公开(公告)号：US11168164B2

公开(公告)日：2021-11-09

申请号：US16341959

申请日：2017-08-22

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Nicole Morozowich Beveridge ,  Ross E. Behling ,  Anish Kurian ,  Mark F. Ellis ,  Karl E. Benson ,  Michele A. Craton ,  Daniel C. Munson ,  David J. Yarusso

IPC: C09J7/38 ,  C09J133/08 ,  C09J133/10 ,  C08F2/48 ,  C08F220/18 ,  C09J133/14

Abstract: Crosslinkable compositions, crosslinked compositions, articles containing these compositions, and methods of making the articles are provided. The crosslinkable compositions, which include two (meth)acrylate polymers, are used to form the crosslinked compositions upon exposure to ultraviolet radiation. The crosslinkable and crosslinked compositions are free or substantially free of tackifiers. The crosslinked compositions can function as pressure-sensitive adhesives. The crosslinkable compositions are well suited for use with hot melt processing methods.

公开(公告)号：US20170283670A1

公开(公告)日：2017-10-05

申请号：US15615425

申请日：2017-06-06

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： David J. Yarusso ,  Thu-Van T. Tran ,  Soyoung Kim ,  Ross E. Behling ,  Karl E. Benson

IPC: C09J133/10 ,  C08L33/10 ,  B32B27/30 ,  C09J133/26

CPC classification number: C09J133/10 ,  B32B27/306 ,  B32B2307/306 ,  C08F220/18 ,  C08F265/06 ,  C08F290/046 ,  C08L23/02 ,  C08L33/08 ,  C08L33/10 ,  C08L33/26 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2205/05 ,  C09J133/08 ,  C09J133/26 ,  C09J155/005 ,  C08F2220/1858 ,  C08F220/56

Abstract: An adhesive composition includes a first acrylic polymer preparable from first components and a second acrylic polymer. The first components comprising i) a branched first alkyl (meth)acrylate having from 4 to 22 carbon atoms, and ii) at least one of acrylic acid and methacrylic acid. The second acrylic polymer is preparable from second components comprising iii) at least one second alkyl (meth)acrylate having from 4 to 22 carbon atoms, iv) a (meth)acrylamide represented by the formula wherein R1 is H or methyl, and R2 and R3 each independently represents H or an alkyl group having from 1 to 8 carbon atoms, or taken together R2 and R3 may form a divalent alkylene group having from 4 to 6 carbon atoms, and v) at least one high Tg macromer having a terminal free-radically polymerizable unsaturated group, the high Tg macromer having a Tg of at least 45° C. Based on the combined total weight of the at least one first acrylic polymer and the at least one second acrylic polymer, the at least one second acrylic polymer is present at a level of from 5 to 40 percent by weight. Methods of making the adhesive composition are also disclosed.

公开(公告)号：US10975221B2

公开(公告)日：2021-04-13

申请号：US16344051

申请日：2017-10-17

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Shijing Cheng ,  Sheng Ye ,  David J. Yarusso ,  Jianhui Xia

IPC: C08F2/46 ,  C08F2/50 ,  C08G61/04 ,  C08K5/07 ,  C09J7/38 ,  C08K5/00 ,  C08K5/45 ,  C08K5/56 ,  C08L33/10 ,  C09J133/10 ,  C09J133/02

Abstract: The present disclosure provides a crosslinkable composition including a (meth)acrylate polymer and a visible light absorbing compound. Two percent or less of the carbon-carbon bonds in the crosslinkable composition are double bonds. The composition allows for inclusion of one or more materials degradable by ultraviolet radiation and/or stabilized against ultraviolet radiation. Methods for making a crosslinked composition is also provided. One method includes obtaining a crosslinkable composition and subjecting the crosslinkable composition to radiation having a wavelength of 400 nm or greater. Another method includes subjecting a crosslinkable composition to first and second radiations that are different from each other.

公开(公告)号：US10287427B2

公开(公告)日：2019-05-14

申请号：US15516419

申请日：2015-12-01

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： David J. Yarusso ,  Thu-Van T. Tran

IPC: C08L29/14 ,  C08L53/00 ,  C08F293/00 ,  C08J3/00 ,  C08L1/14

Abstract: Described herein is a composition comprising a polymeric blend of: (i) a first polymer comprising at least one acrylic block copolymer, wherein the at least one acrylic block copolymer comprises: (a) at least two A block polymeric units wherein each A block has a glass transition temperature of at least 90 C and each A block is independently derived from a monoethylenically unsaturated monomer comprising a first (meth)acrylate monomer; and (b) at least one B block polymeric unit wherein the at least one B block has a glass transition temperature no greater than −30 C and wherein the at least one B block is derived from a monoethylenically unsaturated monomer comprising a second (meth)acrylate monomer; and (ii) a second polymer selected from at least one of a polyvinyl acetal resin, a polyvinyl acetate, and a cellulose ester.

公开(公告)号：US20190002736A1

公开(公告)日：2019-01-03

申请号：US16062931

申请日：2016-12-13

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Kiu-Yuen Tse ,  Shijing Cheng ,  David J. Yarusso

IPC: C09J7/21 ,  C09J7/38 ,  C09J7/20 ,  C09J7/40 ,  C09J11/04 ,  B01J20/20 ,  B01J20/28 ,  D06N3/00 ,  D06N3/12

Abstract: Described herein is a liner comprising a sorbent material entrapped in a non-woven fiber matrix, wherein the liner comprises a first and a second major surface; and a first adhesive layer contacting the first major surface of the liner, wherein the first adhesive layer comprises a pressure sensitive adhesive.

公开(公告)号：US20180355218A1

公开(公告)日：2018-12-13

申请号：US16062887

申请日：2016-12-13

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Shijing Cheng ,  Kiu-Yuen Tse ,  David J. Yarusso

IPC: C09J7/21 ,  C09J11/04 ,  C09J7/38 ,  C09J175/04

CPC classification number: C09J7/21 ,  C08K3/04 ,  C08K3/36 ,  C09J7/38 ,  C09J7/40 ,  C09J11/04 ,  C09J175/04 ,  C09J2201/606 ,  C09J2205/106 ,  C09J2400/263 ,  C09J2401/006 ,  C09J2421/00 ,  C09J2423/046 ,  C09J2423/106 ,  C09J2433/00 ,  C09J2467/006 ,  C09J2475/00 ,  C09J2477/006 ,  C09J2483/00

Abstract: Described herein is a backing comprising a sorbent material entrapped in a non-woven fiber matrix, wherein the backing comprises a first and a second major surface; and a first adhesive layer contacting the first major surface of the backing, wherein the first adhesive layer comprises a pressure sensitive adhesive.

公开(公告)号：US20190241690A1

公开(公告)日：2019-08-08

申请号：US16341959

申请日：2017-08-22

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Nicole Morozowich Beveridge ,  Ross E. Behling ,  Anish Kurian ,  Mark F. Ellis ,  Karl E. Benson ,  Michele A. Craton ,  Daniel C. Munson ,  David J. Yarusso

IPC: C08F220/18 ,  C08F2/48 ,  C09J7/38 ,  C09J133/08 ,  C09J133/10

CPC classification number: C08F220/18 ,  C08F2/48 ,  C08F2810/20 ,  C09J7/385 ,  C09J133/08 ,  C09J133/10 ,  C09J133/14 ,  C09J2205/31 ,  C08F2220/1858 ,  C08F220/06 ,  C08F220/56 ,  C08F2220/302 ,  C08L33/14

Abstract: Crosslinkable compositions, crosslinked compositions, articles containing these compositions, and methods of making the articles are provided. The crosslinkable compositions, which include two (meth)acrylate polymers, are used to form the crosslinked compositions upon exposure to ultraviolet radiation. The crosslinkable and crosslinked compositions are free or substantially free of tackifiers. The crosslinked compositions can function as pressure-sensitive adhesives. The crosslinkable compositions are well suited for use with hot melt processing methods.

公开(公告)号：US20190177586A1

公开(公告)日：2019-06-13

申请号：US16322146

申请日：2017-08-09

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Francois C. D'Haese ,  Tatsuo Fukushi ,  Katherine A. Gibney ,  Klaus Hintzer ,  Tom Opstal ,  Jayshree Seth ,  David J. Yarusso

IPC: C09J201/04 ,  C09J7/38

Abstract: Described herein is a pressure sensitive adhesive comprising a high molecular weight fluorinated polymer having a Tg less than about 0° C. and a number average molecular weight greater than about 20 kilograms/mole; and a low molecular weight fluorinated polymer derived from an ethylenically unsaturated fluorinated monomer, wherein the low molecular weight fluorinated polymer has a Tg greater than about −15° C. and a number average molecular weight less than about 18 kilograms/mole. Also described herein are articles comprising the pressure sensitive adhesive composition.

公开(公告)号：US10208232B2

公开(公告)日：2019-02-19

申请号：US14888949

申请日：2014-05-06

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Shujun J. Wang ,  Zhong Chen ,  John R. Jacobsen ,  Peggy S. Willett ,  David J. Yarusso ,  Soyoung Kim

IPC: C09J133/08 ,  C09J133/10 ,  C08F265/06 ,  C09J151/00 ,  C09J7/38 ,  C08L33/08 ,  C08L33/10

Abstract: Disclosed is a crosslinked adhesive composition comprising a low Tg (meth)acrylate copolymer component, a high Tg (meth)acrylate copolymer component, and a hydrogenated hydrocarbon tackifier. This disclosure provides a pressure-sensitive adhesive and pressure-sensitive adhesive articles that are particularly useful in the bonding of low surface energy (LSE) substrates.

公开(公告)号：US20170183546A1

公开(公告)日：2017-06-29

申请号：US14981122

申请日：2015-12-28

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： David J. Yarusso ,  Thu-Van T. Tran ,  Soyoung Kim ,  Ross E. Behling ,  Karl E. Benson

IPC: C09J133/08

CPC classification number: C09J133/10 ,  B32B27/306 ,  B32B2307/306 ,  C08F220/18 ,  C08F265/06 ,  C08F290/046 ,  C08L23/02 ,  C08L33/08 ,  C08L33/10 ,  C08L33/26 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2205/05 ,  C09J133/08 ,  C09J133/26 ,  C09J155/005 ,  C08F2220/1858 ,  C08F220/56

Abstract: An adhesive composition includes a first acrylic polymer preparable from first components and a second acrylic polymer. The first components comprising i) a branched first alkyl (meth)acrylate having from 4 to 22 carbon atoms, and ii) at least one of acrylic acid and methacrylic acid. The second acrylic polymer is preparable from second components comprising iii) at least one second alkyl (meth)acrylate having from 4 to 22 carbon atoms, iv) a (meth)acrylamide represented by the formula wherein R1 is H or methyl, and R2 and R3 each independently represents H or an alkyl group having from 1 to 8 carbon atoms, or taken together R2 and R3 may form a divalent alkylene group having from 4 to 6 carbon atoms, and v) at least one high Tg macromer having a terminal free-radically polymerizable unsaturated group, the high Tg macromer having a Tg of at least 45° C. Based on the combined total weight of the at least one first acrylic polymer and the at least one second acrylic polymer, the at least one second acrylic polymer is present at a level of from 5 to 40 percent by weight. Methods of making the adhesive composition are also disclosed.