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公开(公告)号：DE3773780D1
公开(公告)日：1991-11-21
申请号：DE3773780
申请日：1987-07-14
Applicant: BASF AG
Inventor： ZEHNER PETER DR , HOFFMANN HERWIG DR , RICHTER WOLFGANG DR , STUETZER DIETER DR , STROHMEYER MAX DR , WALZ HELMUT DR , WEIPPERT ERICH DR
Abstract: The olefin is introduced into the bottom zone of the hydroformylation reactor contg. a liq. reaction zone making up 60-85% of the reactor vol., at 1-40 bar and 50-140 deg. C, using Rh complex cpds. as catalysts. The gaseous reaction prods. and reaction partners are removed from the hydroformylation reactor. The reaction prods. are sepd. and most of the remaining gas is returned to the reactor as recycle gas. The novelty consists in charging 20-80 vol.% of the recycle gas to the hydroformylation reactor above the liq. reaction zone and/or below the liq. surface in the top quarter of the liq. reaction zone.
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公开(公告)号：AT254179B
公开(公告)日：1967-05-10
申请号：AT552465
申请日：1965-06-18
Applicant: BASF AG
Inventor： WALZ HELMUT DR , WALLIS ALBRECHT DR , SINN RICHARD DR , NIENBURG HANS DR
IPC: C07C51/47
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公开(公告)号：MY127613A
公开(公告)日：2006-12-29
申请号：MYPI20012329
申请日：2001-05-17
Applicant: BASF AG
Inventor： HOFFMANN HERWIG DR , ROEPER MICHAEL PROF DR , BLANKERTZ HEINRICH-JOSEF DR , STROHMEYER MAX DR , WALZ HELMUT DR , ZINKE-ALLMANG HELMUT DR
IPC: C07C29/14 , C07B61/00 , C07C29/141 , C07C29/16 , C07C31/10 , C07C31/12 , C07C31/125
Abstract: THE INVENTION RELATES TO A PROCESS FOR THE PREPARATION OF SATURATED C3-C20-ALCOHOLS IN WHICH A LIQUID HYDROGENERATION FEED COMPRISING AT LEAST ONE C3-C20-ALDEHYDE IS PASSED OVER A BED OF A HYDROGENERATION CATALYST IN THE PRESENCE OF A HYDROGEN-CONTAINING GAS , WHICH COMPRISES ADDING TO THE HYDROGENERATION FEED AN AMOUNT , HOMOGENEOUSLY SOLUBLE THEREIN , OF A SALT-LIKE BESE . THE ADDITION OF BASE SUPPRESSES SIDE REACTIONS, SUCH AS ACETALIZATION , ALDOLIZATION , TISCHTSCHENKO REACTION OR ETHER FORMATION .
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公开(公告)号：DE1938102A1
公开(公告)日：1972-03-02
申请号：DE1938102
申请日：1969-07-26
Applicant: BASF AG
Inventor： DUEMBGEN GERD DR , HEESEMANN GUENTHER DIPL-ING , HOHENSCHUTZ HEINZ DR , KERBER HORST DR , NAGEL OTTO DR DIPL-ING , DR ROTHE ROBERT , WALZ HELMUT DR
Abstract: 1308567 Production of aldehydes and ketones by the oxo process BADISCHE ANILIN- & SODA-FABRIK AG 24 July 1970 [26 July 1969] 35891/70 Heading C2C Aldehydes and/or alcohols are produced by the oxo process by reacting an olefinically unsaturated compound with carbon monoxide and hydrogen in the presence of a cobalt carbonyl compound at elevated temperature, super atmospheric pressure and the reactants being introduced into the reaction zone at high speed wherein the reactants are introduced into a mixing zone which is located in the reaction zone in which it extends in the direction of introduction of the reactants, the mixing zone having a diameter which is from twice to fifty times the mean diameter of the stream of reactants supplied and having a length which is from three to thirty times its hydraulic diameter. The diameter of a stream of reactants is the diameter of a circle having the same area as the cross-section of a wand nozzle or other inlet opening and the hydraulic diameter is the diameter of a cylindrical tube which exhibits the same pressure drop as the mixing zone in question having the same length and the same throughput.
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公开(公告)号：MY131979A
公开(公告)日：2007-09-28
申请号：MYPI20013045
申请日：2001-06-27
Applicant: BASF AG
Inventor： WALZ HELMUT DR , SCHONMANN WILLI DR , MULLER ROLF , KROKOSZINSKI ROLAND DR
Abstract: OLEFINS HAVING FROM 2 TO 8 CARBON ATOMS ARE HYDROFORMYLATED IN A PROCESS IN WHICH (I) AN OLEFIN-CONTAINING FEED IN WHICH A PROPORTION OF A SATURATED HYDROCARBON HAVING FROM 2 TO 8 CARBON ATOMS IS PRESENT AND ALSO CARBON MONOXIDE AND HYDROGEN ARE FED INTO A REACTION ZONE AND REACTED IN THE PRESENCE OF A HYDROFORMYLATION CATALYST, (II) A STREAM CONSISTING ESSENTIALLY OF UNREACTED OLEFIN AND SATURATED HYDROCARBON IS SEPARATED OFF FROM THE OUTPUT FROM THE REACTION ZONE, (III) THE STREAM IS SEPARATED INTO AN OLEFIN-ENRICHED FRACTION AND AN OLEFIN-DEPLETED FRACTION BY RECTIFICATION, AND (IV) AT LEAST PART OF THE OLEFIN-ENRICHED FRACTION IS RECIRCULATED TO THE REACTION ZONE.(FIG 1)
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Patent Agency Ranking
公开(公告)号：DE3625261A1
公开(公告)日：1988-02-04
申请号：DE3625261
申请日：1986-07-25
Applicant: BASF AG
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公开(公告)号：DE1643745A1
公开(公告)日：1971-07-01
申请号：DE1643745
申请日：1968-01-19
Applicant: BASF AG
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公开(公告)号：AT68462T
公开(公告)日：1991-11-15
申请号：AT87110130
申请日：1987-07-14
Applicant: BASF AG
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公开(公告)号：DE3228881A1
公开(公告)日：1984-02-09
申请号：DE3228881
申请日：1982-08-03
Applicant: BASF AG
Inventor： BAER KARL DR , ELLIEHAUSEN HEINRICH DR , GRENACHER ARMIN VOLKER DR , HOFFMANN HERWIG DR , STROHMEYER MAX DR , WALZ HELMUT DR
IPC: B01J23/88 , B01J23/885 , C07C29/141 , C07C31/10 , C07C31/12 , C07C31/125
Abstract: Preparation of C3-C5-alcohols by hydrogenation of the corresponding aldehydes with hydrogen by means of a catalyst which, in ready-to-use but not yet reduced form, contains 5 to 70 % by weight of Al2O3 and/or Fe2O3 and 30 to 95 % by weight of a mixture of 100 parts by weight of NiO, 20 to 40 parts by weight of CuO, 0.5 to 6 parts by weight of MoO3 and 0 to 10 % by weight of Mn3O4, the catalyst having been prepared by reaction of an aqueous solution of the corresponding metal salts with an alkali metal carbonate solution under specified conditions, followed by drying, washing and heating.
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公开(公告)号：DE2404855A1
公开(公告)日：1975-08-21
申请号：DE2404855
申请日：1974-02-01
Applicant: BASF AG
Inventor： MOELL HANS DR , STROHMEYER MAX DR , KERBER HORST DR , APPL MAX DR , HOHENSCHUTZ HEINZ DR , WALZ HELMUT DR
Abstract: The formation of an emulsion when working up reaction mixtures containing butyraldehydes and cobalt is avoided by a treatment with gases containing molecular oxygen in an aqueous acid medium at an elevated temperature, at least twice the amount of molecular oxygen stoichiometrically required for the oxidation of the cobalt being used per gram atom of cobalt present in the oxoreaction mixture.
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