Abstract:
PURPOSE: A separating membrane, a manufacturing method of the same, and a composite membrane including the same are provided to form a water treatment module with high energy efficiency. CONSTITUTION: A separating membrane includes polyacyrlonitrile-based copolymer(301). The polyacyrlonitrile-based copolymer includes hydrophobic side chains or hydrophobic repeating units(303). The separating membrane includes a skin layer(101) and a porous layer(102). The thickness ratio of the skin layer to the porous layer is 0.01 or less. The thickness of the skin layer is 1um or less.
Abstract:
The present invention provides: an organic/inorganic hybrid compound with fouling resistance including a vinyl based first structure unit block including a polygonal oligomer silsesquioxane core and one or more arms connected to at least one Si of polygonal oligomer silsesquioxane, wherein the arms include at least one hydrophilic group on a side chain, and a vinyl based second structure unit block including a hydrophobic group on a side chain; and a fouling resistant membrane including the same. [Reference numerals] (AA) SRC15 (comparative example 3); (BB) SBC13 (example 1); (CC) SBC13 (example 2)
Abstract:
PURPOSE: An anti-fouling organic/inorganic composite compound is provided to obtain an antifouling membrane having excellent anti-fouling performance, to extend life and reduce maintenance costs of a membrane such as cleaning costs. CONSTITUTION: An anti-fouling organic/inorganic composite compound comprises an anti-fouling organic/inorganic composite compound, a core formed of polyhedral oligomeric silsesquioxane, and an arm connected to at least one Si of the polyhedral oligomeric silsesquioxane. A manufacturing method of an anti-fouling membrane comprises: a step of preparing a solution which comprises the organic/inorganic composite compound and a solvent; a step of forming a surface layer by spreading the solution on the surface of a membrane which requires anti-fouling surface treatment.
Abstract:
PURPOSE: A separating membrane, a manufacturing method of the same, and a forward osmosis water treatment apparatus including the separating membrane are provided to improve intensity and porosity by including esterified cellulose ether with high molecular weight. CONSTITUTION: A separating membrane includes one or more polymers with structure units represented by chemical formula 1. The contact angle of the separating membrane is in a range between 50 and 65 degrees. A manufacturing method of the polymers with the structural units includes the following steps: a cellulose ether compound with at least one hydroxyl group by etherifying a cellulose compound; and the cellulose ether compound is esterified to obtain esterified cellulose ether.
Abstract:
A forward osmosis water treatment device using a separating membrane as a forward osmosis water treatment device which includes a polymer layer in which a function group having an osmosis draw solute inside an osmosis draw solution and chemical affinity is introduced is provided. The present invention relates to a forward osmosis water treatment device which includes a feed solution containing separation target materials; a osmosis draw solution receiving unit having osmosis concentration higher than that of the feed water; a first housing unit including a separation membrane arranged between the feed water receiving unit and the osmosis draw solution receiving unit; a second housing unit for storing the osmosis draw solution which supplies the osmosis draw solution to the first housing unit and recovers the osmosis draw solution; and a recovery device which separates and recovers the solute of the osmosis draw solution.
Abstract:
Provided is an organic-inorganic hybrid compound having antifouling and antimicrobial properties and capable of being used to manufacture a membrane. The organic-inorganic hybrid compound comprises a polyhedral oligomeric silsesquioxane core; and at least one arm connected to at least one of Si atoms in the polyhedral oligomeric silsesquioxane, wherein the arm comprises a vinyl-based first structural unit comprising at least one ethylene oxide group in a side chain; and a vinyl-based second structural unit comprising at least one antimicrobial functional group in a side chain.
Abstract:
PURPOSE: An induced solution for forward osmosis, a forward osmosis-based water treating apparatus using the same, and a forward osmosis-based water treating method are provided to improve water treating effect. CONSTITUTION: An induced solute for forward osmosis includes copolymer containing a first structural unit and a second structural unit. The first structural unit is composed by graft-polymerizing a temperature sensitive oligomer side chain containing a side chain forming structural unit with a temperature sensitive moiety. The second structural unit includes a hydrophilic functional group. The temperature sensitive moiety is a monovalent substituent represented by chemical formula 1, a monovalent substituent represented by chemical formula 2, and divalent substituent represented by chemical formula 3. In chemical formulas 1 to 3, R1 and R2 are respectively hydrogen atoms, linear or branched C3-C5 alkyl groups; either R1 or R2 is not a hydrogen atom; R3 is C3-C5 alkylene group; and R4 is a linear or branched C3-C5 alkyl group.
Abstract:
PURPOSE: A polyacrylonitrile-based copolymer capable of being used for a separator, a manufacturing method of the separator which includes the same, and a water treatment module are provided to obtain high transparent flux and quantity. CONSTITUTION: A polyacrylonitrile-based copolymer comprises a recurring unit which is represented by chemical formula 1, a recurring unit which is represented by chemical formula 2, and a recurring unit which is represented by chemical formula 3. Here, n indicates 0.5-0.99 and m+o is 0.01-0.5 when the total sum of n, m. and o is 1. L^1 and L^2 are respectively - CR 'R"-, -NR' -, -S-, -SO2-, -O-, -COO-, -NR'CO- or a combination thereof. Here, R' and R"are respectively hydrogen, deuterium, substituted or non-substituted C1-10 alkyl group, substituted or non-substituted C6-30 aryl group, substituted or non-substituted C3-30 heteroaryl group, halogen or a combination thereof. R^1 indicates hydrophilic or hydrophobic substituent. R^2 indicates a hydrophilic or hydrophobic substituent.
Abstract translation:目的:提供能够用于隔膜的聚丙烯腈类共聚物,包含该隔膜的隔膜的制造方法和水处理组件,以获得高透明度的通量和数量。 构成:聚丙烯腈系共聚物包含由化学式1表示的重复单元,由化学式2表示的重复单元,由化学式3表示的重复单元。这里,n表示0.5〜0.99, 当总和为n,m时,m + o为0.01-0.5。 L 1和L 2分别为-CR'R“ - , - NR' - , - S - , - SO 2 - , - O - , - COO - , - NR'CO-或其组合 这里,R'和R“分别为氢,氘,取代或未取代的C 1-10烷基,取代或未取代的C 6-30芳基,取代或未取代的C 3-30杂芳基,卤素或 其组合。 R 1表示亲水或疏水取代基。 R 2表示亲水或疏水取代基。