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    HYDROLYSIS CATALYST AND PROCESS
    131.
    发明申请
    HYDROLYSIS CATALYST AND PROCESS 审中-公开
    水解催化剂和工艺

    公开(公告)号：WO2013181092A1

    公开(公告)日：2013-12-05

    申请号：PCT/US2013/042613

    申请日：2013-05-24

    Applicant: INVISTA NORTH AMERICA S.A.R.L.

    Inventor： AKI, Sudhir ,  VOS, Thomas, E.

    IPC: C07F9/08 ,  C07F9/6574 ,  C07F9/50

    CPC classification number: C07F9/145 ,  B01J31/185 ,  B01J2231/322 ,  C07F9/65744

    Abstract: A process of hydrolyzing a monodentate, bidentate or tridentate phosphorus-based phosphite ester ligand or ligand blend for a transition metal catalyst comprising contacting the ligand or ligand blend with a hydrolysis catalyst of the formula (R 11 X 11 ) n P (OH) 3-n where n is 0, 1 or 2 wherein the ligand or ligand blend comprises one or more of (i) a bidentate biphosphite ligand of formula (III), (R 12 -X 12 ) (R 13 -X 13 ) P-X 14 -Y-X 24 -P (X 22 -R 22 ) (X 23 -R 23 ), (ii) a tridentate triphosphite ligand of formula (IIIΑ) (R 12 -X 12 ) (R 13 -X 13 ) Ρ-Χ 14 -Y-X 32 -P(X 34 -R 34 )-(X 33 -Y 2 -Κ 24 -P(X 23 -R 23 )-(X 22 -R 22 ) or (iii) a monodentate phosphite ligand of formula (IV) P(X 1 -R 1 )(X 2 -R 2 )(X 3 -R 3 ) where each X is oxygen or a bond and each Y is an optionally substituted C6-C20 arylene, followed by separation of the ligand hydrolysis products.

    Abstract translation: 水解用于过渡金属催化剂的单齿，二齿或三齿磷基亚磷酸酯配体或配体共混物的方法，包括使配体或配体共混物与式（R 11 X 11）nP（OH）3-n的水解催化剂接触，其中n 是其中配体或配体共混物包含（i）式（III）的二齿二亚磷酸酯配体，（R12-X12）（R13-X13）P-X14-Y-X24-P（ X22-R22）（X23-R23），（ii）式（IIIa）（R12-X12）（R13-X13）Rho-Chi14-Y-X32-P（X34-R34） - （X33- Y2-Kappa24-P（X23-R23） - （X22-R22）或（iii）式（IV）P（X1-R1）（X2-R2）（X3-R3）的单齿亚磷酸酯配体，其中X为氧 或键，并且每个Y是任选取代的C 6 -C 20亚芳基，然后分离配体水解产物。

    POLYESTER COMPOSITIONS HAVING HIGH DIMENSIONAL STABILITY
    133.
    发明申请
    POLYESTER COMPOSITIONS HAVING HIGH DIMENSIONAL STABILITY 审中-公开
    具有高维稳定性的聚酯组合物

    公开(公告)号：WO2006096175A1

    公开(公告)日：2006-09-14

    申请号：PCT/US2005/007541

    申请日：2005-03-08

    Applicant: INVISTA NORTH AMERICA S.A.R.L. ,  FLORES, Rodolfo, Agustin

    Inventor： FLORES, Rodolfo, Agustin

    IPC: C08L67/02

    CPC classification number: C08K3/34 ,  C08K7/00 ,  Y10T428/251 ,  C08L67/02

    Abstract: The present invention relates to thermoplastic compositions having; high dimensional stability at high temperatures. In particular it is directed to polyester compositions containing mica for use in dual-ovenable trays and clear lids for hot food containers. According to one embodiment, the present invention is directed to a polyester composition comprising a polyester containing greater than about 2 to less than about 10 weight % of a mica filler. According to another embodiment of the present invention the mica containing polyester is prepared by the addition of the mica during polymerization, using a buffer to minimize diethylene glycol formation. According to another embodiment of the present invention, the polyester composition containing greater than 2 to less than 10 weight % mica also contains an additive package of impact modifier, nucleating agent and pigment in a concentration from about 5 weight % to 20 weight of the total composition. According to another embodiment of the present invention, the polyester composition containing mica is thermoformed into a container, such as a food tray.

    Abstract translation: 本发明涉及具有以下成分的热塑性组合物： 在高温下的高尺寸稳定性。 特别地，它涉及含有云母的聚酯组合物，其用于双重可烘烤托盘和用于热食品容器的清漆盖。 根据一个实施方案，本发明涉及包含含有大于约2至小于约10重量％的云母填料的聚酯的聚酯组合物。 根据本发明的另一个实施方案，通过在聚合过程中加入云母，使用缓冲剂使二甘醇形成最小化来制备含云母的聚酯。 根据本发明的另一个实施方案，含有大于2至小于10重量％云母的聚酯组合物还含有抗冲改性剂，成核剂和颜料的添加剂包，其浓度为总重量的约5重量％至20重量％ 组成。 根据本发明的另一个实施方案，将含有云母的聚酯组合物热成型为容器，例如食物托盘。

    OPAQUE POLYESTER CONTAINERS
    135.
    发明申请
    OPAQUE POLYESTER CONTAINERS 审中-公开

    公开(公告)号：WO2003064267A3

    公开(公告)日：2003-08-07

    申请号：PCT/US2003/003042

    申请日：2003-01-31

    Applicant: ARTEVA NORTH AMERICA S.A.R.L. ,  SCANTLEBURY, Geoffrey, R. ,  LIU, Zhenguo ,  HUANG, Xiaoyan

    Inventor： SCANTLEBURY, Geoffrey, R. ,  LIU, Zhenguo ,  HUANG, Xiaoyan

    IPC: B29D22/00

    Abstract: The present invention describes both a stretch-blow-molded opaque polyester container and a method of making it. The container, typically a beverage bottle has less than 15% transmission of visible light (500 nm) through a 0.4 millimeter wall thickness. It contains from about 0.1 to about 5wt. % of said opacifying material. The opacifying material may be any material compatible with polyester resin. The method of making the container includes introducing the opacifying material during polymerization, or prepared as a master batch for mixing with the polymer. Selection of certain opacifying materials can also result in favorable reheat properties, gas permeation-barrier improvements, and when the resin contains both opacifying material and oxygen scavenger there can be a synergistic effect with respect to CO 2 permeation.

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