公开(公告)号：FR2470142A1

公开(公告)日：1981-05-29

申请号：FR8024507

申请日：1980-11-19

Applicant: AGENCY IND SCIENCE TECHN

Inventor： SUDA MICHIKO ASAI YOSHIO ,  IMADA KIYOSHI ,  UENO SUSUMU ,  NOMURA HIROKAZU

IPC: C08J7/00 ,  B29C35/08 ,  B29C59/16 ,  C08F2/48 ,  C08K5/1515 ,  C08L27/06 ,  C08L63/00 ,  C08J7/10 ,  B29C25/00 ,  C08K5/10 ,  C08K5/15

Abstract: The invention provides a novel method for obtaining a shaped article of a vinyl chloride-based resin which is markedly insusceptible to the undesirable phenomenon of exudation or bleeding of the plasticizer and other additive ingredients contained therein on to the surface of the article. The method comprises formulating the resin composition for the fabrication of the shaped article with an epoxy compound containing, preferably, at least 2% by weight of the oxirane oxygen in the molecule in an amount of at least 0.05% by weight based on the vinyl chloride-based resin and irradiating the shaped article with ultraviolet light having a substantial energy distribution in the wavelength region of 200 nm or shorter. The shaped article obtained by the inventive method is remarkably insusceptible to the plasticizer bleeding even after prolonged outdoor exposure or irradiation with ultraviolet light having wavelengths longer than 290 nm.

公开(公告)号：FR2468625B1

公开(公告)日：1987-08-28

申请号：FR8023193

申请日：1980-10-30

Applicant: AGENCY IND SCIENCE TECHN

Inventor： ASAI MICHIHIKO ,  SUDA YOSHIO ,  IMADA KIYOSHI ,  UENO SUSUMU ,  NOMURA HIROKAZU

IPC: C08J7/00 ,  B29C35/08 ,  B29C59/16 ,  C08J7/18 ,  C08J7/10 ,  B29C25/00 ,  C08K5/12 ,  C08K5/13 ,  C08L27/06

公开(公告)号：FR2516525B1

公开(公告)日：1986-05-23

申请号：FR8219048

申请日：1982-11-15

Applicant: AGENCY IND SCIENCE TECHN

Inventor： ASAI MICHIHIKO ,  TSUDA KEISHIRO ,  IMADA KIYOSHI ,  UENO SUSUMU ,  NOMURA HIROKAZU ,  SHIMURA YUKIO

IPC: C08J7/00 ,  B05D3/06 ,  B05D7/26 ,  B29C71/04 ,  C08J7/04 ,  C08J7/12 ,  C08J7/18 ,  C08K5/54 ,  C08L25/04 ,  C08L77/00 ,  C08J7/10

公开(公告)号：DE2925802A1

公开(公告)日：1980-01-10

申请号：DE2925802

申请日：1979-06-26

Applicant: AGENCY IND SCIENCE TECHN ,  SHINETSU CHEMICAL CO

Inventor： ASAI MICHIHIKO ,  SUDA YOSHIO ,  IMADA KIYOSHI ,  UENO SUSUMU ,  NOMURA HIROKAZU ,  KASHIMA IBARAGI

IPC: C08J3/28 ,  C08J5/00 ,  C08J5/18 ,  C08J7/12 ,  C08J7/18 ,  C08K5/04 ,  C08K5/06 ,  C08K5/09 ,  C08K5/17 ,  C08K5/42 ,  C08L27/06 ,  G02B1/10

Abstract: A method for reducing static electricity on the surface of a shaped article made of polyvinyl chloride resins, which method comprises the steps of (a) blending a surface active agent with the polyvinyl chloride resin prior to fabrication of the resin into a shaped article, (b) fabricating the resin admixed with the surface active agent into a shaped article, and (c) subjecting the shaped article to a treatment with low temperature plasma of a gas.

公开(公告)号：FR2516525A1

公开(公告)日：1983-05-20

申请号：FR8219048

申请日：1982-11-15

Applicant: AGENCY IND SCIENCE TECHN

Inventor： ASAI MICHIHIKO ,  TSUDA KEISHIRO ,  IMADA KIYOSHI ,  UENO SUSUMU ,  NOMURA HIROKAZU ,  SHIMURA YUKIO

IPC: C08J7/00 ,  B05D3/06 ,  B05D7/26 ,  B29C71/04 ,  C08J7/04 ,  C08J7/12 ,  C08J7/18 ,  C08K5/54 ,  C08L25/04 ,  C08L77/00 ,  C08J7/10

公开(公告)号：DE3043504A1

公开(公告)日：1981-07-02

申请号：DE3043504

申请日：1980-11-18

Applicant: AGENCY IND SCIENCE TECHN ,  SHINETSU CHEMICAL CO

Inventor： ASAI MICHIHIKO ,  SUDA YOSHIO ,  IMADA KIYOSHI ,  UENO SUSUMU ,  NOMURA HIROKAZU

IPC: C08J7/00 ,  B29C35/08 ,  B29C59/16 ,  C08F2/48 ,  C08K5/1515 ,  C08L27/06 ,  C08L63/00 ,  C08K5/15 ,  C08J7/10

Abstract: The invention provides a novel method for obtaining a shaped article of a vinyl chloride-based resin which is markedly insusceptible to the undesirable phenomenon of exudation or bleeding of the plasticizer and other additive ingredients contained therein on to the surface of the article. The method comprises formulating the resin composition for the fabrication of the shaped article with an epoxy compound containing, preferably, at least 2% by weight of the oxirane oxygen in the molecule in an amount of at least 0.05% by weight based on the vinyl chloride-based resin and irradiating the shaped article with ultraviolet light having a substantial energy distribution in the wavelength region of 200 nm or shorter. The shaped article obtained by the inventive method is remarkably insusceptible to the plasticizer bleeding even after prolonged outdoor exposure or irradiation with ultraviolet light having wavelengths longer than 290 nm.

公开(公告)号：DE2925799A1

公开(公告)日：1980-03-06

申请号：DE2925799

申请日：1979-06-26

Applicant: AGENCY IND SCIENCE TECHN ,  SHINETSU CHEMICAL CO

Inventor： ASAI MICHIHIKO ,  SUDA YOSHIO ,  IMADA KIYOSHI ,  UENO SUSUMU ,  NOMURA HIROKAZU ,  KASHIMA IBARAGI

IPC: C08L27/00 ,  B29D7/01 ,  B29D23/00 ,  C08G18/00 ,  C08J3/28 ,  C08J7/00 ,  C08L1/00 ,  C08L27/06 ,  C08L33/00 ,  C08L33/02 ,  C08L75/00 ,  C08L75/04 ,  H05B7/00 ,  B29D7/02 ,  B29D23/04

Abstract: A method for preventing bleeding of plasticizers on the surface of shaped articles of plasticized polyvinyl chloride resins. The method comprises the steps of (a) blending a urethane elastomer with the polyvinyl chloride resin together with the plasticizer and other optional additives prior to fabrication of the polyvinyl chloride resin composition into shaped articles, (b) fabricating the resin composition into desired shaped articles, and (c) subjecting the thus shaped article to a treatment with low temperature plasma of a gas. Carbon monoxide is preferred as the gas for the plasma atmosphere.