公开(公告)号：AT33628T

公开(公告)日：1988-05-15

申请号：AT86108177

申请日：1986-06-14

Applicant: BASF AG

Inventor： AMBACH EBERHARD DR ,  BIFFAR WERNER DR ,  HOELDERICH WOLFGANG DR ,  IRGANG MATTHIAS DR ,  MROSS WOLF DIETER DR

IPC: C07C5/333 ,  C07C15/40

公开(公告)号：DE3923026A1

公开(公告)日：1990-01-18

申请号：DE3923026

申请日：1989-07-13

Applicant: BASF AG

Inventor： BUECHELE WOLFGANG DR ,  AMBACH EBERHARD DR ,  HOELDERICH WOLFGANG DR ,  MROSS WOLF DIETER DR ,  BIFFAR WERNER DR

IPC: B01J23/86 ,  B01J23/88 ,  B01J23/887 ,  B01J23/888 ,  C07C5/333

Abstract: Catalyst, in particular for the dehydrogenation of hydrocarbons to give olefinically unsaturated hydrocarbons, which essentially comprises in the sintered, ready-to-use state a) 60 to 95% by weight of at least one iron compound, calculated as Fe2O3; b) 1 to 25% by weight of at least one potassium compound, calculated as K2O; c) 0.1 to 5% by weight of at least one compound of chromium or of aluminium, calculated as Cr2O3 or Al2O3; d) 0.1 to 5% by weight of at least one compound of molybdenum or tungsten, calculated as MoO3 or WO3; e) 0.1 to 2.5% by weight of a vanadium compound, calculated as V2O5; f) 0.1 to 5% by weight of a lithium compound, calculated as Li2O; and conventional contaminants and production-related residues, as is obtained when a mixture of either Fe2O3 or FeOOH or a mixture of Fe2O3 and FeOOH and the subsidiary constituents in the form of their compounds is moulded, dried if appropriate at below 160@C and calcined at 200 to 1000@C, the atomic ratio of vanadium to molybdenum or tungsten being 1 to 2.5 and when Fe2O3 is used as starting material in production, the content of vanadium being selected in such a way that in the finished catalyst it is 0.5 to 2% by weight, when FeOOH is used as starting material it is 0.5 to 2.5% by weight and when a mixture of Fe2O3 and FeOOH is used it is no more than 1.5% by weight, in such a manner that when ... Original abstract incomplete.

公开(公告)号：DE3819437A1

公开(公告)日：1989-12-14

申请号：DE3819437

申请日：1988-06-08

Applicant: BASF AG

Inventor： AMBACH EBERHARD DR ,  SPRAGUE MICHAEL JOLYON DR ,  STEIGLEITER WERNER ,  MROSS WOLF DIETER DR ,  GRUENDLER KARL-HEINZ DR ,  IRGANG MATTHIAS DR

IPC: B01J23/86 ,  C01B3/16

Abstract: The application relates to the preparation of a sulphur-free iron-oxide- and chromium-oxide-containing high temperature conversion catalyst, an iron oxide being used which is prepared from iron carbonyl and which has a mean grain size below 10 mu m and a specific surface area of more than 10 m /g. The chromium oxide component is applied to the iron oxide by precipitation. The chromium component used is CrO3 and is precipitated as insoluble chromium(III) compounds by reducing agents.

公开(公告)号：DE3819436A1

公开(公告)日：1989-12-14

申请号：DE3819436

申请日：1988-06-08

Applicant: BASF AG

Inventor： AMBACH EBERHARD DR ,  EBENHOECH FRANZ LUDWIG DR ,  GRUENDLER KARL-HEINZ DR ,  IRGANG MATTHIAS DR ,  ZIRKER GUENTER DR

IPC: B01J23/86 ,  B01J35/10 ,  C01B3/16 ,  C07C45/41

Abstract: The application relates to a process for the preparation of sulphur-free iron-oxide- and chromium-oxide-containing catalysts having BET surface areas of 20 to 100 m /g and in which more than 80% of the pore volume is in the pore radius range of 30 to 100 nm, an iron(III) oxide prepared from iron carbonyl having a mean grain size below 10 mu m and a BET surface area of greater than 50 m /g and chromium(III) oxide having a mean grain size below 40 mu m and a BET surface area of more than 30 m /g being mechanically mixed as powder or suspension and then tableted.

公开(公告)号：DE3521766A1

公开(公告)日：1987-01-02

申请号：DE3521766

申请日：1985-06-19

Applicant: BASF AG

Inventor： HOELDERICH WOLFGANG DR ,  BIFFAR WERNER DR ,  IRGANG MATTHIAS DR ,  MROSS WOLF DIETER DR ,  KROENER MICHAEL DR ,  AMBACH EBERHARD DR

IPC: B01J23/06 ,  B01J23/84 ,  B01J23/85 ,  B01J23/88 ,  B01J27/18 ,  B01J27/188 ,  B01J27/198 ,  B01J27/199 ,  B01J35/04 ,  C01B3/16 ,  C07B61/00 ,  C07C1/00 ,  C07C5/333 ,  C07C15/46 ,  C07C67/00 ,  C07C231/00 ,  C07C231/12 ,  C07C233/03 ,  B01J23/74 ,  B01J23/76 ,  B01J27/185

Abstract: A honeycomb catalyst consisting of from 30 to 95% by weight, calculated as Fe2O3, of an iron compound and from 0.1 to 60% by weight, calculated as Al2O3, CeO2 or Cr2O3, of an aluminum, cerium and/or chromium compound and/or from 1 to 50% by weight of an alkali metal compound, in particular potassium, calculated as K2O, and/or from 0.2 to 20% by weight, calculated as MeO3, of an element of sub-group 6, preferably MoO3 and WO3, and/or from 0.1 to 20% by weight, calculated as V2O5, of a compound of vanadium and/or from 0.1 to 20% by weight, calculated as P2O5, of a compound of phosphorus, a process for the preparation of the honeycomb catalyst, and the use of the catalyst for organic reactions.

公开(公告)号：DE3506022A1

公开(公告)日：1986-08-21

申请号：DE3506022

申请日：1985-02-21

Applicant: BASF AG

Inventor： AMBACH EBERHARD DR ,  BIFFAR WERNER DR ,  MROSS WOLF DIETER DR ,  SCHWARZMANN MATTHIAS DR ,  BECKER HANS-JUERGEN DR ,  KUESSNER KLAUS DR

IPC: B01J23/78 ,  B01J23/85 ,  B01J23/888 ,  C07C5/333 ,  C07C15/46 ,  B01J23/76