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公开(公告)号:DE3676875D1
公开(公告)日:1991-02-21
申请号:DE3676875
申请日:1986-04-11
Applicant: BASF AG
Inventor: HARTIG JUERGEN DR , STOESSEL ARMIN DR , LUCAS EKHART DR
IPC: C07C27/12 , C07C27/00 , C07C27/26 , C07C29/132 , C07C29/50 , C07C35/08 , C07C45/00 , C07C45/33 , C07C45/53 , C07C45/80 , C07C45/82 , C07C49/403 , C07C67/00 , C07C407/00 , C07C409/06 , C07C409/14
Abstract: Reaction mixtures which contain cyclohexanol, cyclohexanone and cyclohexyl hydroperoxide and are obtained in the oxidation of cyclohexane with molecular oxygen, or with a gas containing this, in the liquid phase are worked up by a process in which the reaction mixture is hydrogenated in the presence of a noble metal catalyst at elevated temperatures and under superatmospheric pressure, the resulting mixture is treated with an aqueous alkali metal carbonate solution, and cyclohexanol and cyclohexanone are separated off by distillation.
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公开(公告)号:DE3360051D1
公开(公告)日:1985-02-28
申请号:DE3360051
申请日:1983-04-05
Applicant: BASF AG
Inventor: DUEMBGEN GERD DR , FOUQUET GERD DR , KRABETZ RICHARD DR , LUCAS EKHART DR , MERGER FRANZ DR , NEES FRIEDBERT DR
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公开(公告)号:DE3763474D1
公开(公告)日:1990-08-09
申请号:DE3763474
申请日:1987-01-13
Applicant: BASF AG
Inventor: HARTIG JUERGEN DR , HERRMANN GUENTER DR , LUCAS EKHART DR
IPC: C07C49/403 , B01J31/00 , B01J31/18 , B01J31/26 , C07C27/00 , C07C27/12 , C07C27/26 , C07C29/50 , C07C35/08 , C07C45/00 , C07C45/33 , C07C45/53 , C07C45/78 , C07C45/80 , C07C67/00 , C07C409/06
Abstract: Reaction mixtures which contain cyclohexyl hydroperoxide, cyclohexanol and cyclohexanone and are obtained by oxidizing cyclohexane with molecular oxygen, or a gas containing this, in the liquid phase at from 130 DEG to 200 DEG C. under from 5 to 25 bar are worked up by treatment with an aqueous alkali solution in the presence of a cobalt salt at elevated temperatures by an improved process wherein a phosphonic acid compound of the formula I where X is alkylene or 2 to 6 carbon atoms, R1 is -CH2PO3H and R2, R3 and R4 may be identical or different and are each -CH2PO3H, -CH2OH, hydrogen or alkyl of 1 to 4 carbon atoms, is concomitantly used.
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公开(公告)号:DE3601218A1
公开(公告)日:1987-07-23
申请号:DE3601218
申请日:1986-01-17
Applicant: BASF AG
Inventor: HARTIG JUERGEN DR , HERRMANN GUENTER DR , LUCAS EKHART DR
IPC: C07C49/403 , B01J31/00 , B01J31/18 , B01J31/26 , C07C27/00 , C07C27/12 , C07C27/26 , C07C29/50 , C07C35/08 , C07C45/00 , C07C45/33 , C07C45/53 , C07C45/78 , C07C45/80 , C07C67/00 , C07C409/06 , C07C27/14 , C07C179/053
Abstract: Reaction mixtures which contain cyclohexyl hydroperoxide, cyclohexanol and cyclohexanone and are obtained by oxidizing cyclohexane with molecular oxygen, or a gas containing this, in the liquid phase at from 130 DEG to 200 DEG C. under from 5 to 25 bar are worked up by treatment with an aqueous alkali solution in the presence of a cobalt salt at elevated temperatures by an improved process wherein a phosphonic acid compound of the formula I where X is alkylene or 2 to 6 carbon atoms, R1 is -CH2PO3H and R2, R3 and R4 may be identical or different and are each -CH2PO3H, -CH2OH, hydrogen or alkyl of 1 to 4 carbon atoms, is concomitantly used.
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公开(公告)号:DE3661627D1
公开(公告)日:1989-02-09
申请号:DE3661627
申请日:1986-07-11
Applicant: BASF AG
Inventor: HERRMANN GUNTHER DR , LUCAS EKHART DR
IPC: C07C27/12 , C07C27/00 , C07C27/26 , C07C29/94 , C07C45/33 , C07C45/78 , C07C51/00 , C07C51/31 , C07C51/50 , C07C55/14 , C07C67/00
Abstract: Aqueous acidic scrubbing liquors obtained when oxidation mixtures from the oxidation of cyclohexane are scrubbed with water are stabilized by a process in which the scrubbing liquors are heated at from 50 DEG to 130 DEG C. in the presence of a water-soluble vanadium compound.
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公开(公告)号:DE3526412A1
公开(公告)日:1987-02-05
申请号:DE3526412
申请日:1985-07-24
Applicant: BASF AG
Inventor: HERRMANN GUENTER DR , LUCAS EKHART DR
IPC: C07C27/12 , C07C27/00 , C07C27/26 , C07C29/94 , C07C45/33 , C07C45/78 , C07C51/00 , C07C51/31 , C07C51/50 , C07C55/14 , C07C67/00 , C07C35/08 , C07C49/403 , B01D53/14
Abstract: Aqueous acidic scrubbing liquors obtained when oxidation mixtures from the oxidation of cyclohexane are scrubbed with water are stabilized by a process in which the scrubbing liquors are heated at from 50 DEG to 130 DEG C. in the presence of a water-soluble vanadium compound.
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公开(公告)号:DE3513568A1
公开(公告)日:1986-10-16
申请号:DE3513568
申请日:1985-04-16
Applicant: BASF AG
Inventor: HARTIG JUERGEN DR , STOESSEL ARMIN DR , LUCAS EKHART DR
IPC: C07C27/12 , C07C27/00 , C07C27/26 , C07C29/132 , C07C29/50 , C07C35/08 , C07C45/00 , C07C45/33 , C07C45/53 , C07C45/80 , C07C45/82 , C07C49/403 , C07C67/00 , C07C407/00 , C07C409/06 , C07C409/14
Abstract: Reaction mixtures which contain cyclohexanol, cyclohexanone and cyclohexyl hydroperoxide and are obtained in the oxidation of cyclohexane with molecular oxygen, or with a gas containing this, in the liquid phase are worked up by a process in which the reaction mixture is hydrogenated in the presence of a noble metal catalyst at elevated temperatures and under superatmospheric pressure, the resulting mixture is treated with an aqueous alkali metal carbonate solution, and cyclohexanol and cyclohexanone are separated off by distillation.
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