Abstract:
It is an objective of the present invention to provide, in particular, a curable composition of an extremely high utility which yields a cured film having excellent acid resistance and the like. The curable composition of the present invention is used mainly for paints, adhesives, or sealing agents. The curable composition is based on crosslinking reaction between a specific substituted methyl ester group exemplified by an alkoxymethyl ester group and other functional groups, i.e., an epoxy group and an active hydrogen-containing group such as a hydroxyl group, a carbamate group, and an acetoacetoxy group. Thus, the present invention provides basically two types of compositions: one is the composition containing a self-crosslinkable polymer possessing both a substituted methyl ester group and an active hydrogen-containing group and/or an epoxy group, the other is the composition containing a compound possessing a substituted methyl ester group and a compound containing an active hydrogen-containing group and/or an epoxy group.
Abstract:
A dried film reinforced with coalescable water insoluble polymer particles which are substantially noncoalesced is disclosed. Also disclosed are dried films reinforced with noncoalesced water insoluble polymer particles which are readily water dispersible. Also disclosed are stable aqueous dispersions for formation of such films which comprise (a) a water insoluble component comprising coalescable polymer particles which have a T.sub.g less than 55.degree. C. and a majority of which have a particle size of less than 1 micron; and (b) a water soluble component which comprises a water soluble polymer capable of inhibiting coalescence of the polymer particles, or a water soluble polymer and a component capable of inhibiting coalescence of the polymer particles.
Abstract:
Thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating, a specific vinyl ether or vinyl thioether and a thermal latent acid catalyst. The blocked carboxyl group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule. The thermosetting composition gives cured products having excellent chemical properties, physical properties, weathering resistance and storage stability and is advantageously utilized for coating compositions, ink, adhesive and molded plastics.
Abstract:
A coating composition comprising(A) a film-forming polymer having functional group(s) capable of reacting with the crosslinking agent (D) hereinafter referred to and cationic or anionic functional group(s),(B) a volatile organic liquid diluent in which the polymer (A) is dissolved,(C) crosslinked polymer microparticles bearing anionic or cationic functional group(s) whose electric charge is opposite to that of the film-forming polymer, which are insoluble in the combination of the film-forming polymer (A) and the diluent (B) and are maintained in a stabilized state of dispersion therein, and(D) a crosslinking agent dissolved in the diluent (B).
Abstract:
Amino-formaldehyde products with activated carboxylic ester groups cross-link compounds containing pendant primary or secondary amine groups.This is a continuation, of application Ser. No. 232,455, filed Feb. 9, 1981, which is a continuation of Ser. No. 128,613, filed 3/10/80, which is a division of Ser. No. 32,982, filed 4/25/79, which is a continuation-in-part of Ser. No. 926,762, filed 7/21/78, all now abandoned.
Abstract:
1. A THERMOSETTING SYNTHETIC POLYMER DISPERSION COMPRISING A MIXTURE OF (I) A SYNTHETIC POLYMER DISPERSION COMPRISING PARTICLES OF A COPOLYMER FORMED FROM (A) A COPOLYMERIZABLE ETHYLENICALLY UNSATURATED MONOMER AND (B) A COPOLYMERIZABLE ETHYLENICALLY UNSATURATED MONOMER HAVING A CHEMICALLY REACTIVE CROSS-LINKING GROUP AND A PROTECTIVE LAYER FORMED AROUND SAID COPOLYMER PARTICLES, WHICH IS COMPOSED OF A STABILIZER (I) HAVING A COMPONENT COMPARTIBLE WITH SAID COPOLYMER OR BEING CHEMICALLY BONDED THERETO AND (II) BEING SOLVATED IN AN ORGANIC LIQUID HAVING NO POLARITY OR A LOW POLARITY, SAID COPOLYMER PARTICLES BEING STABLY DISPERSED IN THE ORGANIC LIQUID BY SAID PROTECTIVE LAYER AND HAVING AN AVERAGE PARTICLE SIZE OF 0.1 TO 10U, AND (II) A SYNTHETIC POLYMER DISPERSION COMPRISING PARTICLES OF A COPOLYMER FORMED FROM (A) A COPOLYMERIZABLE ETHYLENICALLY UNSATURATED MONOMELR AND (C) A COPOLYMERIZABLE ETHYLENICALLY UNSATURATED MONOMER HAVING A COMPLEMENTARY, CHEMICALLY REACTIVE CROSS-LINKING GROUP CAPABLE OF REACTING WITH THE CHEMICALLY REACTIVE CROSS-LINKING GROUP OF THE PARTICLES IN DISPERSION (I) AND A PROTECTIVE LAYER FORMED AROUND SAID COPOLYMER PARTICLES, WHICH IS COMPOSED OF A STABILIZER (I) HAVING A COMPONENT COMPARTIBLE WITH SAID COPOLYMER OR BEING CHEMICALLY BONDED THERETO AND (II) BEING SOLVATED IN AN ORGANIC LIQUID HAVING NO POLARITY OR A LOW POLARITY, SAID COPOLYMER PARTICLES BEING STABLY DISPERSED IN THE ORGANIC LIQUID BY SAID PROTECTIVE LAYER AND HAVING AN AVERAGE PARTICLE SIZE OF 0.1 TO 10U.
Abstract:
POLYMERS CONTAINING A NORBORNENYL GROUP ARE READILY CROSSLINKED BY IRADIATION TO PRODUCE INSOLUBLE PRODUCTS. THE CROSSLINKED PRODUCTS ARE USEFUL AS COATINGS ON WOOD, METAL, ETC., AS SELF-SUPPORTIN FILMS, WIRE INSULATION, FOR THE TREATMENT OF FBRICS TO RENDER THEM MORE DURABLE AND CREASE RESISTANT, AS WELL AS IN THE MANY KNOWN AREAS IN WHICH YNTHETIC POLYMERS ARE EMPLOYED SUCH AS THE PRODUCTION OF MOLDED AND EXTRUDED SHAPED ARTICLES.
Abstract:
An aqueous coating composition is provided that is preferably substantially free of styrene and structural units derived from styrene. The coating composition includes a resin system that preferably includes a water-dispersible polymer and an emulsion polymerized ethylenically unsaturated monomer component. The resin system is preferably formed using a process that includes emulsion polymerizing the ethylenically unsaturated monomer component in the presence of an aqueous dispersion including the water-dispersible polymer. In certain preferred embodiments, the water-dispersible polymer is a salt of an acid- or anhydride-functional aromatic polyether polymer.
Abstract:
A functional polymer including at least two different types of side chains, having the general formula (1),
wherein A is an at least monosubstituted alkylene or arylene group; B is an amide, ester or ether group and n is 0 or 1; F is selected from: an ester, secondary amine, amide, ether, thio ether, thio ester, and may be the same or different for the different side chains; D is a side chain intended to reversible bind to a substrate or has a coating function; E is a side chain intended to irreversible bind to a substrate, the side chain E and polymer includes 1 to 10 different side chains D and 1 to 10 different side chains E, but at least one of each, and includes a plurality of each type, whereby the different types of side chains are randomly or regularly distributed in the polymer.
Abstract:
Topcoat compositions are provided that can be used in immersion lithography to form photoresist patterns. The topcoat compositions include a solvent system that comprises 1) a first organic solvent represented by formula (I),
wherein R1 and R2 are alkyl groups of 3-8 carbons and the total number of carbons of R1 and R2 is greater than 6; and 2) a second organic solvent that is a C4 to C10 monovalent alcohol.