公开(公告)号：CA1075709A

公开(公告)日：1980-04-15

申请号：CA231660

申请日：1975-07-16

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT K ,  SURESH DEV D ,  HARDMAN HARLEY F

IPC: B01J23/88 ,  B01J23/887 ,  B01J23/89 ,  B01J27/02 ,  B01J27/192 ,  C07C45/34 ,  C07C45/35 ,  C07C51/25 ,  C07C47/20 ,  C07C57/04

Abstract: The present invention is a process for the oxidation of olefins to unsaturated aldehydes and acids using a catalyst containing iron, bismuth, molybdenum plus at least one of nickel, cobalt, magnesium, zinc, cadmium or calcium and according to the invention, an element selected from cerium, thorium, niobium, praseodymium, yttrium, zirconium, ruthenium, gallium, indium, copper, lanthanum, or antimony. These catalysts may also contain certain elements that further enhance the desirability of the oxidation process.

公开(公告)号：CA1075669A

公开(公告)日：1980-04-15

申请号：CA242831

申请日：1975-12-30

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT K ,  SURESH DEV D

IPC: B01J23/02 ,  B01J23/28 ,  B01J23/30 ,  B01J23/31 ,  B01J23/32 ,  B01J23/68 ,  B01J23/88 ,  B01J23/887 ,  B01J23/888 ,  B01J23/89 ,  B01J27/192 ,  C07B61/00 ,  C07C255/08 ,  B01J23/00

Abstract: OXIDATION CATALYSTS The invention is an oxidation catalyst which contains at least a Group IIA or Group IIB element or manganese plus as required elements, chromium, bismuth and molybdenum. The catalysts can optionally contain a number of other elements and are useful for various oxidation reactions, especially the ammoxidation of propylene or isobutylene to obtain acrylonitrile or methacrylonitrile, the oxidation of propylene or isobutylene to obtain acrolein or methacrolein and the oxidative dehydrogenation of olefins containing 4 or 5 carbon atoms to obtain the corresponding diolefin.

公开(公告)号：CA1065270A

公开(公告)日：1979-10-30

申请号：CA235817

申请日：1975-09-18

Applicant: STANDARD OIL CO OHIO

Inventor： BARTEK JOSEPH P ,  CROSBIE LAWRENCE P ,  GRASSELLI ROBERT K

IPC: C10G35/06 ,  B01J21/04 ,  B01J23/40 ,  B01J23/52 ,  B01J23/56 ,  B01J23/64 ,  B01J23/70 ,  B01J29/18 ,  B01J35/08 ,  C10G35/09 ,  C10G35/04

Abstract: SHAPED CATALYST FOR NAPHTHA REFORMING The present invention is the use of amphora shaped catalysts in the known process of naphtha reforming. Catalysts employed in naphtha reforming have been found to be unexpectedly superior to other commercial catalyst forms when placed in the amphora shape, which is a substantially spherical outer surface with a void center having a cavity in the external surface communicating with the void center.

公开(公告)号：CA1015768A

公开(公告)日：1977-08-16

申请号：CA177446

申请日：1973-07-26

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT K ,  MILLER ARTHUR F ,  SURESH DEV D

IPC: C07B61/00 ,  B01J27/00 ,  B01J27/02 ,  B01J27/057 ,  B01J27/19 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08

公开(公告)号：SE391710B

公开(公告)日：1977-02-28

申请号：SE7313351

申请日：1973-10-01

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT K ,  SURESH DEV D

IPC: B01J23/00 ,  C07C69/65 ,  B01J23/30 ,  B01J25/00 ,  B01J27/00 ,  C07B61/00 ,  C07C51/04 ,  C07C57/04 ,  C07C67/05 ,  C07C67/39 ,  C07C67/44 ,  C07C69/54 ,  C07C69/653

Abstract: 1433168 Esters from unsaturated alcohols and aldehydes STANDARD OIL CO 19 Sept 1973 43892/73 Heading C2C Acrylic and methacrylic esters are prepared by adding an aliphatic or aromatic alcohol containing up to ten carbon atoms to acrolein or methacrolein and reacting the mixture with molecular oxygen in the presence of an oxidation catalyst at a temperature of from 250‹ to 450‹ C. The alcohol is suitably an alkanol of 1 to 4 carbon atoms, and the catalyst suitably contains molybdenum, vanadium and/or tungsten. Reference has been directed by the Comptroller to Specification 1,266,457.

公开(公告)号：CA1004232A

公开(公告)日：1977-01-25

申请号：CA157413

申请日：1972-11-24

Applicant: STANDARD OIL CO OHIO

Inventor： SHAW WILFRID G ,  GRASSELLI ROBERT K

IPC: B01J21/00 ,  B01J23/887 ,  B01J27/192 ,  C07B61/00 ,  C07C1/00 ,  C07C5/333 ,  C07C5/48 ,  C07C11/167 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08

公开(公告)号：CA996574A

公开(公告)日：1976-09-07

申请号：CA157411

申请日：1972-11-24

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT K ,  SURESH DEV D

IPC: B01J23/00 ,  B01J23/30 ,  B01J23/34 ,  B01J23/88 ,  B01J23/888 ,  C07B61/00 ,  C07C51/00 ,  C07C51/235 ,  C07C51/25 ,  C07C57/055 ,  C07C67/00

Abstract: 1391859 Unsaturated aliphatic acids STANDARD OIL CO 28 Dec 1972 [22 Feb 1972] 59764/72 Heading C2C [Also in Division Bl] Unsaturated aliphatic acids are made by the vapour phase oxidation of the corresponding unsaturated aldehydes with O 2 in the presence of a catalyst containing Sb a Sn b W c V d Mo e O x ; wherein a=0-6; b=0À1-12; c=0À1-6; d= 0À5-12; e=8-16 and x is as required by the valence of the other elements, and optionally one or more of Fe, Ni, Co, Zn, Mn, Mg, Cu and/or a support. Examples describe the preparation of acrylic acid from acrolein.

公开(公告)号：CA991381A

公开(公告)日：1976-06-22

申请号：CA174177

申请日：1973-06-15

Applicant: STANDARD OIL CO OHIO

Inventor： CALLAHAN JAMES L ,  HARDMAN HARLEY F ,  GRASSELLI ROBERT K

IPC: B01D53/86 ,  B01D53/72 ,  B01J23/72 ,  C02F1/72 ,  F23G7/07

公开(公告)号：SE7313351A

公开(公告)日：1975-04-02

申请号：SE7313351

申请日：1973-10-01

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT K ,  SURESH DEV D

IPC: C07C69/65 ,  B01J23/00 ,  B01J23/30 ,  B01J25/00 ,  B01J27/00 ,  C07B61/00 ,  C07C51/04 ,  C07C57/04 ,  C07C67/05 ,  C07C67/39 ,  C07C67/44 ,  C07C69/54 ,  C07C69/653

CPC classification number: C07C67/44 ,  B01J23/30 ,  C07C67/39 ,  C07C69/54

公开(公告)号：CA954521A

公开(公告)日：1974-09-10

申请号：CA166671

申请日：1973-03-21

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT K ,  CALLAHAN JAMES L

IPC: C07D215/48 ,  B01J23/00 ,  B01J23/88 ,  C07B61/00 ,  C07C67/00 ,  C07C253/00 ,  C07C255/49 ,  C07C255/50 ,  C07C255/51 ,  C07D213/84

Abstract: 1415468 Preparation of aromatic nitrites STANDARD OIL CO 27 March 1973 [27 March 1972] 14539/73 Heading C2C [Also in Division B1] The invention comprises a process for the preparation of heterocyclic or carbocyclic aromatic nitriles in which a corresponding methyl substituted aromatic compound is reacted at 300-500‹ C. with ammonia and molecular oxygen or oxygen supplied by the catalyst in the presence of a catalyst containing an oxide of formula Fe a Bi b Mo c Ni d Co e Q f R g O x wherein Q is an alkali metal an alkaline earth metal thallium or a mixture thereof; R is boron, phosphorus, arsenic, antimony or tungsten or a mixture thereof; a and b are numbers from 0À1 to 12; c is a number from 8 to 16; d, e and f are numbers from 0 to 10; g is a in which R 1 and R 2 are identical or different number from 0 to 6 and x is a number which satisfies the valence requirements of the other elements.