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公开(公告)号:AT17001T
公开(公告)日:1986-01-15
申请号:AT83101452
申请日:1983-02-16
Applicant: BASF AG
Inventor: DANZ ECKEHARD DR , DUEMBGEN GERD DR , MIESEN ERNEST , SCHMIDT JOAHNNES E DR , WIRTH FRIEDRICH DR
IPC: C07D307/60 , C07C51/573 , C07D307/89
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公开(公告)号:DE2919661A1
公开(公告)日:1980-11-27
申请号:DE2919661
申请日:1979-05-16
Applicant: BASF AG
Inventor: DUEMBGEN GERD DR , VOELKL ERFRIED DR , PFORR GERHARD DR
Abstract: To destroy phosgene contained in gases, the phosgene is decomposed catalytically in the presence of active carbon by hydrolysis with water vapor, in the absence of liquid water, at above the dew point of water.
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公开(公告)号:DE2338111A1
公开(公告)日:1975-02-20
申请号:DE2338111
申请日:1973-07-27
Applicant: BASF AG
Inventor: DUEMBGEN GERD DR , ENGELBACH HEINZ DR , KRABETZ RICHARD DR , LEBERT ULRICH DR , RUCKH PETER DR , THIESSEN FRITZ DR , WILLERSINN CARL-HEINZ DR
IPC: B01J23/88 , B01J23/887 , B01J23/888 , B01J23/89 , B01J27/186 , B01J27/192 , B01J27/195 , C07C45/34 , C07C45/35 , C07C47/20 , C07C47/22 , C07C121/30
Abstract: Catalytic oxidn. or ammonoxidation of alpha-olefins to the corresp. alpha, beta-unsatd. aldehydes or nitriles in the vapour phase at 280-450 degrees C, opt. in the presence of steamd and/or NH3 using oxygen and inert gas in the presence of a catalyst of formula:also contains ZnO oxide, pref. as Znh in the above formula where Me1 is In, La, Ga, Al or a mixt. of these; Me2 is Fe and/or Cu; Me3 is Ni and/or Co; Me4 is >=1 of P, B, As, Cr, V and W; Me5 is >=1 of Ta, Sm, Nb, Ag, Pb, Mn, Re, Sn, Ge, Mg, Ca and Ba; a is 0.1-6, pref. 0.5-3; b is 0.005-3, pref. 0.01-1; c is 0.1-8, pref. 0.5-3; d is 0-16, pref. 2-8; e is 0-6 pref. 0.1-3; g is 36-102, pref. 38-95; h is pref. 0.5-6, partic. 2-4; d+h is pref. 4-12, partic, 6-10. The ZnO gives increased selectively.
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公开(公告)号:DE1958463A1
公开(公告)日:1971-06-03
申请号:DE1958463
申请日:1969-11-21
Applicant: BASF AG
Inventor: MERGER FRANZ DR , FUCHS WERNER DR , OBERHANSBERG JOACHIM DR , DUEMBGEN GERD DR
IPC: C07C69/675 , C07C69/66
Abstract: acid monoester, useful as raw material in the manufacture of synthetic resins and plasticisers, is produced from 2:2-dimethyl-3-hydroxypropanol obtained by reacting HCHO with isobutyraldehyde at elevated temps. in the presence of tert. amines. This reaction mixture, after removal of free amine, is then reacted at 120 - 175 degrees C in the presence of an organic salt of a tert. amine of mol. wt. below 250.
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15.
公开(公告)号:CZ282186B6
公开(公告)日:1997-05-14
申请号:CS386792
申请日:1992-12-23
Applicant: BASF AG
Inventor: DUEMBGEN GERD DR , FIEDLER ECKHARD DR , HAMMON ULRICH DR , THIESSEN FRITZ DR , VOGEL HERBERT DR
IPC: C07C51/44 , C07C51/487 , C07C51/50 , C07C57/04 , C07C57/055 , C07C57/07
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公开(公告)号:CZ386792A3
公开(公告)日:1993-12-15
申请号:CS386792
申请日:1992-12-23
Applicant: BASF AG
Inventor: DUEMBGEN GERD DR , FIEDLER ECKHARD DR , HAMMON ULRICH DR , THIESSEN FRITZ DR , VOGEL HERBERT DR
IPC: C07C51/44 , C07C51/487 , C07C51/50 , C07C57/04 , C07C57/055 , C07C57/07
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公开(公告)号:DE4201697A1
公开(公告)日:1993-07-29
申请号:DE4201697
申请日:1992-01-23
Applicant: BASF AG
Inventor: DUEMBGEN GERD DR , FIEDLER ECKHARD DR , HAMMON ULRICH DR , THIESSEN FRITZ DR , VOGEL HERBERT DR
IPC: C07C51/44 , C07C51/487 , C07C51/50 , C07C57/04 , C07C57/055 , C07C57/07
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公开(公告)号:DE3360051D1
公开(公告)日:1985-02-28
申请号:DE3360051
申请日:1983-04-05
Applicant: BASF AG
Inventor: DUEMBGEN GERD DR , FOUQUET GERD DR , KRABETZ RICHARD DR , LUCAS EKHART DR , MERGER FRANZ DR , NEES FRIEDBERT DR
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公开(公告)号:DE3308625A1
公开(公告)日:1984-09-13
申请号:DE3308625
申请日:1983-03-11
Applicant: BASF AG
Inventor: DUEMBGEN GERD DR , FOUQUET GERD DR , KRABETZ RICHARD DR , MERGER FRANZ DR , NEES FRIEDBERT DR
IPC: B01J27/18 , B01J27/19 , B01J27/198 , B01J27/199 , C07B61/00 , C07C51/00 , C07C51/25 , C07C57/04 , C07C57/055 , C07C67/00
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公开(公告)号:DE1938102A1
公开(公告)日:1972-03-02
申请号:DE1938102
申请日:1969-07-26
Applicant: BASF AG
Inventor: DUEMBGEN GERD DR , HEESEMANN GUENTHER DIPL-ING , HOHENSCHUTZ HEINZ DR , KERBER HORST DR , NAGEL OTTO DR DIPL-ING , DR ROTHE ROBERT , WALZ HELMUT DR
Abstract: 1308567 Production of aldehydes and ketones by the oxo process BADISCHE ANILIN- & SODA-FABRIK AG 24 July 1970 [26 July 1969] 35891/70 Heading C2C Aldehydes and/or alcohols are produced by the oxo process by reacting an olefinically unsaturated compound with carbon monoxide and hydrogen in the presence of a cobalt carbonyl compound at elevated temperature, super atmospheric pressure and the reactants being introduced into the reaction zone at high speed wherein the reactants are introduced into a mixing zone which is located in the reaction zone in which it extends in the direction of introduction of the reactants, the mixing zone having a diameter which is from twice to fifty times the mean diameter of the stream of reactants supplied and having a length which is from three to thirty times its hydraulic diameter. The diameter of a stream of reactants is the diameter of a circle having the same area as the cross-section of a wand nozzle or other inlet opening and the hydraulic diameter is the diameter of a cylindrical tube which exhibits the same pressure drop as the mixing zone in question having the same length and the same throughput.
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