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11.
公开(公告)号:MX2007010884A
公开(公告)日:2007-11-23
申请号:MX2007010884
申请日:2006-03-27
Applicant: BASF AG
Inventor: HINZ WERNER , DEXHEIMER EDWARD MICHAEL , WILDESON JACOB
IPC: C08G64/34
Abstract: Un metodo para formar un poliol de polietercarbonato que incorpora CO2 en el poliol de polietercarbonato. El metodo provee un catalizador que incluye un compuesto de cianuro de multiples metales. Un iniciador H-funcional, un oxido de alquileno y CO2 se hacen reaccionar en presencia del compuesto de cianuro de multiples metales en un reactor. El metodo provee ademas un compuesto CO2-filico o un sustituyente CO2-filico. El compuesto y sustituyente CO2-filico mejoran la incorporacion de CO2 en el poliol de polietercarbonato y reduce la formacion de carbonatos de alquileno ciclicos, tales como carbonato de propileno ciclico, que son subproductos indeseables.
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公开(公告)号:PL363645A1
公开(公告)日:2004-11-29
申请号:PL36364501
申请日:2001-06-26
Applicant: BASF AG
Inventor: DEXHEIMER EDWARD MICHAEL , GROSCH GEORG HEINRICH
Abstract: Improved methods for synthesizing double metal cyanide (DMC) catalysts are disclosed. These methods combine an aqueous solution of a first metal salt, such as ZnCl2, with an aqueous solution of a second metal salt, such as CoCl2, and with an aqueous solution of an alkali metal cyanide, such as KCN, in different manners to synthesize DMC catalysts, such as Zn3[Co(CN)6]2.
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公开(公告)号:DE10319242A1
公开(公告)日:2004-11-18
申请号:DE10319242
申请日:2003-04-28
Applicant: BASF AG
Inventor: GROER PETER , HENDREICH REGINA , KIERKUS PAUL , OSTROWSKI THOMAS , STROEFER ECKARD , THIELE KAI , SCHNORPFEIL CHRISTOPH , DEXHEIMER EDWARD MICHAEL
IPC: C07C43/315 , C08G2/34 , C08G18/54 , C08G65/26 , C07C47/263 , C08G65/30 , C08G18/10
Abstract: The invention relates to initial compounds for producing polyurethanes and is characterised in that said polyurethanes can be produced by reaction of hydroxyl group containing formaldehyde oligomers.
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公开(公告)号:HU0300708A2
公开(公告)日:2003-07-28
申请号:HU0300708
申请日:2001-06-26
Applicant: BASF AG
Inventor: DEXHEIMER EDWARD MICHAEL , GROSCH GEORG HEINRICH
Abstract: Improved methods for synthesizing double metal cyanide (DMC) catalysts are disclosed. These methods combine an aqueous solution of a first metal salt, such as ZnCl2, with an aqueous solution of a second metal salt, such as CoCl2, and with an aqueous solution of an alkali metal cyanide, such as KCN, in different manners to synthesize DMC catalysts, such as Zn3[Co(CN)6]2.
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公开(公告)号:AU5395800A
公开(公告)日:2000-12-28
申请号:AU5395800
申请日:2000-05-19
Applicant: BASF AG
Inventor: GROSCH GEORG HEINRICH , HARRE KATHRIN , ERBES JORG , LORENZ REINHARD , BAUER STEPHAN , OSTROWSKI THOMAS , BAUM EVA , JUNGE DIETER , DEXHEIMER EDWARD MICHAEL
Abstract: Catalyst suspensions for the ring-opening polymerization of alkylene oxides comprise a) at least one multimetal cyanide compound having a crystalline structure and a content of platelet-shaped particles of at least 30% by weight, based on the multimetal cyanide compound, and b) at least one organic complexing agent c) water and/or d) at least one polyether and/or e) at least one surface-active substance, with the proviso that at least component a) and at least two of the components b) to e) have to be present.
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公开(公告)号:DE60129707T2
公开(公告)日:2008-04-30
申请号:DE60129707
申请日:2001-06-26
Applicant: BASF AG
Inventor: DEXHEIMER EDWARD MICHAEL , GROSCH GEORG HEINRICH
Abstract: Improved methods for synthesizing double metal cyanide (DMC) catalysts are disclosed. These methods combine an aqueous solution of a first metal salt, such as ZnCl2, with an aqueous solution of a second metal salt, such as CoCl2, and with an aqueous solution of an alkali metal cyanide, such as KCN, in different manners to synthesize DMC catalysts, such as Zn3[Co(CN)6]2.
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公开(公告)号:DE60129707D1
公开(公告)日:2007-09-13
申请号:DE60129707
申请日:2001-06-26
Applicant: BASF AG
Inventor: DEXHEIMER EDWARD MICHAEL , GROSCH GEORG HEINRICH
Abstract: Improved methods for synthesizing double metal cyanide (DMC) catalysts are disclosed. These methods combine an aqueous solution of a first metal salt, such as ZnCl2, with an aqueous solution of a second metal salt, such as CoCl2, and with an aqueous solution of an alkali metal cyanide, such as KCN, in different manners to synthesize DMC catalysts, such as Zn3[Co(CN)6]2.
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公开(公告)号:DE60312900T2
公开(公告)日:2007-08-30
申请号:DE60312900
申请日:2003-10-17
Inventor: HINZ WERNER , DEXHEIMER EDWARD MICHAEL
Abstract: A method of removing and reclaiming a double metal cyanide (DMC) catalyst from a polyol is disclosed. A polymeric acid that is soluble in the polyol is introduced into the polyol during or after the polymerization reaction. The polymeric acid reacts with the double metal cyanide catalyst thereby causing the double metal cyanide catalyst and the polymeric acid to form an agglomeration in the polyol. The agglomeration is easily separated from the polyol via filtration, for example. The recovered agglomerated DMC catalyst can then be reconstituted using an acid solution.
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公开(公告)号:DE60312900D1
公开(公告)日:2007-05-10
申请号:DE60312900
申请日:2003-10-17
Inventor: HINZ WERNER , DEXHEIMER EDWARD MICHAEL
Abstract: A method of removing and reclaiming a double metal cyanide (DMC) catalyst from a polyol is disclosed. A polymeric acid that is soluble in the polyol is introduced into the polyol during or after the polymerization reaction. The polymeric acid reacts with the double metal cyanide catalyst thereby causing the double metal cyanide catalyst and the polymeric acid to form an agglomeration in the polyol. The agglomeration is easily separated from the polyol via filtration, for example. The recovered agglomerated DMC catalyst can then be reconstituted using an acid solution.
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