Microcapsules formed from unsaturated acid anhydrides

    公开(公告)号:GB2280164B

    公开(公告)日:1997-05-07

    申请号:GB9412585

    申请日:1994-06-23

    Applicant: BASF AG

    Abstract: Microcapsules which are composed of a core and of a shell of a polymer, the core containing at least one oil which can be emulsified in water, and which are obtainable by polymerization of oil-soluble monomer mixtures which contain (a) 1-100% by weight of acrylic anhydride, methacryic anhydride, itaconic anhydride, citraconic anhydride, dimethylmaleic anhydride, 4-vinylbenzoic anhydride, mixed carboxylic anhydrides, mixtures of the said anhydrides and/or more than 40% by weight of maleic anhydride, (b) 0-99% by weight of at least one monoethylenically unsaturated monomer which is different from the monomers of group (a), (c) 0-80% by weight of crosslinking monomers which have at least two monoethylenically unsaturated non-conjugated double bonds in the molecule, and (d) 0-20% by weight of water-soluble monoethylenically unsaturated monomers in the oil phase of a stable oil-in-water emulsion in the presence of polymerization initiators which form free radicals, where the temperature of the polymerizing reaction mixture may be continuously or periodically increased during the polymerization, a process for producing the microcapsules by polymerization of the abovementioned monomer mixtures in the oil phase of a stable oil-in-water emulsion in the presence of polymerization initiators which form free radicals, where the temperature of the polymerizing reaction mixture may be continuously or periodically increased during the polymerization, and the use of the microcapsules for the controlled release of the core material of the microcapsules as active substance by destruction of their shell, in particular by the action of bases.

    Microcapsules formed from unsaturated acid anhydrides

    公开(公告)号:GB2280164A

    公开(公告)日:1995-01-25

    申请号:GB9412585

    申请日:1994-06-23

    Applicant: BASF AG

    Abstract: Microcapsules which are composed of a core and of a polymeric shell, the core containing at least one oil which can be emulsified in water, can be obtained by polymerization of an oil-soluble monomer mixture which comprises (a) 1-100% by weight of at least one ethylenically unsaturated anhydride selected from acrylic anhydride, methacrylic anhydride, itaconic anhydride, citraconic anhydride, dimethylmaleic anhydride, 4-vinylbenzoic anhydride, mixed carboxylic anhydrides, and mixtures of two or more of the said anhydrides, and/or more than 40% by weight of maleic anhydride, (b) 0-99% by weight of at least one monoethylenically unsaturated monomer which is different from the anhydrides of group (a), (c) 0-80% by weight of at least one crosslinking monomer which has at least two monoethylenically unsaturated non-conjugated double bonds in the molecule, and (d) 0-20% by weight of at least one water-soluble monoethylenically unsaturated monomer, in the oil phase of a stable oil-in-water emulsion in the presence of a polymerization initiator which forms free radicals, the temperature of the polymerizing reaction mixture being optionally continuously or periodically increased during the polymerization. The resulting microcapsules can be used for the controlled release of the core material of the microcapsules as active substance by destruction of the shell of the microcapsules, in particular by the action of bases.

    14.
    发明专利
    未知

    公开(公告)号:DE4321205B4

    公开(公告)日:2006-06-29

    申请号:DE4321205

    申请日:1993-06-25

    Applicant: BASF AG

    Abstract: Microcapsules which are composed of a core and of a shell of a polymer, the core containing at least one oil which can be emulsified in water, and which are obtainable by polymerization of oil-soluble monomer mixtures which contain (a) 1-100% by weight of acrylic anhydride, methacryic anhydride, itaconic anhydride, citraconic anhydride, dimethylmaleic anhydride, 4-vinylbenzoic anhydride, mixed carboxylic anhydrides, mixtures of the said anhydrides and/or more than 40% by weight of maleic anhydride, (b) 0-99% by weight of at least one monoethylenically unsaturated monomer which is different from the monomers of group (a), (c) 0-80% by weight of crosslinking monomers which have at least two monoethylenically unsaturated non-conjugated double bonds in the molecule, and (d) 0-20% by weight of water-soluble monoethylenically unsaturated monomers in the oil phase of a stable oil-in-water emulsion in the presence of polymerization initiators which form free radicals, where the temperature of the polymerizing reaction mixture may be continuously or periodically increased during the polymerization, a process for producing the microcapsules by polymerization of the abovementioned monomer mixtures in the oil phase of a stable oil-in-water emulsion in the presence of polymerization initiators which form free radicals, where the temperature of the polymerizing reaction mixture may be continuously or periodically increased during the polymerization, and the use of the microcapsules for the controlled release of the core material of the microcapsules as active substance by destruction of their shell, in particular by the action of bases.

    STABILISED BLACK POLYOXYMETHYLENE MOULDING MATERIALS

    公开(公告)号:PL359153A1

    公开(公告)日:2004-08-23

    申请号:PL35915301

    申请日:2001-06-22

    Applicant: BASF AG

    Inventor: DAMES BURKHARDT

    Abstract: Thermoplastic molding compositions comprising, as substantive components,A) from 5% by weight to (99.99% by weight minus 1 ppb), based on components A) to D), of a polyoxymethylene homo- or copolymer,B) from 1 ppb to 1% by weight, based on the molding composition made from A) to D), of at least one polyethyleneimine homo- or copolymer,C) from 0.01 to 15% by weight of carbon black, andD) from 0 to 80% by weight of other additives,where the total of percentages by weight of components A) to D) is always 100%.

    17.
    发明专利
    未知

    公开(公告)号:AT264368T

    公开(公告)日:2004-04-15

    申请号:AT01945306

    申请日:2001-06-22

    Applicant: BASF AG

    Abstract: The invention relates to thermoplastic molding compounds, comprising at least (A) 10 to 99.99 wt.-% of a polyoxymethylene homopolymer or copolymer, at least (B) 0.01 to 5 wt.-% of a polyethylenimine homopolymer or copolymer, at least (C) 0.1 to 15 wt.-% of a polyalkylene glycol or polyalkylene glycolamine or the mixtures thereof, (D) 0 to 70 wt.-% of further additives, whereby the sum of the weight percentages of components (A) to (D) always adds up to 100%.

    Stabilized polyoxymethylene moulding materials.

    公开(公告)号:HK1038033A1

    公开(公告)日:2002-03-01

    申请号:HK01109047

    申请日:2001-12-24

    Applicant: BASF AG

    Abstract: Thermoplastic polyoxymethylene molding materials containingA) from 10 to 99.98% by weight of a polyoxymethylene homo- or copolymerB) from 0.005 to 2% by weight of a sterically hindered phenolC) from 0.001 to 2% by weight of a polyamideD) from 0.002 to 2% by weight of an alkaline earth metal silicate or of an alkaline earth metal glycerophosphateE) from 0.01 to 5% by weight of at least one ester or amide of saturated or unsaturated aliphatic carboxylic acids of 10 to 40 carbon atoms with polyols or aliphatic saturated alcohols or amines of 2 to 40 carbon atoms or an ether which is derived from alcohols and ethylene oxideF) from 0 to 5% by weight of a melamine/formaldehyde condensateG) from 0 to 74% by weight of further additives, the sum of the percentages by weight of the components A) to G) being 100% in each case.

    Antistatic polyoxymethylene molding compounds

    公开(公告)号:AU6756001A

    公开(公告)日:2002-01-08

    申请号:AU6756001

    申请日:2001-06-22

    Applicant: BASF AG

    Abstract: The invention relates to thermoplastic molding compounds, comprising at least (A) 10 to 99.99 wt.-% of a polyoxymethylene homopolymer or copolymer, at least (B) 0.01 to 5 wt.-% of a polyethylenimine homopolymer or copolymer, at least (C) 0.1 to 15 wt.-% of a polyalkylene glycol or polyalkylene glycolamine or the mixtures thereof, (D) 0 to 70 wt.-% of further additives, whereby the sum of the weight percentages of components (A) to (D) always adds up to 100%.

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