公开(公告)号：WO03042151A8

公开(公告)日：2004-06-24

申请号：PCT/EP0212491

申请日：2002-11-08

Applicant: BASF AG ,  WARTINI ALEXANDER ,  DERNBACH MATTHIAS ,  SCHROEDER JUERGEN ,  MARTIN FRIEDRICH-GEORG ,  SIRCH TILMAN

Inventor： WARTINI ALEXANDER ,  DERNBACH MATTHIAS ,  SCHROEDER JUERGEN ,  MARTIN FRIEDRICH-GEORG ,  SIRCH TILMAN

IPC: C07C67/08 ,  C07B61/00 ,  C07C29/141 ,  C07C29/80 ,  C07C31/22 ,  C07C51/50 ,  C07C67/62 ,  C07C69/54

CPC classification number: C07C51/50 ,  C07C67/62 ,  C07C57/04 ,  C07C69/54

Abstract: The invention relates to a method for producing (meth) acrylic acid esters of polyhydric alcohols by reacting (meth) acrylic acid and the corresponding polyhydric alcohols in the presence of at least one acid catalyst and, optionally, of at least one polymerization inhibitor and, optionally, in the presence of a solvent, whereby the polyhydric alcohol that is used has a content of bound formaldehyde of less than 500 ppm.

Abstract translation: 一种通过（甲基）丙烯酸的反应制备的多元醇的（甲基）丙烯酸酯和在至少一种酸性催化剂的存在下，相应的多元醇和任选的至少一种聚合抑制剂和任选地在溶剂的存在下，其中使用的多元醇具有的结合的内容的处理 包括下500ppm的甲醛。

公开(公告)号：WO2004087790A3

公开(公告)日：2004-12-16

申请号：PCT/EP2004003551

申请日：2004-04-02

Applicant: BASF AG ,  POPP ANDREAS ,  DANIEL THOMAS ,  SCHROEDER JUERGEN ,  JAWOREK THOMAS ,  FUNK RUEDIGER ,  SCHWALM REINHOLD ,  WEISMANTEL MATTHIAS ,  RIEGEL ULRICH

Inventor： POPP ANDREAS ,  DANIEL THOMAS ,  SCHROEDER JUERGEN ,  JAWOREK THOMAS ,  FUNK RUEDIGER ,  SCHWALM REINHOLD ,  WEISMANTEL MATTHIAS ,  RIEGEL ULRICH

IPC: C08G65/32 ,  A61L15/60 ,  C07C69/00 ,  C08F20/00 ,  C08G63/00 ,  C08G65/26 ,  C08G65/28 ,  C08G65/332

CPC classification number: C08F220/06 ,  A61L15/60 ,  C07C67/08 ,  C08F222/1006 ,  C08G65/2609 ,  C08G65/3322 ,  C07C69/54

Abstract: The invention relates to novel mixtures of polyalkoxylated trimethylolpropane (meth)acrylate of formula (I), wherein AO independently represents EO, PO, or BO for each AO, EO representing O-CH2-CH2-, PO independently representing O-CH2-CH(CH3)- or O-CH(CH3)-CH2-, BO independently representing O-CH2-CH(CH2-CH3)- or O-CH(CH2-CH3)-CH2-, p1 + p2 + p3 equals 28, 29, 30, 31, 32, 33, 34,35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45, 46, 47, 48, 49, 50, 51, 52, 53, 54, 55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69, 70, 71, 72, 73, 74. or 75, and R1, R2, R3 independently represent H or CH3. Also disclosed are a simplified method for producing said ester mixtures and the use of the obtained reaction mixtures.

Abstract translation: 本发明涉及的（甲基）丙烯酸盐三元共聚物与AO独立地EO，PO或BO的式（I）的聚烷氧基化三羟甲基丙烷的新混合物意味着每个AO其中EO是O-CH2-CH2-PO独立地为O-CH 2 CH （CH 3） - 或O-CH（CH 3）-CH 2 - BO各自独立地是O-CH2-CH（CH2-CH3） - 或-O-CH（CH2-CH3）-CH2-PL + P2 + P3是28，29 ，30，31，32，33，34,35，36，37，38，39，40，41，42，43，44，45，46，47，48，49，50，51，52，53，54 ，55，56，57，58，59，60，61，62，63，64，65，66，67，68，69，70，71，72，73，74或75中，R，R2，R3彼此独立地 H或CH3，制备这些酯混合物的简化方法和使用由此得到的反应混合物。

公开(公告)号：WO02051786A3

公开(公告)日：2003-01-23

申请号：PCT/EP0115206

申请日：2001-12-21

Applicant: BASF AG ,  HAMMON ULRICH ,  SUTORIS HEINZ-FRIEDRICH ,  SCHROEDER JUERGEN ,  SCHLIEPHAKE VOLKER

Inventor： HAMMON ULRICH ,  SUTORIS HEINZ-FRIEDRICH ,  SCHROEDER JUERGEN ,  SCHLIEPHAKE VOLKER

IPC: C07C51/44 ,  C07C51/50 ,  C07C57/07 ,  C07C57/075

CPC classification number: C07C51/44 ,  C07C51/50 ,  C07C57/04

Abstract: The invention relates to a method for processing (meth)acrylic acid in the presence of at least one stabilising agent. A mixture which contains the stabilising agent and is essentially devoid of (meth)acrylic acid and arising from the processing is introduced into a distilling device, and a low boiling flow which contains the stabilising agent and which is obtained from mixture is reintroduced into the preparation.

Abstract translation: 一种用于在存在下，其中包括这样的化合物被引入了从进行后衍生的至少一种稳定剂的（甲基）丙烯酸的后处理过程中，基本上丙烯酸自（甲基）释放，稳定剂在一个蒸馏装置并从后处理所获得，稳定剂低沸点流含 再循环。

公开(公告)号：WO03043712A8

公开(公告)日：2003-08-07

申请号：PCT/EP0213084

申请日：2002-11-21

Applicant: BASF AG ,  THIEL JOACHIM ,  SCHROEDER JUERGEN

Inventor： THIEL JOACHIM ,  SCHROEDER JUERGEN

IPC: B01D3/26 ,  B01D3/14 ,  B01D3/22 ,  C07C51/44

CPC classification number: B01D3/225 ,  B01D3/22

Abstract: The invention relates to a column for the thermal treatment of mixtures containing at least one polymerisable compound. Said column comprises dual flow plates which are provided with openings, the diameter of each opening being constant inside a dual flow plate. The diameter of the openings of said dual flow plates decreases as the distance of the plates from the inlet of the mixture to be treated increases.

Abstract translation: 存在对包含一种或多种可聚合化合物的混合物，提出了双流塔板增加有开口，其直径为双流塔板，其中所述双流塔盘与内是恒定的热处理的柱 与待处理混合物入口的距离具有直径逐渐减小的开口。

公开(公告)号：WO0034220A2

公开(公告)日：2000-06-15

申请号：PCT/EP9909543

申请日：1999-12-07

Applicant: BASF AG ,  SUTORIS HEINZ FRIEDRICH ,  WAGENBLAST GERHARD ,  SCHLIEPHAKE VOLKER ,  SCHROEDER JUERGEN ,  MUELLER ENGEL KLAUS JOACHIM ,  KELLER HARALD ,  JAWOREK THOMAS

Inventor： SUTORIS HEINZ FRIEDRICH ,  WAGENBLAST GERHARD ,  SCHLIEPHAKE VOLKER ,  SCHROEDER JUERGEN ,  MUELLER-ENGEL KLAUS JOACHIM ,  KELLER HARALD ,  JAWOREK THOMAS

IPC: C07C45/86 ,  C07B63/04 ,  C07C47/22 ,  C07C51/50 ,  C07C51/64 ,  C07C57/075 ,  C07C67/62 ,  C07C69/54 ,  C07C51/00

CPC classification number: C07C51/64 ,  C07B63/04 ,  C07C67/62 ,  C07C57/04 ,  C07C69/54

Abstract: A method for stabilizing chemical compounds containing at least one ethylenically unsaturated bond in order to prevent undesirable radical polymerization, whereby a nitroxyl radical and a chemical compound containing chemically bonded phosphorus are added to an unsaturated compound existing in the form of a pure substance or constituent in a mixture.

Abstract translation: 一种用于稳定至少一个烯不饱和键的化合物对不想要的自由基聚合方法，其包括增加了作为纯物质或作为混合物组分的不饱和化合物的方法，是硝酰自由基和含磷的化学结合的化学化合物。

公开(公告)号：WO03047713A3

公开(公告)日：2003-09-18

申请号：PCT/EP0213728

申请日：2002-12-04

Applicant: BASF AG ,  HAMMON ULRICH ,  SCHROEDER JUERGEN

Inventor： HAMMON ULRICH ,  SCHROEDER JUERGEN

IPC: F16B2/04 ,  B01D3/14 ,  B01D3/32

CPC classification number: B01D3/326 ,  Y10T29/49963 ,  Y10T29/49998

Abstract: The invention relates to a clamp (1) for releasably connecting a column plate (4) to a supporting ring (5) in a column, comprising a bolt (2) and a bolt bottom part (3) that is connected to said bolt (2), wherein the bolt bottom part (3) has at least one opening (8) through which a liquid located inside the column can flow out.

Abstract translation: 公开了一种用于与一个支撑环5在一列中的列托盘4的可拆卸连接的夹具1，包括螺栓2和连接到引脚2夹紧下部3，其中所述夹具下部3具有至少一个开口8，通过在列其中 可以排出液体。

公开(公告)号：EP0813526A1

公开(公告)日：1997-12-29

申请号：EP96905803

申请日：1996-02-27

Applicant: BASF AG

Inventor： MERKLE HANS RUPERT ,  FRETSCHNER ERICH ,  SCHROEDER JUERGEN

IPC: C07D231/12 ,  C07D521/00

CPC classification number: C07D231/12 ,  C07D233/56 ,  C07D249/08

Abstract: A process is disclosed for preparing N-substituted pyrazoles having the general formula (I), in which R1 stands for C¿1? to C12 alkyl or C7 to C20 phenylalkyl, and R?2, R3, R4¿ represent independently from each other hydrogen, C¿1? to C12 alkyl, C7 to C20 phenylalkyl or optionally substituted aryl residues, by reacting pyrazoles having the general formula (II), in which R?2, R3 and R4¿ have above-said meanings, with an alcohol having the general formula (III) R1-O-H, in which R1 has above-said meanings, at temperatures from 50 to 400 °C in the presence of a catalyst. The reaction of pyrazole (II) with compound (III) is carried out in a molar ratio from 0.001:1 to 1:1 in the liquid phase at a slight negative pressure up to an overpressure of 250 bars. Acids, their alkyl esters and/or their anhydrides are used as catalysts in a molar ratio from 0.0001:1 to 0.5:1 in relation to pyrazole (II).

公开(公告)号：ZA200505209B

公开(公告)日：2006-10-25

申请号：ZA200505209

申请日：2005-06-28

Applicant: BASF AG

Inventor： SCHROEDER JUERGEN

IPC: C07C20090101 ,  C07C51/44

Abstract: A process for rectificatively separating liquids containing (meth)acrylic monomers in a rectification column is provided, in which a stream is withdrawn from the rectification column and recycled into the rectification column as a molecular oxygen-enriched liquid phase.

公开(公告)号：BR0317583A

公开(公告)日：2005-11-22

申请号：BR0317583

申请日：2003-12-24

Applicant: BASF AG

Inventor： THIEL JOACHIM ,  DAMS ALBRECHT ,  SCHROEDER JUERGEN

IPC: B01D3/14 ,  B01D5/00 ,  C07C45/81 ,  C07C45/82 ,  C07C51/43 ,  C07C51/44 ,  C07C67/54 ,  B01D3/16

公开(公告)号：PL374441A1

公开(公告)日：2005-10-17

申请号：PL37444103

申请日：2003-06-06

Applicant: BASF AG

Inventor： POPP ANDREAS ,  DANIEL THOMAS ,  SCHROEDER JUERGEN ,  JAWOREK THOMAS ,  FUNK RUEDIGER ,  SCHWALM REINHOLD ,  WEISMANTEL MATTHIAS ,  RIEGEL ULRICH

IPC: C08G65/332 ,  A61L15/60 ,  C07B61/00 ,  C07C67/08 ,  C07C69/54 ,  C08F290/06 ,  C08G65/26 ,  C08G65/28

Abstract: The present invention relates to novel (meth)acrylic esters of polyalkoxylated trimethylolpropane of the formula where AO is for each AO independently at each instance EO, PO or BO where EO is O-CH2-CH2- PO is independently at each instance O-CH2-CH(CH3)- or O-CH(CH3)-CH2- BO is independently at each instance O-CH2-CH(CH2-CH3)- or O-CH(CH2-CH3)-CH2- p1+p2+p3 is 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45, 46, 47, 48, 49, 50, 51, 52, 53, 54, 55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69, 70, 71, 72, 73, 74 or 75, R1, R2 and R3 are independently H or CH3, a simplified process for preparing these esters and the use of reaction mixtures thus obtainable.