THERMOPLASTIC MOULDING MASS
    12.
    发明专利

    公开(公告)号:DE3364835D1

    公开(公告)日:1986-09-04

    申请号:DE3364835

    申请日:1983-03-04

    Applicant: BASF AG

    Abstract: A thermoplastic molding material comprises copolymers I and II. Copolymer I is a high-impact (graft) copolymer which is derived from a monovinyl-aromatic monomer and a polymer or copolymer predominantly containing polymerized 1,3-diene units, and is present in a proportion of 0.1-1.0% by weight, based on the molding material. Copolymer II is a block copolymer with star-shaped branching, ie. a radial block copolymer, having an average of more than two branches per molecule. It is substantially derived from 55-80% by weight of a monovinyl-aromatic monomer and 20-45% by weight of a 1,3-diene monomer. The molding material may contain conventional assistants and is used for the production of blown film.

    PROCESS FOR THE PREPARATION OF LINEAR TRIBLOCK COPOLYMER MIXTURES, AND FORMED ARTICLES THEREFROM

    公开(公告)号:DE3061691D1

    公开(公告)日:1983-02-24

    申请号:DE3061691

    申请日:1980-10-01

    Applicant: BASF AG

    Abstract: A process for the preparation of a mixture of linear three-block copolymers which contain from 70 to 80% by weight of styrene units and from 20 to 30% by weight of elastomeric polymer segments based on a conjugated diene, in a total of three stages, specific conditions in respect of the initiator and of the monomers to be polymerized being essential in the individual stages in order to ensure the polymodal structure of the three-block copolymers. After complete reaction of the monomers, the mixture of the living polymers is treated with proton-active compounds, and the mixture of the block copolymers is isolated by removing the solvent. The compositions obtained by the novel process are transparent and clear and have good mechanical properties. They are furthermore readily processable by the methods conventionally used for thermoplastics. The compositions are particularly suitable for the production of moldings and of packaging materials.

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