METHOD OF MAKING PRECISION-MOLDED ARTICLES BY POLYMERIZING ETHYLENICALLY-UNSATURATED MATERIALS IN A MOLD USING IONIZING RADIATION
    12.
    发明申请
    METHOD OF MAKING PRECISION-MOLDED ARTICLES BY POLYMERIZING ETHYLENICALLY-UNSATURATED MATERIALS IN A MOLD USING IONIZING RADIATION 审中-公开
    通过使用离子辐射在模具中聚合乙烯基不饱和材料制备精密模制品的方法

    公开(公告)号:US20150298366A1

    公开(公告)日:2015-10-22

    申请号:US14648055

    申请日:2013-12-06

    Abstract: Methods of (co)polymerizing ethylenically-unsaturated materials, including the steps of providing a mixture of free radically (co)polymerizable ethylenically-unsaturated material in a mold, exposing the mixture in the mold to a source of ionizing radiation for a time sufficient to initiate (co)polymerization of at least a portion of the free radically (co)polymerizable ethylenically-unsaturated material, and allowing the free radically (co)polymerizable ethylenically-unsaturated material to (co)polymerize in the mold while continuing to expose the mixture to the source of ionizing radiation for a time sufficient to yield an at least partially (co)polymerized (co)polymer. The ethylenically-unsaturated materials are selected from vinyl-functional monomers, vinyl-functional oligomers, vinyl-functional macromers, and combinations thereof. The mixture is preferably free of thermally-induced or UV-induced free radical polymerization initiators. The source of ionizing radiation may be a gamma ray source, an x-ray source, an electron beam source with an emission energy greater than 300 keV, and combinations thereof.

    Abstract translation: (共)聚合烯属不饱和材料的方法,包括以下步骤:在模具中提供自由基(共)可聚合的烯属不饱和材料的混合物,将模具中的混合物暴露于电离辐射源,时间足以 引发至少一部分自由基(共)可聚合烯键式不饱和材料的共 - 聚合,并允许自由基(共)可聚合的烯属不饱和材料在模具中(共)聚合,同时继续暴露混合物 到电离辐射源一段足以产生至少部分(共)聚合(共)聚合物的时间。 烯键式不饱和材料选自乙烯基官能单体,乙烯基官能低聚物,乙烯基官能大分子单体及其组合。 该混合物优选不含热诱导或UV诱导的自由基聚合引发剂。 电离辐射源可以是伽马射线源,x射线源,发射能量大于300keV的电子束源及其组合。

    RETROREFLECTIVE ARTICLES AND DEVICES HAVING VISCOELASTIC LIGHTGUIDE
    14.
    发明申请
    RETROREFLECTIVE ARTICLES AND DEVICES HAVING VISCOELASTIC LIGHTGUIDE 审中-公开
    回归物品和具有粘弹性光泽的装置

    公开(公告)号:US20140160764A1

    公开(公告)日:2014-06-12

    申请号:US14177332

    申请日:2014-02-11

    Abstract: Disclosed herein is an optical device having a light source, a viscoelastic lightguide and a retroreflective film suitable for retroreflecting light. Light from the light source enters the viscoelastic lightguide and is transported within the lightguide by total internal reflection. The transported light is extracted from the lightguide and retroreflected at a structured surface of the retroreflective film. The optical device may have a “front lit” or a “back lit” configuration depending on the relative positioning of the lightguide and the retroreflective film. The retroreflective film may include prismatic retroreflective sheeting, holographic film or film structured with diffraction gratings. The optical device may be used, for example, as a sign or marking, a license plate assembly, a tail light assembly for vehicles, a security laminate for protection of documents against tampering, or an illumination device.

    Abstract translation: 本文公开了一种具有光源,粘弹性光导和适于回射光的回射膜的光学装置。 来自光源的光进入粘弹性光导,并通过全内反射在光导内传输。 被输送的光从光导中提取出来并在回射膜的结构化表面回射。 根据光导和逆反射膜的相对定位,光学装置可以具有“前灯”或“背光”配置。 回射膜可以包括棱镜式反光片,全息膜或由衍射光栅构成的膜。 光学装置可以例如用作标志或标记,车牌组件,用于车辆的尾灯组件,用于保护文件免受篡改的安全层压板或照明装置。

    METHOD OF POLYMERIZING ETHYLENICALLY-UNSATURATED MATERIALS USING IONIZING RADIATION
    19.
    发明申请
    METHOD OF POLYMERIZING ETHYLENICALLY-UNSATURATED MATERIALS USING IONIZING RADIATION 有权
    使用离子化辐射聚合乙烯基不饱和材料的方法

    公开(公告)号:US20150299532A1

    公开(公告)日:2015-10-22

    申请号:US14647924

    申请日:2013-12-06

    Abstract: Methods of (co)polymerizing ethylenically-unsaturated materials, including the steps of providing a non-deaerated mixture of free radically (co)polymerizable ethylenically-unsaturated material in a batch reactor, exposing the non-deaerated mixture to a source of ionizing radiation for a time sufficient to initiate (co)polymerization of at least a portion of the free radically (co)polymerizable ethylenically-unsaturated material, and allowing the free radically (co)polymerizable ethylenically-unsaturated material to (co)polymerize under essentially adiabatic conditions while continuing to expose the mixture to the source of ionizing radiation for a time sufficient to yield an at least partially (co)polymerized (co)polymer. The ethylenically-unsaturated materials are selected from vinyl-functional monomers, vinyl-functional oligomers, vinyl-functional macromers, and combinations thereof. The mixture is preferably free of thermally-induced or UV-induced free radical polymerization initiators. The source of ionizing radiation may be a gamma ray source, an x ray source, an electron beam source with an emission energy greater than 300 keV, and combinations thereof.

    Abstract translation: (共)聚合烯属不饱和材料的方法,包括以下步骤:在间歇式反应器中提供自由基(共)可聚合烯属不饱和材料的非脱气混合物,将未脱气的混合物暴露于电离辐射源 足以引发(共)聚合自由基(共)可聚合的烯属不饱和材料的至少一部分的聚合,并且允许自由基(共)可聚合的烯属不饱和材料在基本上绝热的条件下(共)聚合,同时 继续将混合物暴露于电离辐射源一段足以产生至少部分(共)聚合(共)聚合物的时间。 烯键式不饱和材料选自乙烯基官能单体,乙烯基官能低聚物,乙烯基官能大分子单体及其组合。 该混合物优选不含热诱导或UV诱导的自由基聚合引发剂。 电离辐射源可以是伽马射线源,x射线源,发射能量大于300keV的电子束源及其组合。

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