12.
    发明专利
    未知

    公开(公告)号:BR9915230A

    公开(公告)日:2001-07-31

    申请号:BR9915230

    申请日:1999-11-05

    Applicant: BASF AG

    Abstract: In a process for esterifying (meth)acrylic acid with an alkanol in the presence of an esterification catalyst, in which unconverted starting compounds and (meth)acrylic ester to be formed are separated off by distillation and an oxyester-containing bottom product is formed, the bottom product is first separated off and then the oxyesters contained in it are cleaved in the presence of a relatively long-chain alkylbenzenesulfonic acid at elevated temperatures.

    METHOD FOR PRODUCING 4,4' DIHALOGENDIPHENYLSULFONE

    公开(公告)号:CA2283894A1

    公开(公告)日:1998-12-30

    申请号:CA2283894

    申请日:1998-06-10

    Applicant: BASF AG

    Abstract: The invention relates to a method for producing 4,4'-dihalogendiphenylsulfone by reacting halogenated benzene with 4-halogenphenylsulfonyl chloride in a liquid phase at high temperature, in the presence of a solid catalyst having acid centers. The method is characterized in that the reaction of 4halogenphenylsulfonyl chloride with formula (I), in which X is chlorine, bromine or fluorine, with chlorobenzene, bromobenzene, or fluorobenzene, is carried out in the presence of a catalyst which is selected from one of the following groups: K1) catalysts consisting of essentially stratified silicates not having Lewis acids and having proton-saturated negative layer loads, or containing these as a basic component; K2) catalysts consisting of zeolites in the acid H form, or containing these as a basic component; and K3) catalysts consisting of mixed oxides having acidic centres, or containing these as basic components. The mixed oxides consist of a combination of (a) titanium, circonium, hafnium, tin, iron or Cr(III) oxides on the one hand, and (b) vanadium, chromium(VI), molybdenum, wolfram or scandium oxides on the other hand; or the mixed oxides are sulfatized or phosphatized oxides of the group (a), and said mixed oxides are calcined after combination, at temperatures of 450 to 800 ~C.

    14.
    发明专利
    未知

    公开(公告)号:AT170638T

    公开(公告)日:1998-09-15

    申请号:AT95924250

    申请日:1995-06-16

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP95/02328 Sec. 371 Date Dec. 24, 1996 Sec. 102(e) Date Dec. 24, 1996 PCT Filed Jun. 16, 1995 PCT Pub. No. WO96/00409 PCT Pub. Date Jan. 4, 1996Naphthalene derivatives of the formula where the rings A and B may be benzofused, X is nitrogen or a radical of the formula CH or CH=CH-CH, Z is a heterocyclic radical or additionally, when x is CH=CH-CH, a 5- or 6-membered aromatic carbocyclic radical, and R1, R2 and R3 are hydrogen, C1-C4-alkyl or C5-C7-cycloalkyl, are useful in nonlinear optics.

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