公开(公告)号：AU6739490A

公开(公告)日：1991-06-26

申请号：AU6739490

申请日：1990-11-13

Applicant: BASF AG

Inventor： DUNG BERNHARD ,  TRIESELT WOLFGANG ,  HAHN ERWIN ,  PERNER JOHANNES ,  OFTRING ALFRED

IPC: C11D3/28 ,  C07D265/22 ,  C11D3/39 ,  C11D3/42

Abstract: PCT No. PCT/EP90/01897 Sec. 371 Date Mar. 3, 1992 Sec. 102(e) Date Mar. 3, 1992 PCT Filed Nov. 13, 1990 PCT Pub. No. WO91/08279 PCT Pub. Date Jun. 13, 1991.Heterocyclic compounds which are useful as bleach activators or optical brighteners in washing and cleaning agents have the formula (* CHEMICAL STRUCTURE *) I where the variables have the following meanings: X is O, S or the group N-R3, where R3 is hydrogen, C1-C25-alkyll C1-C25-acyl or an aryl group of up to 12 carbon atoms, Y is CH or N, R1 for X=S or N-R3 is hydrogen, a C1-C25-alkyl or C2-C25-alkenyl group or a phenyl radical which may be additionally substituted by one or two C1-C4-alkyl, C1-C4-alkoxy, hydroxyl, carboxyl, sulfo, amino, C1-C4-acylamino, nitro or cyano groups or chlorine or bromine atoms, which substituents, if there are two of them, may be identical or different, R1 for X=O is phenyl, o-, m- or p-tolyl, p-chlorophenyl, m-nitrophenyl, m-methoxyphenyl or m-methylsulfonylphenyl, R2 for X=S or N-R3 is hydrogen, a C1-C4-alkyl, C1-C4-alkoxy, hydroxyl, carboxyl, sulfo, amino or C1-C4-acylamino group or a chlorine or bromine atom, and R2 for X=O is hydrogen.

公开(公告)号：ES2076056T3

公开(公告)日：1995-10-16

申请号：ES93902188

申请日：1993-01-14

Applicant: BASF AG

Inventor： SCHWENDEMANN VOLKER ,  GLASER KLAUS ,  TSCHANG CHUNG-JI ,  BURKHART BERND ,  OFTRING ALFRED ,  DUNG BERNHARD

IPC: C25D3/14 ,  C25D3/18 ,  C25D3/16

Abstract: PCT No. PCT/EP93/00063 Sec. 371 Date Jul. 25, 1994 Sec. 102(e) Date Jul. 25, 1994 PCT Filed Jan. 14, 1993 PCT Pub. No. WO93/15241 PCT Pub. Date Aug. 5, 1993.Nickelized shaped articles are produced by electrodeposition of nickel from aqueous acidic baths containing as essential constituents one or more nickel salts, one or more inorganic acids and at least two brighteners by using as brighteners a mixture of A) from 2 to 98% by weight of one or more cyclic N-allylammonium or N-vinylammonium compounds I (I) where the nitrogen atom is part of a pyridine, quinoline or isoquinoline ring system which may additionally carry one or two C1- to C4-alkyl substituents or halogen atoms, R1, R3 and R4 are each hydrogen or C1- to C4-alkyl, R2 is hydrogen or methyl, m is from 0 to 4, n is from 1 to 4, and X(-) is an n-valent inorganic or organic anion which promotes solubility in water, and B) from 98 to 2% by weight of one or more acetylenically unsaturated compounds II R4-C 3BOND C-R5(II) where R4 and R5 are identical or different and each is C1- to C4-alkyl substituted by hydroxyl, sulfo, amino, C1- to C4-alkylamino or di(C1- to C4-alkyl)amino, although hydroxyl groups may have been reacted with from 1 to 10 mol of a C2- to C4-alkylene oxide or a mixture of such alkylene oxides and one of the radicals R4 and R5 may also be hydrogen or C1- to C4-alkyl.

公开(公告)号：AT127541T

公开(公告)日：1995-09-15

申请号：AT93902188

申请日：1993-01-14

Applicant: BASF AG

Inventor： SCHWENDEMANN VOLKER ,  GLASER KLAUS ,  TSCHANG CHUNG-JI ,  BURKHART BERND ,  OFTRING ALFRED ,  DUNG BERNHARD

IPC: C25D3/16 ,  C25D3/14 ,  C25D3/18

Abstract: PCT No. PCT/EP93/00063 Sec. 371 Date Jul. 25, 1994 Sec. 102(e) Date Jul. 25, 1994 PCT Filed Jan. 14, 1993 PCT Pub. No. WO93/15241 PCT Pub. Date Aug. 5, 1993.Nickelized shaped articles are produced by electrodeposition of nickel from aqueous acidic baths containing as essential constituents one or more nickel salts, one or more inorganic acids and at least two brighteners by using as brighteners a mixture of A) from 2 to 98% by weight of one or more cyclic N-allylammonium or N-vinylammonium compounds I (I) where the nitrogen atom is part of a pyridine, quinoline or isoquinoline ring system which may additionally carry one or two C1- to C4-alkyl substituents or halogen atoms, R1, R3 and R4 are each hydrogen or C1- to C4-alkyl, R2 is hydrogen or methyl, m is from 0 to 4, n is from 1 to 4, and X(-) is an n-valent inorganic or organic anion which promotes solubility in water, and B) from 98 to 2% by weight of one or more acetylenically unsaturated compounds II R4-C 3BOND C-R5(II) where R4 and R5 are identical or different and each is C1- to C4-alkyl substituted by hydroxyl, sulfo, amino, C1- to C4-alkylamino or di(C1- to C4-alkyl)amino, although hydroxyl groups may have been reacted with from 1 to 10 mol of a C2- to C4-alkylene oxide or a mixture of such alkylene oxides and one of the radicals R4 and R5 may also be hydrogen or C1- to C4-alkyl.

公开(公告)号：DE59203126D1

公开(公告)日：1995-09-07

申请号：DE59203126

申请日：1992-05-06

Applicant: BASF AG

Inventor： HAHN ERWIN ,  DUNG BERNHARD ,  BURKHART BERND ,  TSCHANG CHUNG-JI

IPC: C25D3/22 ,  C25D3/56

Abstract: PCT No. PCT/EP92/00983 Sec. 371 Date Nov. 9, 1993 Sec. 102(e) Date Nov. 9, 1993 PCT Filed May 6, 1992 PCT Pub. No. WO92/22683 PCT Pub. Date Dec. 23, 1992.The production of shining shaped articles coated with zinc or a zinc alloy by electrodeposition of zinc or a zinc alloy from acidic aqueous electrolytic baths which contain as essential components one or more zinc salts and, where appropriate, salts of the other alloy metals, one or more conducting salts, one or more surfactants and one or more brighteners, entails employing as brighteners compounds of the formula I I where R1 is C1-C8-alkoxy, phenoxy, benzyloxy, amino, C1-C6-alkylamino or di(C1-C6)alkylamino, R2 is C1-C4-alkyl, phenyl, benzyl or the meanings of R1, and Ar is phenyl or naphthyl which can additionally be substituted by one to three C1-C4-alkyl groups or C1-C4-alkoxy groups.

公开(公告)号：AU653505B2

公开(公告)日：1994-10-06

申请号：AU6739490

申请日：1990-11-13

Applicant: BASF AG

Inventor： DUNG BERNHARD ,  TRIESELT WOLFGANG ,  HAHN ERWIN ,  PERNER JOHANNES ,  OFTRING ALFRED

IPC: C11D3/28 ,  C07D265/22 ,  C11D3/39 ,  C11D3/42 ,  D06L3/02

Abstract: PCT No. PCT/EP90/01897 Sec. 371 Date Mar. 3, 1992 Sec. 102(e) Date Mar. 3, 1992 PCT Filed Nov. 13, 1990 PCT Pub. No. WO91/08279 PCT Pub. Date Jun. 13, 1991.Heterocyclic compounds which are useful as bleach activators or optical brighteners in washing and cleaning agents have the formula (* CHEMICAL STRUCTURE *) I where the variables have the following meanings: X is O, S or the group N-R3, where R3 is hydrogen, C1-C25-alkyll C1-C25-acyl or an aryl group of up to 12 carbon atoms, Y is CH or N, R1 for X=S or N-R3 is hydrogen, a C1-C25-alkyl or C2-C25-alkenyl group or a phenyl radical which may be additionally substituted by one or two C1-C4-alkyl, C1-C4-alkoxy, hydroxyl, carboxyl, sulfo, amino, C1-C4-acylamino, nitro or cyano groups or chlorine or bromine atoms, which substituents, if there are two of them, may be identical or different, R1 for X=O is phenyl, o-, m- or p-tolyl, p-chlorophenyl, m-nitrophenyl, m-methoxyphenyl or m-methylsulfonylphenyl, R2 for X=S or N-R3 is hydrogen, a C1-C4-alkyl, C1-C4-alkoxy, hydroxyl, carboxyl, sulfo, amino or C1-C4-acylamino group or a chlorine or bromine atom, and R2 for X=O is hydrogen.

公开(公告)号：CA2066570A1

公开(公告)日：1991-05-22

申请号：CA2066570

申请日：1990-11-13

Applicant: BASF AG

Inventor： DUNG BERNHARD ,  TRIESELT WOLFGANG ,  HAHN ERWIN ,  PERNER JOHANNES ,  OFTRING ALFRED

IPC: C11D3/28 ,  C07D265/22 ,  C11D3/39 ,  C11D3/42

Abstract: 2066570 9108279 PCTABS00005 Heterocyclic compounds of formula (I), where X stands for O, S or the N-R3 grouping, in which R3 stands for hydrogen, C1-C25 alkyl, C1-C25 acyl or an aryl group with up to 12 carbon atoms, Y stands for CH or N, R1 stands for X = S or N-R3, hydrogen, a C1-C25 alkyl or C2-C25 alkenyl group or a phenyl residue which can be additionally substituted by one or two C1-C4 alkyl, C1-C4 alkoxy, hydroxyl, carboxyl, sulpho, amino, C1-C4 acylamino, nitro or cyano groups or chlorine or bromine atoms, whereby for two substituents these may be the same or different, R1 stands for X = O, phenyl, o-, m- or p-tolyl, p-chlorphenyl, m-nitrophenyl, m-methoxyphenyl or m-methylsulphonylphenyl, R2 stands for X = S or NR3, hydrogen, a C1-C4 alkyl, C1-C4 alkoxy, hydroxyl, carboxyl, sulpho, amino or C1-C4 acylamino group or a chlorine or bromine atom and R2 stands for X = O or hydrogen, can be used as bleach activators or optical lighteners in washing and cleaning agents.