PRODUCTION OF LOW-DENSITY RIGID POLYURETHANE FOAM AND USE OF RIGID POLYURETHANE FOAM PRODUCED THEREBY

    公开(公告)号:JPH10273549A

    公开(公告)日:1998-10-13

    申请号:JP5995098

    申请日:1998-03-11

    Applicant: BASF AG

    Abstract: PROBLEM TO BE SOLVED: To provide a process for producing a low-density rigid polyurethane foam excellent in compression strength and long-term dimensional stability and a method for using a low-density rigid polyurethane foam produced thereby. SOLUTION: In this process, a (modified) org. polyisocyantate (a) is reacted with a high-molecular compd. (b) having at least two reactive hydrogen atoms and if necessary a low-molecular chain extended and/or a cross-linker (c) in the presence of a blowing agent (d), a catalyst (e), and if necessary other auxiliaries and/or additives (f). Here, the blowing agent (d) comprises 0.1-10 wt.% cyclopentane, 0.1-6 wt.% compd. homogeneously miscible with cyclopentane and selected from among 3-4C alkanes and 3-4C alkenes, and carbon dioxide generated by the reaction of water with the isocyanate (a); and a polyether having arom. parts and nitrogen atoms is used in an amt. of 5-25 wt.% as the high mol.wt. compd. (b).

    MULTI-METAL CYANIDE CATALYSTS
    6.
    发明申请
    MULTI-METAL CYANIDE CATALYSTS 审中-公开
    多金属氰化物催化剂

    公开(公告)号:WO0074844A8

    公开(公告)日:2001-03-29

    申请号:PCT/EP0004572

    申请日:2000-05-19

    CPC classification number: C08G65/2663 B01J27/26

    Abstract: The invention relates to multi-metal cyanide compounds of the general formula (I). In said formula: M represents at least one metal ion, selected from the group containing Zn , Fe , Co , Ni , Mn , Pb , Fe , Mo , Mo , Al , V , Sr , W , W , Cu , Cr , Cr , Cd , Hg , Pd , Pt , V , Mg , Ca , Ba ; M represents at least one metal ion, selected from the group containing Fe , Fe , Co , Cr , Mn , Mn , Rh , Ru , Ru , V , V , Co , Ir and Cr and M is different from M ; X represents at least one anion, selected from the group containing halide, hydroxide, sulphate, carbonate, cyanide, thiocyanate, isocyanate, carboxylate, in particular, formiate, acetate, propionate, oxalate, nitrate; A represents at least one anion, selected from the group containing halide, hydroxide, sulphate, carbonate, cyanate, thiocyanate, isocyanate, carboxylate or nitrate, in particular, cyanide; a, b, c and d are whole or fractional numbers which are selected in such a way, that the electroneutrality of the cyanide compound is guaranteed, whereby a, b and d are greater than zero and c is greater than or equal to zero; e is a whole or fractional number greater than zero and h is a whole or fractional number greater than or equal to zero; and f and g are whole or fractional numbers which are selected in such a way that the electroneutrality of M fXg is guaranteed.

    Abstract translation: 涉及多金属的式(I)的氰化:M <1> [M <2>(CN)BAC] D * E中号<1> FXG * H 2 O,其中M <1>,选自Zn <中选择的至少一种金属离子2+ >,铁<2+>,钴<3+>,镍<2+>,锰<2+>,钴<2+>,锡<2+>,铅<2+>,铁<3+> 沫<4+>,莫<6+>,铝<3+>,V <5+>,SR <2+>,W <4+>,W <6+>,铜<2+>,铬< 2+>,铬<3+>,镉<2+>,汞<2+>,钯<2+>,铂<2+>,V <2+>,镁<2+>,钙<2+ >,钡<2+>; 中号<2>的至少一种金属选自Fe <2+>,铁<3+>,钴<3+>,铬<3+>,锰<2+>,锰<3+>,铑<3+ >,茹<2+>,钌<3+>,V <4+>,V <5+>,钴<2+>,IR <3+>和Cr <2+>和M <2>不同 是M <1>的; X是至少一种阴离子选自卤化物,氢氧化物,硫酸盐,碳酸盐,氰化物,硫氰酸盐,异氰酸酯,羧酸盐中,特别是甲酸盐,乙酸盐,丙酸盐,草酸盐,硝酸盐; 甲至少一个阴离子选择卤化物,氢氧化物,硫酸盐,碳酸盐,氰酸盐,硫氰酸盐,异氰酸酯,羧酸盐,或硝酸盐,特别是氰化装置; 并且a,b,c和d是被选择的整数或分数,使得氰化物化合物的电中性保证,其中a,b和d是大于零,而c是大于或等于零,并且f和g是整数或分数 是被选择使得M <1> FXG的Elektoneutralität保证数字。

    8.
    发明专利
    未知

    公开(公告)号:DE602005004539D1

    公开(公告)日:2008-03-13

    申请号:DE602005004539

    申请日:2005-04-21

    Applicant: BASF AG

    Abstract: Process for preparing polyether polyols having an end block of ethylene oxide by addition of alkylene oxides onto H-functional starter substances, in which A) a polyether polyol precursor is prepared by means of double metal cyanide (DMC) catalysis in a semicontinuous mode of operation in which previously prepared polyether polyol together with the DMC catalyst are placed in a reactor and H-functional starter substance and propylene oxide are added continuously, B) the polyether polyol precursor from stage A) is reacted with propylene oxide or an ethylene oxide/propylene oxide mixture in the presence of the DMC catalyst in a continuously operating reactor to give a polyether polyol intermediate, C) the intermediate from stage B) is mixed with an alkali metal hydroxide as catalyst and D) reacted with ethylene oxide in a continuously operating reactor to give the final product, E) the catalyst is separated off from the final product obtained in stage D).

    PROCESO PARA LA PREPARACION DE POLIETER POLIOLES REACTIVOS QUE TIENEN UN BLOQUE DE EXTREMO DE OXIDO DE ETILENO.

    公开(公告)号:MXPA06011930A

    公开(公告)日:2007-01-26

    申请号:MXPA06011930

    申请日:2005-04-21

    Applicant: BASF AG

    Abstract: Se presenta un proceso para la preparacion de polieter polioles que tienen un bloque de extremo de oxido de etileno mediante adicion de oxidos de alquileno en sustancias iniciadoras con funcionalidad H, en donde A) se prepara un precursor de polieter poliol a traves de catalisis de cianuro de metal doble (DMC, por sus siglas en ingles), en un modo semi-continuo de operacion en el cual el polieter poliol previamente preparado junto con el catalizador DMC se colocan en un reactor y una sustancia iniciadora con funcionalidad H y oxido de propileno se agregan continuamente; B) el precursor de polieter poliol de la etapa A) reacciona con oxido de propileno o una mezcla de oxido de etileno /oxido de propileno en presencia del catalizador DMC en un reactor de operacion continua para proporcionar un producto intermedio de polieter poliol; C) el producto intermedio de la etapa B) se mezcla con un hidroxido de metal alcalino como catalizador y D) reacciona con oxido de etileno en un reactor de operacion continua para proporcionar el producto final; E) el catalizador es separado del producto final obtenido en la etapa D).

    Method for the production of polyetherosis

    公开(公告)号:ZA200502073B

    公开(公告)日:2006-05-31

    申请号:ZA200502073

    申请日:2005-03-11

    Applicant: BASF AG

    Abstract: A process for preparation of polyetherols includes reaction of at least one alkylene oxide with at least one starter compound in the presence of a catalyst which is a multimetal oxide compound. A process for preparation of polyetherols includes reaction of at least one alkylene oxide with at least one starter compound in the presence of a catalyst, i.e. a multimetal oxide compound of formula (I). M1p(M2qOn(OH)2(3-n))x (I) M1 = at least 1 element from the groups IA, IIA, IIIA, IVA, VA, IB, IIB, IIIB, IVB, VB, VIB, VIIB and/or VIIIB; M2 = at least one element from groups IVA, VA and/or VIA, n = 2 or 3, p = 0 or fractional or whole number greater than 0, q = fractional or whole number greater than 0, x = 1-20 fractional or whole number. An Independent claim is included for a polyetherol obtained as above.

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