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公开(公告)号：DE2241714A1
公开(公告)日：1974-03-28
申请号：DE2241714
申请日：1972-08-24
Applicant: BASF AG
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公开(公告)号：DE2136396A1
公开(公告)日：1973-02-08
申请号：DE2136396
申请日：1971-07-21
Applicant: BASF AG
Inventor： DUEMBGEN GERD DR , ENGELBACH HEINZ DR , FREY WALTER DR , KRABETZ RICHARD DR , LEBERT ULRICH DR , SPITZL HERMANN DIPL ING , THIESSEN FRITZ DR , WILLERSINN CARL-HEINZ DR
Abstract: Acrylic acid practically devoid of water, acrolein, formaldehyde and acetic acid is obtained at particularly low cost by countercurrent scrubbing and quenching of the reaction gas formed in the catalytic oxidation of propylene and/or acrolein with a high-boiling, extremely hydrophobic solvent followed by processing of the extract.
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公开(公告)号：CH526496A
公开(公告)日：1972-08-15
申请号：CH901270
申请日：1970-06-15
Applicant: BASF AG
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公开(公告)号：DE1793433A1
公开(公告)日：1971-07-01
申请号：DE1793433
申请日：1968-09-17
Applicant: BASF AG
Inventor： REUSS GUENTER DR , ENGELBACH HEINZ DR , HAUG JUERGEN DR
Abstract: Process for manufacturing styrene, by catalytic dehydrogenation of ethylbenzene with oxygen or gases containing molecular oxygen in the presence of water vapor in a fluid bed at temperatures between 350 and 600º c, by the use of solid catalysts and regeneration of these catalysts by combustión, characterized by that the catalyst is regenerated by incompletely burning the carbonaceous deposits with oxygen or gases containing molecular oxygen only to such an extent that on average it contains during the transformation between 1 and 30% by weight, based on the catalyst, of said carbonaceous deposits. (Machine-translation by Google Translate, not legally binding)
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公开(公告)号：DE3761761D1
公开(公告)日：1990-04-05
申请号：DE3761761
申请日：1987-12-09
Applicant: BASF AG
Inventor： GRAF FRITZ DR , ENGELBACH HEINZ DR , HUPFER LEOPOLD DR , SCHULTHEISS HARALD DR , SPRAGUE MICHAEL JOLYON DR
Abstract: A process for the preparation of carbonyl compounds by oxidation of alcohols in the gas phase with a gas containing oxygen in the presence of catalysts containing copper or silver and a phosphorus compound that is volatile under the conditions of the reaction, the ratio of the mass of phosphorus to the mass of the alcohol being less than 0.5 ppm.
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Patent Agency Ranking
公开(公告)号：DE3643469A1
公开(公告)日：1988-06-30
申请号：DE3643469
申请日：1986-12-19
Applicant: BASF AG
Inventor： GRAF FRITZ DR , ENGELBACH HEINZ DR , HUPFER LEOPOLD DR , SCHULTHEISS HARALD DR , SPRAGUE MICHAEL JOLYON DR
Abstract: A process for the preparation of carbonyl compounds by oxidation of alcohols in the gas phase with a gas containing oxygen in the presence of catalysts containing copper or silver and a phosphorus compound that is volatile under the conditions of the reaction, the ratio of the mass of phosphorus to the mass of the alcohol being less than 0.5 ppm.
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公开(公告)号：DE3267908D1
公开(公告)日：1986-01-23
申请号：DE3267908
申请日：1982-07-15
Applicant: BASF AG
Inventor： SAUER WOLFGANG DR , HALBRITTER KLAUS DR , ENGELBACH HEINZ DR
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公开(公告)号：DE3061184D1
公开(公告)日：1983-01-05
申请号：DE3061184
申请日：1980-03-07
Applicant: BASF AG
Inventor： KRABETZ RICHARD DR , ENGELBACH HEINZ DR , PALM PETER , SPAHN HEINRICH DR , HERRMANN WALTER DR
Abstract: A coated catalyst comprising (a) an inert carrier having particles of not less than 100 mu m diameter and a surface area of up to 20 m2/g and (b) a coating which contains the catalytic material and adheres firmly to the outer surface and to the edge zone, near the surface, of the carrier particles, can be prepared by applying the catalytic material as a 10-70% strength suspension in water to the agitated carrier particles, which are at below 70 DEG C., if the suspension is sprayed, at a constant rate of from 0.01 to 2.0 kg of active material/hour/liter of carrier onto the carrier particles, while at the same time uniformly passing from 0.1 to 12 m3 (S.T.P.)/hour/liter of carrier of an inert gas at from 20 DEG to 300 DEG C. over the carrier particles, under conditions such that the water only evaporates incompletely but the water content of the resulting coating is less than the maximum degree of saturation of the catalytic material.
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公开(公告)号：DE3060108D1
公开(公告)日：1982-02-11
申请号：DE3060108
申请日：1980-03-07
Applicant: BASF AG
Inventor： KRABETZ RICHARD DR , FERRMANN WALTER DR , ENGELBACH HEINZ DR , PALM PETER , SOMMER KARL DR , SPAHN HEINRICH DR
IPC: B01J23/00 , B01J23/88 , B01J23/887 , B01J23/888 , B01J35/08 , B01J35/10 , B01J37/02 , C07C45/35 , C07C45/36 , C07C51/235 , C07C51/25 , C07C57/055
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公开(公告)号：DE2338111A1
公开(公告)日：1975-02-20
申请号：DE2338111
申请日：1973-07-27
Applicant: BASF AG
Inventor： DUEMBGEN GERD DR , ENGELBACH HEINZ DR , KRABETZ RICHARD DR , LEBERT ULRICH DR , RUCKH PETER DR , THIESSEN FRITZ DR , WILLERSINN CARL-HEINZ DR
IPC: B01J23/88 , B01J23/887 , B01J23/888 , B01J23/89 , B01J27/186 , B01J27/192 , B01J27/195 , C07C45/34 , C07C45/35 , C07C47/20 , C07C47/22 , C07C121/30
Abstract: Catalytic oxidn. or ammonoxidation of alpha-olefins to the corresp. alpha, beta-unsatd. aldehydes or nitriles in the vapour phase at 280-450 degrees C, opt. in the presence of steamd and/or NH3 using oxygen and inert gas in the presence of a catalyst of formula:also contains ZnO oxide, pref. as Znh in the above formula where Me1 is In, La, Ga, Al or a mixt. of these; Me2 is Fe and/or Cu; Me3 is Ni and/or Co; Me4 is >=1 of P, B, As, Cr, V and W; Me5 is >=1 of Ta, Sm, Nb, Ag, Pb, Mn, Re, Sn, Ge, Mg, Ca and Ba; a is 0.1-6, pref. 0.5-3; b is 0.005-3, pref. 0.01-1; c is 0.1-8, pref. 0.5-3; d is 0-16, pref. 2-8; e is 0-6 pref. 0.1-3; g is 36-102, pref. 38-95; h is pref. 0.5-6, partic. 2-4; d+h is pref. 4-12, partic, 6-10. The ZnO gives increased selectively.
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