Abstract:
본 발명은 질소산화물 제거용 바나디아-티타니아 촉매 및 그 제조방법에 관한 것이다. 본 발명은 티탄 전구체를 기화시키는 기화단계; 상기 기화된 티탄 전구체 기화물을 산소 공급원과 함께 반응부로 이송시키는 반응물 이송단계; 상기 반응부로 이송된 티탄 전구체 기화물과 산소 공급원을 반응시켜 티타니아 입자를 합성하는 반응단계; 상기 합성된 티타니아 입자를 응축시켜 포집하는 회수단계; 상기 회수된 티타니아 입자와 바나듐 전구체 용액을 혼합하는 혼합단계; 상기 티타니아 입자와 바나듐 전구체 용액의 혼합물을 건조시키는 건조단계; 및 상기 건조된 혼합물을 산소 또는 공기 분위기에서 소성하는 소성단계를 포함하는 질소산화물 제거용 바나디아-티타니아 촉매의 제조방법 및 이에 따라 제조된 바나디아-티타니아 촉매를 제공한다. 본 발명에 따르면, 화학기상응축법을 통해 티타니아 입자(담체)를 제조한 다음, 상기 티타니아 입자(담체)에 함침 및 소성을 통해 바나디아를 담지시켜 제조함으로써, 비표면적이 높고 균일한 미세 나노입자 크기를 가지며 바나디아의 분산도 등이 우수하여, 특히 200℃ 내지 250℃의 저온 영역에서 우수한 질소산화물 제거 효율을 갖는다.
Abstract:
PURPOSE: A manufacturing apparatus of a composite nanoparticle is provided to prevent coagulation between particles by synthesizing a first precursor vaporized product and a second precursor vaporized product in a gas phase in an order through a U-shaped reaction chamber. CONSTITUTION: A manufacturing apparatus of a composite nanoparticle comprises a first precursor feeding unit (100), a second precursor feeding unit (200), a reaction unit (300), an oxygen supplying line (400) and a collecting unit (500). The first precursor feeding unit supplies the first precursor to the reaction unit after vaporizing. The second precursor feeding unit supplies the second precursor to the reaction unit after vaporizing. The reaction unit generates a composite nanoparticle synthesizing the first precursor vaporized product and the second precursor vaporized product. The oxygen supplying line supplies an oxygen source to the reaction unit. The collecting unit collects the composite nanoparticles generated from the reaction unit. The reaction unit comprises a U-shaped reaction chamber (310), a second precursor inlet liquid path (320) and a heat supplying means (330). The U-shaped reaction chamber has a first straight liquid path (312), a curbed liquid path (314), and a second straight liquid path (316).
Abstract:
An apparatus for incinerating waste matters and sludge and a method thereof are provided to incinerate sewage sludge so that it is not necessary to use a sludge exclusive incinerating furnace. An incinerating apparatus(100) is structured so that waste material and sludge are mixed in an incinerating furnace to be incinerated. The incinerating apparatus includes an incinerating furnace(110) having the waste material and the sludge incinerated in reaction to the incinerating air. The incinerating furnace includes a waste inlet(112) and a sludge inlet(113). The waste material and the sludge received in an incinerating chamber(111) of the incinerating furnace react with the incinerating air received through a heat exchanger(120) to be incinerated. The waste material is received from a waste supply source(141) to the incinerating furnace. The waste material supplying source includes a waste storage unit and a waste transfer unit for transferring the stored waste material to the waste material inlet. The waste material incinerated in the incinerating furnace is city waste.
Abstract:
PURPOSE: Provided are an apparatus and a method for synthesis of carbon nanotube by making inverse diffusion flame using oxidizer, fuel and ambient gas, without making vacuum environment. CONSTITUTION: The method comprises the step of synthesizing a carbon nanotube by making inverse diffusion flame(10) which is consisted of an oxidizer(1), fuel(2) surrounding the oxidizer(1), and ambient gas(3) surrounding the fuel(2) to intercept air, thereby synthesizing carbon nanotube without vacuum condition. The apparatus includes a combustor(9) with an oxidizer inlet for receiving oxidizer(1) therethrough, a fuel inlet for receiving fuel(2) therethrough, and an ambient gas inlet for receiving ambient gas(3) therethrough to make an inverse diffusion flame(10) being consisted of an oxidizer(1), fuel(2) surrounding the oxidizer(1), and ambient gas(3) surrounding the fuel to intercept air.
Abstract:
The present invention relates to a titania carrier for supporting a catalyst for removing nitrogen oxide, a manganese oxide-titania catalyst comprising the same, an apparatus for manufacturing the titania carrier and the manganese oxide-titania catalyst, a method for manufacturing the titania carrier and the manganese oxide-titania catalyst, and a method for removing nitrogen oxide. The present invention provides a titania carrier, a manufacturing apparatus thereof and a manufacturing method thereof, wherein the titania carrier has a specific surface area of 100 to 150 m^2/g, an average pore volume of 0.1 to 0.2 cm^3/g, and an average particle size of 5 to 20 nm. Also the present invention provides a manganese oxide-titania catalyst having manganese oxide supported on the titania carrier, a manufacturing method thereof, and a method for removing nitrogen oxide using the catalyst. The catalyst according to the present invention has high activity and dispersibility, and thus provides excellent denitrogenation efficiency even in a low temperature range of about 200°C.
Abstract:
PURPOSE: A method and an apparatus for treating volatile organic compound are provided to safely eliminate volatile organic compound without the generation of secondary pollutants such as ozone. CONSTITUTION: A method for treating volatile organic compound includes the following: ozone is generated in an ozone generator(1) based on an ultraviolet ray-based lamp reactor or a plasma reactor; and reaction activating radical generated by treating the generated ozone based on catalyst in the form of a catalyst layer(3), and volatile organic compound is decomposed by the reaction activating radical. While the ozone is generated, the generating amount of the ozone is determined based on the concentration of the volatile organic compound contained in the air.
Abstract:
PURPOSE: An apparatus for reducing concentration of polychlorinated biphenyl contained in waste oil is provided, which prevents explosion due to contact with air. CONSTITUTION: An apparatus for reducing concentration of polychlorinated biphenyl contained in waste oil comprises an oil tank(271); a pipe(272) for supply of oil; a tank(275) for manufacturing powder metallic sodium; a pulverizing device(277) which pulverizes metallic sodium lump into fine powder; a powder metallic sodium-containing oil outflow tube(278); a second waste oil delivery pipe(279) in which waste oil containing polychlorinated biphenyl is provided; and a mixture reaction tube(282) in which degradation process is performed.
Abstract:
A method for reducing mercury from fuel gas is provided to significantly reduce the mercury from the fuel gas, thereby performing a bio-friendly operation of combustion facilities, by using halogenated compound-impregnated activated carbon. Mercury from fuel gas is reduced by directly mixing halogenated compound-impregnated activated carbon into discharge gas in a power type, installing a fixation-type adsorbing tower of halogenated compound-impregnated activated carbon, or performing the combination thereof. The halogenated compound-impregnated activated carbon is KI-impregnated activated carbon, or HCl-impregnated activated carbon.