公开(公告)号：DE3870543D1

公开(公告)日：1992-06-04

申请号：DE3870543

申请日：1988-08-04

Applicant: BASF AG

Inventor： FISCHER ROLF DR ,  GOSCH HANS-JUERGEN DR ,  HARDER WOLFGANG DR ,  MALSCH KLAUS-DIETER DR ,  EGGERSDORFER MANFRED DR ,  FRANZ LOTHAR DR ,  ZIMMERMANN HORST DR ,  BRENNER KARL ,  HALBRITTER KLAUS DR ,  SAUER WOLFGANG DR ,  SCHEIPER HANS-JUERGEN

IPC: B01J27/18 ,  B01J27/19 ,  C07B61/00 ,  C07C27/00 ,  C07C29/136 ,  C07C29/147 ,  C07C29/149 ,  C07C29/17 ,  C07C29/56 ,  C07C31/20 ,  C07C67/00 ,  C07D307/08

Abstract: Catalytic hydrogenation (H2) of maleic acid (VI) or anhydride (IV), succinic acid (VII) or anhydride (V) or fumaric acid (VIII) gives THF (I) and gamma-butyrolactone (II), and 1,4-butanediol, (III). The catalyst is composed of oxides of cobalt (40-60% wt., as metal), copper (13-17 wt.%), molybdenum (0.5-5 wt.% as MoO3), manganese (0-8 wt.% as metal) and phosphorus (0.1-5% wt. as H3PO4). Temps. for reaction are 150-350 deg.C, pressures 50-350 bar. The starting materials can be used molten, or in soln., suitable solvents being water, gamma-butyrolactone, dioxan, tetrahydropyran, tetrahydrofuran, diethyl ether. Prod. ratios depend upon temp., reaction time (throughput) and catalyst compsns. Catalysts suitable are for example, 3% H3PO4, 64.2% CoO (50.5% Co) 18.5% CuO (14.8% Cu), 6.7% Mn3O4 (4.8% Mn) and 3.7% MoO3; also 3% H3PO4, 64.2% CoO, 18.5% CuO, 3.7% MoO3 (all % are wt.%). Ideal temp. is 170-250 deg.C, ideal pressures 250-300 bar.

公开(公告)号：DE2960921D1

公开(公告)日：1981-12-17

申请号：DE2960921

申请日：1979-03-28

Applicant: BASF AG

Inventor： SAUER WOLFGANG DR ,  FLIEGE WERNER DR ,  DUDECK CHRISTIAN DR ,  PETRI NORBERT DR

IPC: B01J23/00 ,  B01J35/00 ,  C07C45/00 ,  C07C45/29 ,  C07C45/38 ,  C07C47/20 ,  C07C47/228 ,  C07C47/52 ,  C07C47/54 ,  C07C67/00 ,  C07C213/00 ,  C07C223/00

Abstract: Aromatic and araliphatic aldehydes are prepared by oxidizing corresponding alcohols with oxygen in the presence of a silver catalyst of a defined particle size, and under defined temperature conditions. The products are starting materials for the preparation of dyes, pesticides, plastics and scents.

公开(公告)号：DE59106173D1

公开(公告)日：1995-09-14

申请号：DE59106173

申请日：1991-02-09

Applicant: BASF AG

Inventor： ZIMMERMANN HORST DR ,  BRENNER KARL ,  SCHEIPER HANS-JUERGEN ,  SAUER WOLFGANG DR ,  HARTMANN HORST

IPC: C07D307/08 ,  C07D307/32 ,  C07D307/33 ,  C07D315/00

Abstract: Process for the preparation of THF or of THF and gamma -butyrolactone from the hydrogenation product of the hydrogenation of maleic acid, succinic acid, maleic anhydride, succinic anhydride and/or fumaric acid by treating the crude hydrogenation product without prior workup at 100 to 300 DEG C with proton acids and isolating pure tetrahydrofuran and gamma -butyrolactone from the reaction mixture obtained by distillation.

公开(公告)号：DE3726510A1

公开(公告)日：1989-02-16

申请号：DE3726510

申请日：1987-08-08

Applicant: BASF AG

Inventor： EGGERSDORFER MANFRED DR ,  FRANZ LOTHAR DR ,  ZIMMERMANN HORST DR ,  BRENNER KARL ,  HALBRITTER KLAUS DR ,  SAUER WOLFGANG DR ,  SCHEIPER HANS-JUERGEN

IPC: C07C29/17 ,  C07D307/08

Abstract: Process for the preparation of tetrahydrofuran or of mixtures which, in addition to tetrahydrofuran, contain gamma -butyrolactone and/or 1,4-butanediol, by catalytic hydrogenation of maleic acid, succinic acid, fumaric acid, maleic anhydride or succinic anhydride at temperatures from 150 to 350@C and at pressures from 50 to 350 bar on a catalyst which contains, as catalytically active metal, cobalt and at least one of the elements copper and phosphorus.

公开(公告)号：DE3061326D1

公开(公告)日：1983-01-20

申请号：DE3061326

申请日：1980-05-08

Applicant: BASF AG

Inventor： SAUER WOLFGANG DR ,  HOFFMANN WOLFGANG DR

IPC: C07C47/127 ,  B01J8/02 ,  B01J8/04 ,  B01J23/00 ,  B01J23/50 ,  C07B61/00 ,  C07C45/00 ,  C07C45/38 ,  C07C45/78 ,  C07C45/81 ,  C07C67/00

Abstract: Glyoxal is prepared by oxidizing glycol in the presence of a silver catalyst, with subsequent or partial condensation of glycol, glyoxal, glycol aldehyde, formaldehyde and/or water by treatment with water or aqueous glyoxal solution in fine dispersion, under specific conditions with regard to the temperature and dispersion of the treatment liquid. The glyoxal which can be prepared by the process of the invention is a wrinkle-resist agent, an assistant for increasing the tear strength and elasticity of fiber materials, a tanning agent, a photographic hardener and a valuable starting material for the production of synthetic resins, textile assistants, paper assistants and plastics.

公开(公告)号：ES2075229T3

公开(公告)日：1995-10-01

申请号：ES91101833

申请日：1991-02-09

Applicant: BASF AG

Inventor： ZIMMERMANN HORST DR ,  BRENNER KARL ,  SCHEIPER HANS-JURGEN ,  SAUER WOLFGANG DR ,  HARTMANN HORST

IPC: C07D307/08 ,  C07D307/32 ,  C07D307/33 ,  C07D315/00

Abstract: Process for the preparation of THF or of THF and gamma -butyrolactone from the hydrogenation product of the hydrogenation of maleic acid, succinic acid, maleic anhydride, succinic anhydride and/or fumaric acid by treating the crude hydrogenation product without prior workup at 100 to 300 DEG C with proton acids and isolating pure tetrahydrofuran and gamma -butyrolactone from the reaction mixture obtained by distillation.

公开(公告)号：DE3070191D1

公开(公告)日：1985-03-28

申请号：DE3070191

申请日：1980-03-20

Applicant: BASF AG

Inventor： ROSS KARL-HEINZ DR ,  DUDECK CHRISTIAN DR ,  HIMMELE WALTER DR ,  LEBKUECHER ROLF DR ,  SAUER WOLFGANG DR

IPC: C07D303/14 ,  C07D307/20 ,  C07D307/32 ,  C07D307/60

公开(公告)号：AT126222T

公开(公告)日：1995-08-15

申请号：AT91101833

申请日：1991-02-09

Applicant: BASF AG

Inventor： ZIMMERMANN HORST DR ,  BRENNER KARL ,  SCHEIPER HANS-JUERGEN ,  SAUER WOLFGANG DR ,  HARTMANN HORST

IPC: C07D307/08 ,  C07D307/32 ,  C07D307/33 ,  C07D315/00

Abstract: Process for the preparation of THF or of THF and gamma -butyrolactone from the hydrogenation product of the hydrogenation of maleic acid, succinic acid, maleic anhydride, succinic anhydride and/or fumaric acid by treating the crude hydrogenation product without prior workup at 100 to 300 DEG C with proton acids and isolating pure tetrahydrofuran and gamma -butyrolactone from the reaction mixture obtained by distillation.

公开(公告)号：DE4005293A1

公开(公告)日：1991-08-22

申请号：DE4005293

申请日：1990-02-20

Applicant: BASF AG

Inventor： ZIMMERMANN HORST DR ,  BRENNER KARL ,  SCHEIPER HANS-JUERGEN ,  SAUER WOLFGANG DR ,  HARTMANN HORST

IPC: C07D307/08 ,  C07D307/32 ,  C07D307/33 ,  C07D315/00

Abstract: Process for the preparation of THF or of THF and gamma -butyrolactone from the hydrogenation product of the hydrogenation of maleic acid, succinic acid, maleic anhydride, succinic anhydride and/or fumaric acid by treating the crude hydrogenation product without prior workup at 100 to 300 DEG C with proton acids and isolating pure tetrahydrofuran and gamma -butyrolactone from the reaction mixture obtained by distillation.

公开(公告)号：DE3267908D1

公开(公告)日：1986-01-23

申请号：DE3267908

申请日：1982-07-15

Applicant: BASF AG

Inventor： SAUER WOLFGANG DR ,  HALBRITTER KLAUS DR ,  ENGELBACH HEINZ DR

IPC: C07C47/127 ,  B01J23/00 ,  B01J23/50 ,  B01J23/72 ,  B01J23/89 ,  B01J27/16 ,  B01J27/18 ,  B01J37/02 ,  C07B61/00 ,  C07C29/38 ,  C07C45/00 ,  C07C45/38 ,  C07C67/00