

    Abstract: The present invention relates to an improved process for manufacturing polytetramethylene ether glycol. The process involves controlling the number average molecular weight of the diacetate of polytetramethylene ether glycol intermediate produced by tetrahydrofuran polymerization before methanolysis thereof to desired polytetramethylene ether glycol product.

    Abstract translation: 本发明涉及一种制备聚四亚甲基醚二醇的改进方法。 该方法包括控制通过四氢呋喃聚合制备的聚四亚甲基醚二醇中间体的二乙酸酯的数均分子量,然后甲醇分解为所需的聚四亚甲基醚二醇产物。

    METHODS FOR BIOSYNTHESIZING 3-OXOPENT-4-ENOYL-CoA
    135.
    发明申请
    METHODS FOR BIOSYNTHESIZING 3-OXOPENT-4-ENOYL-CoA 审中-公开
    用于制备3-氧代-4-环氧基-CoA的方法

    公开(公告)号:US20160168610A1

    公开(公告)日:2016-06-16

    申请号:US14908659

    申请日:2014-07-29

    CPC classification number: C12P19/32 C12N9/1029 C12P7/26 C12P7/40 C12Y203/01016

    Abstract: This document describes biochemical pathways that include the production of 3-oxopent-4-enoyl-CoA by condensation of acryloyl-CoA and acetyl-CoA using a β-ketothiolase with a SER-HIS-HIS catalytic triad. These pathways described herein rely on enzymes such as, inter alia, dehydrogenases, dehydratases and β-ketothiolases.

    Abstract translation: 本文件描述了生物化学途径,其包括通过使用α-氧化还原酶与SER-HIS-HIS催化三单元组缩合丙烯酰辅酶A和乙酰辅酶A来生产3-氧代-4-烯酰辅酶A。 本文描述的这些途径依赖于酶,例如脱氢酶,脱水酶和β-酮硫解酶。

    PROCESS FOR STABILIZING HEAT EXCHANGER TUBES IN ANDRUSSOW PROCESS
    136.
    发明申请
    PROCESS FOR STABILIZING HEAT EXCHANGER TUBES IN ANDRUSSOW PROCESS 审中-公开
    在安捷伦工艺中稳定换热器管的方法

    公开(公告)号:US20160046498A1

    公开(公告)日:2016-02-18

    申请号:US14742134

    申请日:2013-12-12

    Abstract: The present invention relates to an improved process for producing hydrogen cyanide involving a heat exchanger comprising a plurality of tubes, wherein each of the plurality of tubes comprises a ceramic ferrule extending through the entrance of the tube, each ferrule comprising an insulation layer surrounding at least a portion of the ferrule, and one or more washers, wherein at least one of the one or more washers surrounds the ferrule above the entrance of the tube, wherein the ceramic ferrule is spaced apart from the tube. It further relates to a reaction apparatus for producing hydrogen cyanide involving a heat exchanger comprising a plurality of tubes, wherein each of the plurality of tubes comprises a ceramic ferrule extending through the entrance of the tube, each ferrule comprising an insulation layer surrounding at least a portion of the ferrule, and one or more washers, wherein at least one of the one or more washers surrounds the ferrule above the entrance of the tube, wherein the ceramic ferrule is spaced apart from the tube. It further relates to the heat exchanger for use in this improved process and reaction apparatus.

    Abstract translation: 本发明涉及一种生产氰化氢的改进方法,该方法涉及包括多个管的热交换器,其中多个管中的每个管包括延伸穿过管的入口的陶瓷套圈,每个套圈包括至少包围绝缘层 所述套圈的一部分和一个或多个垫圈,其中所述一个或多个垫圈中的至少一个围绕所述管的入口上方的所述套圈,其中所述陶瓷套圈与所述管间隔开。 本发明还涉及一种用于生产含有多个管的热交换器的氰化氢的反应装置,其中多个管中的每个管包括延伸穿过管的入口的陶瓷套圈,每个套圈包括至少一个 所述套圈的一部分以及一个或多个垫圈,其中所述一个或多个垫圈中的至少一个围绕所述管的入口上方的所述套圈,其中所述陶瓷套圈与所述管间隔开。 它还涉及用于该改进的方法和反应装置的热交换器。

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