Pressurized production of alkanesulfonyl chloride and alkanesulfonic acid
    152.
    发明公开
    Pressurized production of alkanesulfonyl chloride and alkanesulfonic acid 失效
    Herstellung von Alkansulfonylchloriden undAlkansulfonsäurenunter Druck。

    公开(公告)号:EP0675107A1

    公开(公告)日:1995-10-04

    申请号:EP95104523.6

    申请日:1995-03-28

    CPC classification number: C07C303/16 C07C309/80 C07C309/04

    Abstract: A process for coproducing alkanesulfonyl chloride (ASC) or alkanesulfonic acid (ASA) and hydrochloric acid of reduced contamination with ASC, wherein a compound of the formula RSX, where X is hydrogen or -SR¹ and R and R¹ are alkyl radicals having from 1 to 20 carbon atoms, is reacted with chlorine in the presence of aqueous hydrochloride at an elevated pressure.

    Abstract translation: 用于共同生产具有降低的ASC污染的烷基磺酰氯(ASC)或烷烃磺酸(ASA)和盐酸的方法,其中式RSX的化合物,其中X是氢或-SR 1,R和R 1是 具有1至20个碳原子的烷基在氯化氢盐水溶液的存在下,在升高的压力下与氯反应。

    Reactive hindered amine light stabilizers
    160.
    发明公开
    Reactive hindered amine light stabilizers 失效
    Reaktive,gehinderte Aminlichtstabilisatoren。

    公开(公告)号:EP0516192A2

    公开(公告)日:1992-12-02

    申请号:EP92113890.5

    申请日:1989-02-13

    CPC classification number: C07D401/04 C07D211/58 C08K5/3435 C08L23/12

    Abstract: N-(2,2,6,6-tetraalkyl-4-piperidinyl)amine-hydrazides of dicarboxylic acids contain a light stabilizing group, a heat stabilizing group, a 5-membered lactam ring and a reactive hydrazide functionality in the same molecule. The reactive stabilizers can be prepared by reacting 4-amino-2,2,6,6-tetraalkylpiperidines with dialkyl itaconates followed by hydrazinolysis of the ester group of the intermediate mono ester-amide. The compounds are useful for introducing permanent heat and light stability to coreactive polymers or copolymers. They are also useful in the stabilization of inert polymeric systems against the degradative effects of heat and light when merely mixed with, rather than reacted with, the polymers for which stabilization is sought.

    Abstract translation: 二羧酸的N-(2,2,6,6-四烷基-4-哌啶基)胺 - 酰肼在同一分子中含有光稳定基团,热稳定基团,5元内酰胺环和反应性酰肼官能团。 反应性稳定剂可以通过使4-氨基-2,2,6,6-四烷基哌啶与衣康酸二烷酯反应,然后通过中间体单酯 - 酰胺的酯基进行肼解来制备。 该化合物可用于将热稳定性和光稳定性引入聚合物或共聚物。 它们也可用于稳定惰性聚合物体系以抵抗热和光的降解作用,当仅与需要稳定化的聚合物混合而不是与其反应时。

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