公开(公告)号：KR790000826B1

公开(公告)日：1979-07-18

申请号：KR750001586

申请日：1975-07-21

Applicant: STANDARD OIL CO OHIO

Inventor： SURESH DEV D ,  HARDMAN H ,  GRASSELLI R K

Abstract: Unsatd. aldehydes and acids were obtained by oxidn. of olefins using the improved catalyst I (X = Ce, Th, Mn, Pr, Nb, Ge, Cr, Y, Zr, Ru, Ga, Sn, In, Cu, La, Ta, W or their mixt., A = alkali metal, Tl or their mixt, D = Ni, Co, Mg, Zn, Cd, Ca, Sr, or their mixt., E = P, As, B, S, Al, or their mixt. 0

公开(公告)号：US3907713A

公开(公告)日：1975-09-23

申请号：US32903473

申请日：1973-02-02

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT K ,  SURESH DEV D ,  FRIEDRICH MARIA

IPC: C07C27/00 ,  B01J21/02 ,  B01J23/28 ,  B01J23/31 ,  B01J23/34 ,  B01J23/76 ,  B01J23/84 ,  B01J23/88 ,  B01J27/057 ,  B01J27/18 ,  B01J37/02 ,  C07B61/00 ,  C07C27/14 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08 ,  B01J23/10

CPC classification number: B01J23/8872 ,  B01J21/02 ,  B01J23/31 ,  B01J23/34 ,  B01J23/8871 ,  B01J23/8876 ,  B01J27/0576 ,  B01J2523/00 ,  C07C253/26 ,  Y02P20/52 ,  B01J2523/13 ,  B01J2523/22 ,  B01J2523/41 ,  B01J2523/51 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/847 ,  B01J2523/845 ,  B01J2523/64 ,  B01J2523/72 ,  C07C255/08

Abstract: Very desirable oxidation catalysts are prepared by impregnating a catalytic oxide matrix containing at least cobalt and molybdenum, magnesium and molybdenum, nickel and mulybdenum, manganese and molybdenum with iron, bismuth, tellurium or a mixture thereof.

Abstract translation: 通过将含有至少钴和钼，镁和钼，镍和钼，锰和钼的催化氧化物基质浸渍在铁，铋，碲或其混合物中来制备非常理想的氧化催化剂。

公开(公告)号：US3907859A

公开(公告)日：1975-09-23

申请号：US30065072

申请日：1972-10-25

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT K ,  SURESH DEV D ,  MILLER ARTHUR F

IPC: B01J23/24 ,  B01J23/32 ,  B01J23/68 ,  B01J23/887 ,  B01J27/192 ,  C07C51/25 ,  C07C57/055 ,  C07C120/14 ,  C07C51/32 ,  C07C57/04

CPC classification number: C07C253/26 ,  B01J23/24 ,  B01J23/32 ,  B01J23/687 ,  B01J23/8876 ,  B01J27/192 ,  C07C51/252 ,  Y02P20/52 ,  C07C57/04 ,  C07C255/08

Abstract: High per pass conversions to acrylonitrile and acrylic acid or methacrylonitrile and methacrylic acid and desirable commercial flexibility are realized by reacting propylene or isobutylene with molecular oxygen and about 0.1 to about 0.9 moles of ammonia per mole of olefin in the presence of two catalysts. The first catalyst is an ammoxidation catalyst, and the second catalyst is an oxidation catalyst.

Abstract translation: 丙烯腈和丙烯酸或甲基丙烯腈和甲基丙烯酸的高通过转化率和所需的商业柔性通过在两种催化剂存在下使丙烯或异丁烯与分子氧和约0.1至约0.9摩尔氨/摩尔烯烃反应来实现。 第一催化剂是氨氧化催化剂，第二催化剂是氧化催化剂。

公开(公告)号：CS226199B2

公开(公告)日：1984-03-19

申请号：CS238782

申请日：1982-04-02

Applicant: STANDARD OIL CO OHIO ,  STANDARD OIL CO OHIO

Inventor： GRASSELI ROBERT K ,  GRASSELI ROBERT K ,  SURESH DEV D ,  SURESH DEV D ,  HARDMAN HARLEY F ,  HARDMAN HARLEY F

IPC: C07C47/22 ,  C07C57/05

公开(公告)号：AT174024T

公开(公告)日：1998-12-15

申请号：AT93307073

申请日：1993-09-08

Applicant: STANDARD OIL CO OHIO

Inventor： FRIEDRICH MARIA S ,  SEELEY MICHAEL J ,  PAPARIZOS CHRISTOS ,  SURESH DEV D

IPC: B01J23/18 ,  B01J23/22 ,  B01J23/26 ,  B01J23/847 ,  B01J23/889 ,  C01C3/02 ,  C07B61/00 ,  C07C253/26 ,  C07C255/08

Abstract: Disclosed is a method for ammoxidizing C3 to C5 mono-olefins to a,b-mono-unsaturated acyclic nitriles having 3 to 5 carbon atoms and HCN by introducing such mono-olefins molecular oxygen and ammonia into a reaction zone into vapor phase contact with a solid ammoxidation catalyst, wherein the mol ratio of introduced molecular oxygen and ammonia to said introduced mono-olefin is at least 1.5 and 1.0, respectively, wherein said catalyst contains the elements and proportions indicated by the empirical formula: V1SbaMmNnOx where a = 0.5 to 2 M = one or more of: Sn, Ti, Fe, and Ga m = 0.05 to 3, usually at least 0.1 and at most 1 N = one or more of: W, Bi, Mo, Li, Mg, P, Zn, Mn, Te, Ge, Nb, Zr, Cr, Al, Cu, Ce, B n = 0.0 to 0.5, and wherein the preparation of the catalyst includes contacting in an aqueous dispersion a vanadium compound and an antimony compound while said vanadium is in solution.

公开(公告)号：ZA941200B

公开(公告)日：1994-11-30

申请号：ZA941200

申请日：1994-02-22

Applicant: STANDARD OIL CO OHIO

Inventor： SHAW WILRID G ,  TROTT LOUIS R ,  BIGLER KENNETH L ,  MIKO STEVE J ,  REILING VINCENT G ,  SURESH DEV D ,  BOTT PAUL E ,  SHUKI ALBERT R JR ,  KOCJANCIC FRANK J ,  SEELY MICHAEL J ,  FRIEDRICH MARIA S ,  SOCKELL EDWARD J ,  KECKLER KENNETH P ,  ROWE STEVEN J

IPC: C07B20060101 ,  C07C20060101 ,  C07C ,  C07B

公开(公告)号：ZA9401200B

公开(公告)日：1994-11-30

申请号：ZA9401200

申请日：1994-02-22

Applicant: STANDARD OIL CO OHIO

Inventor： SHAW WILRID G ,  TROTT LOUIS R ,  BIGLER KENNETH L ,  MIKO STEVE J ,  REILING VINCENT G ,  SURESH DEV D ,  BOTT PAUL E ,  SHUKI ALBERT R JR ,  KOCJANCIC FRANK J ,  SEELY MICHAEL J ,  FRIEDRICH MARIA S ,  SOCKELL EDWARD J ,  KECKLER KENNETH P ,  ROWE STEVEN J

IPC: C07B20060101 ,  C07C20060101 ,  C07C ,  C07B

CPC classification number: Y02A50/2346

公开(公告)号：BR8801113A

公开(公告)日：1988-10-18

申请号：BR8801113

申请日：1988-03-11

Applicant: STANDARD OIL CO OHIO

Inventor： SURESH DEV D ,  ORNDOFF DAVID A ,  BRAZDIL JAMES F ,  GLAESER LINDA C ,  FRIEDRICH MARIA S

IPC: B01J21/12 ,  B01J23/22 ,  B01J23/31 ,  C07B61/00 ,  C07C67/00 ,  C07C253/00 ,  C07C253/24 ,  C07C255/08 ,  C07C120/14 ,  C07C121/32

Abstract: Disclosed is a process for the vapor phase ammoxidation of a C3 to C5 paraffin to an alpha , beta -unsaturated nitrile having 3-5 C atoms, using a particulate bismuth-vanadium oxide catalyst containing at least one other specified element.

公开(公告)号：CA1188287A

公开(公告)日：1985-06-04

申请号：CA395180

申请日：1982-01-29

Applicant: STANDARD OIL CO OHIO

Inventor： BRAZDIL JAMES F JR ,  SURESH DEV D ,  GRASSELLI ROBERT K

IPC: C07C57/055 ,  B01J23/31 ,  B01J23/68 ,  B01J23/88 ,  B01J23/885 ,  B01J27/057 ,  C07B61/00 ,  C07C1/00 ,  C07C5/48 ,  C07C11/02 ,  C07C45/00 ,  C07C45/34 ,  C07C45/35 ,  C07C45/37 ,  C07C45/38 ,  C07C47/22 ,  C07C51/00 ,  C07C51/21 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08 ,  C07C27/14 ,  C07C120/14

Abstract: Bismuth cerium molybdate catalysts promoted with alkali metal and other optional ingredients provide high yields of acrylonitrile in the ammoxidation of propylene.

公开(公告)号：CA1178570A

公开(公告)日：1984-11-27

申请号：CA395801

申请日：1982-02-08

Applicant: STANDARD OIL CO OHIO

Inventor： FRIEDRICH MARIA S ,  SURESH DEV D ,  GRASSELLI ROBERT K

IPC: B01J23/84 ,  B01J23/88

Abstract: (5277) IMPREGNATING CATALYSTS An element selected from Groups IA, IB, IIB, IIIA and IIIB is incorporated into an iron bismuth molybdate oxide complex catalyst by impregnation.