公开(公告)号：DK0823890T3

公开(公告)日：2000-05-01

申请号：DK96914977

申请日：1996-04-23

Applicant: BASF AG

Inventor： OBERDORF KLAUS ,  GRAMMENOS WASSILIOS ,  SAUTER HUBERT ,  GITZ NORBERT

IPC: C07C67/327 ,  C07C67/333 ,  C07C67/343 ,  C07C69/734

Abstract: PCT No. PCT/EP96/01689 Sec. 371 Date Oct. 9, 1997 Sec. 102(e) Date Oct. 9, 1997 PCT Filed Apr. 23, 1996 PCT Pub. No. WO96/34847 PCT Pub. Date Nov. 7, 1996A process for the preparation of essentially isomerically pure methyl E-2-(2-aryloxymethylenephenyl)crotonates of the formula Ia Ia where R is an aromatic radical and R' is a C1-C3-alkyl group, which comprises first converting a suitable methyl 2-(2-aryloxymethylenephenyl)- alpha -ketoacetate with an alkyl metal compound of the formula IIIM-CH2-R'IIIwhere M is a metal ion equivalent into the corresponding methyl 2-(2-aryloxymethylenephenyl)- alpha -hydroxybutyrate of the formula IV, subsequently dehydrating IV in the presence of an acid to give a mixture of methyl E- and Z-2-(2-aryloxymethylenephenyl)crotonates and, subsequently, converting this mixture in the presence of a base in an inert polar solvent into the essentially isomerically pure methyl E-2-(2-aryloxymethylenephenyl)crotonate Ia.

公开(公告)号：DK0775107T3

公开(公告)日：1999-12-27

申请号：DK95930419

申请日：1995-07-28

Applicant: BASF AG

Inventor： HARREUS ALBRECHT ,  RANG HARALD ,  GITZ NORBERT ,  MOHR JUERGEN ,  HARTMANN HORST ,  GEHRER EUGEN ,  LAUTH GUENTER

IPC: B01J31/02 ,  C07B61/00 ,  C07C249/12 ,  C07C251/38 ,  C07C251/44 ,  C07C251/54

Abstract: Preparation of O-(2-hydroxyalkyl) oximes of formula (I), (R and R are alkyl or R and R and the common C atom are 5-membered to 7-membered cycloalkyl; R is alkyl) by causing a ketoxime II to react with an olefin oxide III in the presence of a tertiary amine or with a carbonate IV in the presence of a catalyst. The end products (I) are suitable for use as intermediates for crop protection agents.

公开(公告)号：DK0793645T3

公开(公告)日：1999-10-25

申请号：DK95938441

申请日：1995-11-10

Applicant: BASF AG

Inventor： M LLER BERND ,  M LLER RUTH ,  RIHL FRANZ ,  AMMERMANN EBERHARD ,  LORENZ GISELA ,  GITZ NORBERT ,  BAYER HERBERT ,  SAUTER HUBERT

IPC: A01N37/22 ,  A01N37/34 ,  A01N47/20 ,  A01N47/24 ,  A01N47/30 ,  A01N47/40 ,  A01P3/00 ,  A01P7/04 ,  C07C20060101 ,  C07C205/34 ,  C07C239/08 ,  C07C251/58 ,  C07C255/64 ,  C07C259/06 ,  C07C269/06 ,  C07C271/28 ,  C07C271/38 ,  C07C271/58 ,  C07C271/60 ,  C07C273/18 ,  C07C275/64 ,  C07C317/26 ,  C07C317/28 ,  C07C323/18 ,  C07C323/23 ,  C07C327/38 ,  C07C327/42 ,  C07D213/56 ,  C07D239/24 ,  C07D241/10 ,  C07D521/00

Abstract: PCT No. PCT/EP95/04428 Sec. 371 Date May 6, 1997 Sec. 102(e) Date May 6, 1997 PCT Filed Nov. 10, 1995 PCT Pub. No. WO96/16030 PCT Pub. Date May 30, 1996Iminooxymethyleneanilides of the formula I where the substituents and the index have the following meanings: R is hydrogen, unsubst. or subst. alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, cycloalkynyl, alkylcarbonyl or alkoxycarbonyl; R1 is alkyl, alkenyl, alkynyl, cycloalkyl or cycloalkenyl and in the case where X is NRa, additionally hydrogen; X is a direct bond, O or NRa; Ra is hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl or cycloalkenyl; R2 is cyano, nitro, trifluoromethyl, halogen, alkyl or alkoxy; n is 0, 1 or 2; R3 is hydrogen, hydroxyl, cyano, cyclopropyl, trifluoromethyl, halogen, alkyl, alkoxy or alkylthio; R4 is hydrogen, hydroxyl, halogen, alkyl, haloalkyl, alkoxy, alkylthio, unsubstituted or substituted cycloalkyl, heterocyclyl, aryl, arylalkyl, hetaryl or hetarylalkyl; R5 is hydrogen, unsubstituted or substituted alkyl, cycloalkyl, alkenyl, alkynyl, alkylcarbonyl, alkenylcarbonyl, alkynylcarbonyl or alkylsulfonyl, unsubstituted or substituted aryl, hetaryl, arylcarbonyl, hetarylcarbonyl, arylsulfonyl or hetarylsulfonyl; and their salts, processes and intermediates for their preparation and compositions containing them.