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公开(公告)号：WO2011059228A2
公开(公告)日：2011-05-19
申请号：PCT/KR2010/007916
申请日：2010-11-10
Applicant: 한국에너지기술연구원 , 전상구 , 노남선 , 신대현 , 김광호
CPC classification number: C10G49/04 , B01J31/2239 , B01J2231/64 , B01J2531/0216 , B01J2531/16 , B01J2531/31 , B01J2531/64 , B01J2531/66 , B01J2531/72 , B01J2531/842 , B01J2531/847
Abstract: 본 발명은 유용성(Oil-soluble) 몰리브데늄 계열 이금속 촉매의 제조방법 및 이를 이용한 중질유의 수소화 전환방법에 관한 것으로, 높은 비점의 중질유(重質油)를 낮은 비점의 경질유(輕質油)로 전환시키기 위하여 유용성 몰리브데늄 계열 이금속 촉매를 제조하고 중질유을 촉매 수소화 전환하는 방법에 관한 것이다. 이를 위하여 유용성으로 제조가 어려운 몰리브데늄 이금속 촉매를 수산화물 전구체를 경유하여 제조함으로써 금속들의 비율 조정 및 제조가 용이하도록 하며, 중질유의 수소화 전환반응 시 유용성 촉매를 사용함에 따라 분산효과가 뛰어나 수소화 전환반응에서 소량의 촉매만을 사용하여도 우수한 반응 효과를 기대할 수 있도록 하는 것이다.
Abstract translation: 本发明涉及一种油溶性钼基双金属催化剂的制备方法和使用其的重油的加氢转化方法，其中为了将具有高沸点的重油转化为具有 制备低沸点的油溶性钼基双金属催化剂，并用催化剂将重油加氢转化。 为此，通过氢氧化物前体制备难以制备成油溶性的钼基双金属催化剂，从而能够容易地控制金属比例和容易制备催化剂。 并且，由于在重油的加氢转化中使用油溶性而分散效果优异，因此即使在加氢转化中使用少量的催化剂也能够预期出色的反应效果。
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2.发明申请2가지 이상의 금속이 결합된 수산화물 계열 전구체의 표면 개질을 통한 유용성 입자 제조방법 审中-公开一种通过表面改性具有两种或更多种键合于其上的金属的氢氧化物基前体来制备油溶性粒子的方法
公开(公告)号：WO2011059226A3
公开(公告)日：2011-05-19
申请号：PCT/KR2010/007914
申请日：2010-11-10
Applicant: 한국에너지기술연구원 , 전상구 , 노남선 , 신대현 , 김광호
Abstract: 본 발명은 2가지 이상의 금속이 결합된 수산화물 계열 전구체의 표면 개질을 통한 유용성(Oil-Soluble) 입자 제조방법에 관한 것이다. 더욱 상세하게는 서로 다른 금속들의 결합으로 이루어진 유용성 입자를 제조하는 것으로, 서로 다른 금속염들을 유기산들과 동시에 혼합하여 유용성 입자로 제조하는 대신에 금속들의 비율 조정 및 제조가 용이한 수산화물 계열 전구체들을 먼저 제조한 후에 유기산들과의 반응을 유도하여 유용성 입자로 제조하는 것을 특징으로 한다.
Abstract translation: 本发明涉及通过表面改性两种或更多种金属键合氢氧化物基前体来生产油溶性粒子的方法。 更具体地说，本发明涉及制备油溶性前体的方法，该方法可以容易地调节比例并制备金属，而不是通过将不同的金属盐与有机酸同时混合来制备油溶性颗粒。 然后与有机酸反应生成油溶性颗粒。
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公开(公告)号：KR101892589B1
公开(公告)日：2018-08-28
申请号：KR1020150081863
申请日：2015-06-10
Applicant: 한국에너지기술연구원
Abstract: 본발명은오일샌드에포함된아스팔텐의산화를유도하여오일샌드로부터아스팔텐을활용하는방법에관한것으로, 오일샌드에포함된아스팔텐의산화를유도하여생성된산화아스팔텐을이용하여거품처리공정을포함한업스트림에서첨가제로서역할을하여용매사용량감소와더불어아스팔텐을석출되도록유도하며다운스트림공정에서희석제로서역할을하여개질공정으로의이송을위한점도를조절하는방법으로산화아스팔텐을공정내 투입하여아스팔텐을제거하거나이송중오일샌드의점도를낮출수 있어유기용매또는희석제를사용하지않거나기존에비해사용량을줄일수 있다는효과가있다.
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公开(公告)号：KR1020160145368A
公开(公告)日：2016-12-20
申请号：KR1020150081863
申请日：2015-06-10
Applicant: 한국에너지기술연구원
Abstract: 본발명은오일샌드에포함된아스팔텐의산화를유도하여오일샌드로부터아스팔텐을활용하는방법에관한것으로, 오일샌드에포함된아스팔텐의산화를유도하여생성된산화아스팔텐을이용하여거품처리공정을포함한업스트림에서첨가제로서역할을하여용매사용량감소와더불어아스팔텐을석출되도록유도하며다운스트림공정에서희석제로서역할을하여개질공정으로의이송을위한점도를조절하는방법으로산화아스팔텐을공정내 투입하여아스팔텐을제거하거나이송중오일샌드의점도를낮출수 있어유기용매또는희석제를사용하지않거나기존에비해사용량을줄일수 있다는효과가있다.
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公开(公告)号：KR1020140058979A
公开(公告)日：2014-05-15
申请号：KR1020120125511
申请日：2012-11-07
Applicant: 한국에너지기술연구원
CPC classification number: B01J8/1872 , C10J3/48
Abstract: The present invention relates to an indirect gasifier with a dual bubbling fluidized bed. The indirect gasifier comprises: a first bubbling fluidized bed reactor (100) including a gasification area (110) in which materials to be gasified are fed and gasified to be discharged as a synthetic gas; and a second bubbling fluidized bed reactor (200) that is installed adjacent to the first bubbling fluidized bed reactor (100) with a wall (300) therebetween and includes a combustion area (210) in which materials to be combusted are fed and combusted to be discharged as a combusted gas. A fluid sand transferring device (400) is installed on the wall (300) so as to move the gasification area (110) and combustion area (210), so that heat that is generated during combustion in the combustion area (210) is transferred to the gasification area (110). According to the configuration of the present invention, fluid sand is circulated by being horizontally moved in two bubbling fluidized bed reaction areas so that heat that is generated during combustion is transferred to the gasification area (110) and raw materials, which are fed in the indirect gasifier, are gasified. Fluid sand can be horizontally circulated so that the indirect gasifier can be stably and easily operated.
Abstract translation: 本发明涉及具有双重鼓泡流化床的间接气化器。 间接气化器包括：第一鼓泡流化床反应器（100），其包括气化区域（110），其中待气化的材料被气化并气化以作为合成气体排出; 和与第一鼓泡流化床反应器（100）相邻的第二鼓泡流化床反应器（200），其间具有壁（300），并且包括燃烧区域（210），其中待燃烧的材料被进料并燃烧至 作为燃烧气体排放。 流体砂输送装置（400）安装在壁（300）上，以便移动气化区（110）和燃烧区（210），使得在燃烧区域（210）中的燃烧期间产生的热量被转移 到气化区域（110）。 根据本发明的结构，流体砂通过在两个鼓泡流化床反应区域中水平移动而循环，使得在燃烧期间产生的热量被转移到气化区域（110）和原料 间接气化器气化。 流砂可以水平循环，使得间接气化器可以稳定和容易地操作。
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Patent Agency Ranking
公开(公告)号：KR1020110075308A
公开(公告)日：2011-07-06
申请号：KR1020090131725
申请日：2009-12-28
Applicant: 한국에너지기술연구원
CPC classification number: Y02W30/703
Abstract: PURPOSE: A continuous processing method of a batch type process for producing recycled fuel oil from waste plastic is provided to convert a batch type thermal cracking process into a continuous thermal cracking process by adding some apparatuses to the batch type thermal cracking process and remodeling a conventional apparatus. CONSTITUTION: A continuous processing method of a batch type process for producing recycled fuel oil from waste plastic comprises the steps of: transferring residue sludge stacked in a thermal cracking step to a sludge reactor(9); leaving the powdery residue at the back end of the sludge reactor and transferring the residue to a residue transfer device(10) by thermally cracking the transferred sludge in the sludge reactor at a temperature of 410 - 460°C; and transferring the residue to a cooling device(12) through the residue transfer device and storing the cooled residue in a storage device(13).
Abstract translation: 目的：提供一种用于从废塑料生产回收燃料油的间歇式方法的连续加工方法，通过向批式热裂解工艺添加一些装置并将常规 仪器。 构成：用于从废塑料生产回收燃料油的间歇式方法的连续加工方法包括以下步骤：将在热裂解步骤中堆叠的残渣污泥转移至污泥反应器（9）; 在污泥反应器的后端留下粉末残留物，并通过在410-460℃的温度下对污泥反应器中转移的污泥进行热裂化将残余物转移到残余物转移装置（10）; 并通过残余物转移装置将残余物转移到冷却装置（12），并将冷却的残余物储存在存储装置（13）中。
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7.发明公开
公开(公告)号：KR1020110051330A
公开(公告)日：2011-05-18
申请号：KR1020090107842
申请日：2009-11-10
Applicant: 한국에너지기술연구원
CPC classification number: C07F15/065 , C01G39/02 , B82Y30/00 , B82Y40/00 , C01G51/04 , C01P2004/64
Abstract: PURPOSE: A method for preparing oil-soluble particles is provided to obtain the oil-soluble particles based on various metal by inducing the reaction with organic acid after a hydroxide-based precursor is prepared. CONSTITUTION: Two or more metal compound aqueous solutions are mixed and stirred(S11). The pH of the mixed aqueous solution is controlled between 5.0 and 10.0 in order to cause coprecipitation. Precipitate is collected through the coprecipitation(S12). A hydroxide-based precursor combined with two or more metal is prepared. The surface of the hydroxide-based precursor is modified using organic acid through an esterification reaction. The organic acid is one selected from a group including aliphatic acid, alicyclic acid, aromatic acid, phosphorus-containing acid.
Abstract translation: 目的：提供一种制备油溶性颗粒的方法，通过在制备基于氢氧化物的前体之后通过诱导与有机酸的反应，获得基于各种金属的油溶性颗粒。 构成：将两种以上的金属化合物水溶液混合搅拌（S11）。 将混合水溶液的pH控制在5.0和10.0之间以引起共沉淀。 通过共沉淀收集沉淀物（S12）。 制备与两种或更多种金属组合的基于氢氧化物的前体。 基于氢氧化物的前体的表面通过酯化反应用有机酸改性。 有机酸是选自脂肪酸，脂环族酸，芳香酸，含磷酸的组中的一种。
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公开(公告)号：KR100922366B1
公开(公告)日：2009-10-19
申请号：KR1020070122429
申请日：2007-11-29
Applicant: 한국에너지기술연구원
IPC: C10G25/02
Abstract: 본 발명은 염소 성분을 제거하기 위한 연료유 정제장치에 관한 것으로, 더 상세하게는 폐플라스틱을 열분해하여 수득한 연료유 중 대부분을 차지하는 저급연료유를 경제성이 있는 고품질로 정제하기 위한 연료유정제장치를 제공하되, 특히 염소성분을 효과적으로 제거하기 위하여 화학정제장치 및 물-오일분리기와 물-오일혼합기의 분리 및 혼합효율을 더욱 향상시키기 위한 고효율 염소제거장치를 구비한 연료유정제장치에 관한 것이다.
염소제거장치, 저급 열분해유, 정제장치, 폐플라스틱, 열분해, 효율향상-
公开(公告)号：KR100824965B1
公开(公告)日：2008-04-28
申请号：KR1020070043953
申请日：2007-05-07
Applicant: 한국에너지기술연구원
CPC classification number: C10L1/32 , C10G1/10 , C10L2250/08 , C10L2290/02 , C10L2290/24 , C10L2290/543 , C10L2290/547
Abstract: A fuel oil-refining apparatus is provided to remove chloride components contained in fuel oil, which is obtained by treating waste plastic or waste oil, thereby producing high-quality fuel oil without chloride components. A chemical refinement unit(60) mixes low-quality fuel oil and basic aqueous solution, wherein the low-quality fuel oil is prepared by pyrolyzing and distilling one component selected from waste plastic, waste synthetic resin, waste rubber, or waste oil. A water-oil separator(70) separates fuel oil from the mixture of the fuel oil and the basic aqueous solution. A horizontal partition wall(730) is disposed in the middle of the water-oil separator to divide an inside space of the water-oil separator into a first space(710) and a second space(720). Upper portions of the first space and the second space communicate with each other. Further, a fuel oil-refining apparatus(200) additionally contains a water-oil mixer(80) at an upper part of the chemical refinement unit.
Abstract translation: 提供燃料油精炼装置以除去通过处理废塑料或废油获得的燃料油中所含的氯化物成分，由此生产没有氯化物组分的高质量燃料油。 化学精制单元（60）将低质量燃料油和碱性水溶液混合，其中低质量燃料油通过热解和蒸馏选自废塑料，废合成树脂，废橡胶或废油中的一种组分来制备。 油 - 油分离器（70）将燃料油与燃料油和碱性水溶液的混合物分离。 水分隔壁（730）设置在水 - 油分离器的中间以将油水分离器的内部空间分成第一空间（710）和第二空间（720）。 第一空间和第二空间的上部彼此连通。 此外，燃料精炼装置（200）另外在化学精制装置的上部还含有水 - 油混合器（80）。
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公开(公告)号：KR100464167B1
公开(公告)日：2005-01-03
申请号：KR1020020010366
申请日：2002-02-27
Applicant: 한국에너지기술연구원
Abstract: PURPOSE: A catalyst embedded multistep low temperature plasma reactor is provided which is capable of controlling desired reaction according to types of catalyst used by minimizing a time required for radicals generated in the plasma region to reach the catalyst region. CONSTITUTION: In treating air pollutants such as nitrogen oxides, sulfur oxides and volatile organic compounds, the catalyst embedded multistep low temperature plasma reactor is characterized in that an upper duct(1) on which inlet is formed is connected to a reactor main body(3) formed in multistep through an upper flange(2), a lower duct(5) on which outlet is formed is connected to reactor main body(3') through a lower flange(6), upper supports(9,9') are connected to lower supports(8,8') on which bar type electrodes(7,7') are formed in the respective reactor main bodies(3,3'), catalyst (C) is charged into the supports(8,8',9,9'), and catalyst grounding electrode and catalyst discharging electrode at which meshes(10,10') and wires(11,11') are installed are inserted into upper and lower parts of the supports(8,8',9,9'), wherein the reactor main bodies(3,3') are fabricated of Teflon, alumina or ceramics, and the catalyst electrodes are fabricated of stainless steel, Teflon, alumina or ceramics, wherein honeycomb shaped particulate catalyst (C) such as Cu/ZSM-5 based catalyst, photocatalyst, mixed photocatalyst, SCR catalyst and oxidation catalyst is charged into cylinder of the catalyst electrodes, and wherein the catalyst grounding electrode and catalyst discharging electrode are connected in series to easily control capacity of the reactor.
Abstract translation: 目的：提供一种催化剂嵌入的多步低温等离子体反应器，其能够根据所使用的催化剂类型来控制期望的反应，其通过最小化在等离子体区域中产生的自由基到达催化剂区域所需的时间。 本发明公开了一种催化剂埋入式多级低温等离子体反应器，在处理空气污染物如氮氧化物，硫氧化物和挥发性有机化合物时，其特征在于：形成入口的上导管（1）与反应器主体（3） ）通过上部凸缘（2）形成为多级，形成有出口的下部管道（5）通过下部凸缘（6）与反应器主体（3'）连接，上部支撑体（9,9'）为 （3,3'）上形成有棒状电极（7,7'）的下部支承体（8,8'）上，将催化剂（C）填充到支承体（8,8' ，9,9'）以及在其上安装网眼（10,10'）和导线（11,11'）的催化剂接地电极和催化剂放电电极被插入到支撑件（8,8'，8,9'）的上部和下部中， 9,3'），其中反应器主体（3,3'）由聚四氟乙烯，氧化铝或陶瓷制成，并且催化剂电极由不锈钢，聚四氟乙烯，氧化铝或c 在催化剂电极的圆筒内填充Cu / ZSM-5系催化剂，光催化剂，混合光催化剂，SCR催化剂，氧化催化剂等蜂窝状颗粒状催化剂（C），催化剂接地电极和催化剂放电电极为 串联连接以容易地控制反应器的容量。
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