Abstract:
PURPOSE: A pyrolysis process and an operation method thereof are provided to successively operate, to conveniently drive, and to increase thermal efficiency and operating ratio. CONSTITUTION: An operation method of a pyrolysis process comprises the following steps: inserting pre-treated raw materials into a raw material melting bath (13); melting the raw materials by heating exterior wall of the raw material melting bath using a burner or high temperature exhaust gas comes from a pyrolysis reactor (15); measuring the melted raw materials through a melted material measuring tub (14) and adding into the pyrolysis reactor; heating the melted raw materials in the pyrolysis reactor at 350-450 deg. Celsius and pyrolyzing the same; storing liquefied gasoline which is produced by transferring vapor through a wax reduction device (16-1), a gasoline purifier (24) and a condenser(25) in a gasoline collection tank (24); withdrawing sludge after pyrolysis and sending the same to a sludge reactor(18); completely pyrolyzing sludge and forming into powder residue; cooling the powder residue down to approximately 150 deg. Celsius; and repeatedly discharging the cooled residue and storing in the residue collection tank.
Abstract:
본 발명은 추출탑 내부에 고전압의 전기장을 인가하여 초중질원유 내 아스팔텐을 효과적으로 제거하는 초중질원유의 정제방법 및 정제장치에 관한 것으로, 더욱 상세하게는 탄소수 3~8개의 탄화수소로 구성된 용매와 초중질원유를 혼합하고 이에 고전압의 전기장을 인가하여 초중질원유 내의 아스팔텐 분산 특성을 변화시킴으로써 초중질원유의 응집을 유도하고 이와 동시에 용매와 초중질원유의 접촉을 원활히 하여 용매 추출 효과를 극대화한 다음, 전기장 인가를 중지하여 상부의 아스팔텐 제거 오일 층과 하부의 아스팔텐 층으로 분리시킴으로써 아스팔텐이 제거된 원유를 회수하는 방법 및 장치에 관한 것이다. 즉, 본 발명은 간단한 공정 구성과 온화한 조업 조건을 특징으로 하므로 기존의 탈아스팔텐 용매 추출 공정이 안고 있던 막대한 장치비 및 에너지 다소비 문제를 해결하여 초중질원유 고도화에 소요되는 설치, 운전 비용을 감소할 수 있는 것이다.
Abstract:
본 발명은 2가지 이상의 금속이 결합된 수산화물 계열 전구체의 표면 개질을 통한 유용성(Oil-Soluble) 입자 제조방법에 관한 것이다. 더욱 상세하게는 서로 다른 금속들의 결합으로 이루어진 유용성 입자를 제조하는 것으로, 서로 다른 금속염들을 유기산들과 동시에 혼합하여 유용성 입자로 제조하는 대신에 금속들의 비율 조정 및 제조가 용이한 수산화물 계열 전구체들을 먼저 제조한 후에 유기산들과의 반응을 유도하여 유용성 입자로 제조하는 것을 특징으로 한다. 금속결합 수산화물 계열 전구체, 표면개질, 유용성, 에스테르 반응
Abstract:
본 발명은 특정의 용매인 화학식 1의 용매를 사용하여 상온(15~30)에서 초중질원유를 용해시키고, 극성 유기용매와 비극성 용매를 가함으로써 초중질원유를 경질화하는 방법에 관한 것으로서, 더욱 상세하게는 상온(15~30)에서 오일샌드 비튜멘, 천연역청, 감압잔사유 등의 초중질원유에 특정의 용매 및 극성 유기용매를 가하여, 상부의 아스팔텐 분산제와 극성 유기용매, 레진 성분이 용해된 극성 유기용매층과 하부의 고농축 초중질원유 층으로 분리한 다음, 하부에 탄화수소비극성 유기용매를 가하여 다시 상부의 탈아스팔텐 오일 층과 하부의 아스팔텐 층으로 분리함으로써 초중질원유를 경질화하는 방법에 관한 것이다. 즉, 본 발명은 기존의 초중질원유의 경질화공정이 안고 있던 막대한 장치비 및 에너지 다소비 문제를 해결하여 초중질원유의 경질화에 소요되는 설치, 운전 비용을 감소할 수 있는 것이다.
Abstract:
A sludge injecting apparatus which has a simple structure, and improves the crushing efficiency by intermittently feeding compressed inert gas into a crushing equipment such that sludge is crushed well by an impact of gas applied to the sludge in addition to mechanical crushing of the crushing equipment, and a pyrolysis system having the sludge injecting apparatus are provided. A sludge injecting apparatus comprises: a cylindrical main body(210) including a body consisted of a cylindrical part(212) and a conical tapered part(213), a sludge inflow port(214) and a sludge discharge port(216), and connecting flanges(215,217); an impact generating part(220) which is connected to a lower part of the main body and intermittently generates a gas impact to discharge the gas impact into the main body, the impact generating part including an impact generator(223), a gas inflow pipe(222), and a gas exhaust pipe(227); a first valve(240) which is installed at the sludge inflow port side to control inflow of sludge, and includes a valve plate(241), a traction rack(242), a pinion(243), and a motor(244); and a second valve installed at the sludge discharge port side to control discharge of sludge. The sludge injecting apparatus further comprises an exhaust part(230) including an exhaust pipe(231), a filter part(232), and a sound arrester(235).
Abstract:
A fuel oil refining device and a pyrolysis system having the same are provided to improve the quality of fuel oil by successively passing various impurities and harmful gas included in the fuel oil distilled in a distillation tower through plural refining tanks. In the pyrolysis system, the fuel oil refining device(200) is composed of a first refining tank(10) for receiving fuel oil including impurities and filtering large particles of the fuel oil through an envelop-shaped bag filter; a second refining tank(20) for filtering fine particles of the fuel oil refined in the first refining tank by a first rod-shaped cartridge filter installed inside; a third refining tank(30) for filtering hyperfine particles and moisture of the fuel oil refined in the second refining tank by second and third cartridge filters installed inside; and a fourth refining tank(40) receiving the fuel oil refined in the third refining tank and filtering harmful chemical components by passing the fuel oil through a fourth cartridge filter made of carbons.
Abstract:
The present invention relates to an indirect gasifier with a dual bubbling fluidized bed. The indirect gasifier comprises: a first bubbling fluidized bed reactor (100) including a gasification area (110) in which materials to be gasified are fed and gasified to be discharged as a synthetic gas; and a second bubbling fluidized bed reactor (200) that is installed adjacent to the first bubbling fluidized bed reactor (100) with a wall (300) therebetween and includes a combustion area (210) in which materials to be combusted are fed and combusted to be discharged as a combusted gas. A fluid sand transferring device (400) is installed on the wall (300) so as to move the gasification area (110) and combustion area (210), so that heat that is generated during combustion in the combustion area (210) is transferred to the gasification area (110). According to the configuration of the present invention, fluid sand is circulated by being horizontally moved in two bubbling fluidized bed reaction areas so that heat that is generated during combustion is transferred to the gasification area (110) and raw materials, which are fed in the indirect gasifier, are gasified. Fluid sand can be horizontally circulated so that the indirect gasifier can be stably and easily operated.
Abstract:
본 발명은 생활계 혼합 폐플라스틱을 열분해하여 생성된 저급 왁스 오일을 제올라이트계 촉매 존재하에서 열분해하여 고급 탄화수소로 전환시키는 방법에 관한 것이다. 보다 구체적으로, 본 발명은 폴리올레핀계가 주성분인 필름유의 혼합 폐플라스틱을 고온의 상용 로터리 킬른(rotary kiln) 반응 장치에서 열분해하여 얻은 왁스 오일을 제올라이트계 촉매하에서 열분해하여 탄소수 5개 내지 40개인 고급 탄화수소로 전환시키는 방법에 관한 것이다.
Abstract:
PURPOSE: A transforming method of wax oil obtained by hydrolyzing waste plastic into high class light oil is provided to catalyst-decomposing the wax oil using a zeolite based catalyst. CONSTITUTION: A transforming method of wax oil obtained by hydrolyzing waste plastic into high class light oil comprises a step of hydrolyzing the waste plastic to obtain the low class wax oil with 5-40 carbons including normal paraffin and normal olefin as main components at 350-450 deg C, under the presence of a zeolite based catalyst. The zeolite based catalyst is a ZSM-5 catalyst or a zeolite Y catalyst.
Abstract:
PURPOSE: A continuous processing method of a batch type process for producing recycled fuel oil from waste plastic is provided to convert a batch type thermal cracking process into a continuous thermal cracking process by adding some apparatuses to the batch type thermal cracking process and remodeling a conventional apparatus. CONSTITUTION: A continuous processing method of a batch type process for producing recycled fuel oil from waste plastic comprises the steps of: transferring residue sludge stacked in a thermal cracking step to a sludge reactor(9); leaving the powdery residue at the back end of the sludge reactor and transferring the residue to a residue transfer device(10) by thermally cracking the transferred sludge in the sludge reactor at a temperature of 410 - 460°C; and transferring the residue to a cooling device(12) through the residue transfer device and storing the cooled residue in a storage device(13).