Abstract:
PROBLEM TO BE SOLVED: To obtain the subject new compound useful for controlling harmful animals and harmful fungi. SOLUTION: This compound is shown by formula I Y is a halogen, a 1-4C alkyl or the like; (n) is 0-2; E is a group of formula II (V is O or the like); T is O or oxymethylene; Z is a group X [X is a (substituted) heterocyclyl, a (substituted) aryl or the like], N=CWR [W is a (substituted) 1-6C alkyl or the like; R is H, cyano or the like] or the like} such as N-methyl-5-[2-(o-tolyloxymethylene)phenyl]-1,3- oxazolidine-2,4-dione.The compound of formula I, for example, in the case in which it is a compound of formula III, is obtained by a process for acylating an alkyl α- hydroxy-α-phenylacetate with phosgene or the like to give a compound of formula IV and further reacting the compound with a primary amine of the formula H2 N-R αto cause a ring formation and in the case of not advancing the ring formation by the strength of the amine, by a process for hydrolyzing an ester amide of formula V, then treating the resultant substance with an acid and reacting the treated substance with a compound of the formula Z-OH.
Abstract:
PROBLEM TO BE SOLVED: To obtain the subject new compounds useful as intermediate compounds for the production of phenylacetic acid derivatives suitable as bactericides, effective for a wide variety of phytopathogens and usable also as leaf and soil disinfectants. SOLUTION: The objective compound is expressed by the formula R5ON=C (R4)-C(R3)=NOH [R3 is H, cyano, nitro, hydroxy, amino, a halogen, a 1-4C (halo)alkyl or the like; R4 is H, cyano, nitro, hydroxy, amino, a halogen, a 1-6C alkyl or the like; R5 is H, a 1-10C alkyl or the like], e.g. (E,E)-2- methoxyimino-2-[2'-(1"-methyl,1"-acetyl)-iminoxymethyl]phenylacetic acid methyl ester. The objective compound of the formula can be produced by reacting the corresponding hydroxyimine of the formula HON=C(R4)-C(R3)=NOH with a nucleophilically substituted reagent of the formula R5-L2 (L2 is a nucleophilic exchangeable eliminable group such as a halogen or sulfonate).
Abstract:
PROBLEM TO BE SOLVED: To obtain a new compound having an excellent effect. SOLUTION: This invention relates to a derivative of phenylacetic acid expressed by formula I, and its salt, method of manufacturing of the same, a medicine including the compound to remove a toxic material and a poisonous fungus and its using method.
Abstract:
PROBLEM TO BE SOLVED: To prepare a new compound useful for controlling animal pests such as insects, arachnides or nematodes. SOLUTION: This compound is represented by formula I [R1 is a 1-4C alkyl; R2 is cyano, a 1-4C alkyl or the like; (m) is 0-2; R3 is H, a 1-4C alkyl or the like; R4 and R6 are each H, a 1-10C alkyl or the like; R5 is H, a 1-6C alkyl or the like], e.g. a compound represented by formula II. The compound represented by formula I is prepared by reacting a hydroxyimine represented by formula III with a benzyl derivative represented by formula IV (L1 is a nucleophilically replaceable leaving group).
Abstract:
The invention relates to bisoximether derivatives of formula (I) in which the variables have the following meanings: R represents halogen, C1-C4 alkyl, C1-C4 alkyl halide, C1-C4 alkoxy or C1-C4 alkoxy halide; n is 1 to 5, whereby the radicals R can be different if n is not equal to 1; R represents C1-C4 alkyl, C3-C6 alkenyl or C3-C6 alkynyl, whereby these groups can be partially or completely halogenated; Q represents C(=CHOCH3)-COOCH3, C(=CHCH3)-COOCH3, C(=NOCH3)-COOCH3 or C(=NOCH3)-CONHCH3. The invention also relates to the salts of the bisoximether derivatives, to methods and intermediate products for the production of these compounds and to their use for combating animal pests and fungicidal pests.
Abstract:
The invention relates to the use of substituted 5-hydroxypyrazoles of formula (I) in which the substituents have the following meanings: B represents aryl or heteroaryl; A represents C=O, C=S or SO2; R represents alkyl, alkyl halide, alkenyl, alkenyl halide, alkynyl or alkynyl halide, cycloalkyl, C3-C10-cycloalkenyl, cycloalkynyl, or aryl, heterocyclyl or heteroaryl; R represents hydrogen; R represents hydrogen, nitro, cyano, N(R')2, alkyl, alkyl halide, alkoxy, alkoxy halide, alkenyl, alkenyl halide, alkynyl or alkynyl halide, whereby R', independent of one another, represents hydrogen or alkyl; or R and R , together, represent a group =O, =S or =N-O-R , whereby R represents hydrogen, alkyl, alkyl halide, alkenyl, alkenyl halide, alkynyl or alkynyl halide; R represents hydrogen, halogen, nitro, cyano N(R')2, alkyl, alkyl halide, COOR', heteroaryl or heterocyclyl. The invention also relates to the use of said compounds for combating harmful fungi, to agents containing the compounds, to novel 5-hydroxypyrazoles and to methods for the production thereof.
Abstract translation:本发明涉及式(I)的5-羟基吡唑啉的用途,其中取代基具有以下含义:B芳基或杂芳基; A C = O,C = S或SO 2; R 1是烷基,卤代烷基,烯基,卤代烯基,炔基或卤代炔基,环烷基,C 3 -C 10 - 环烯基,环炔基或芳基,杂环基或杂芳基; R 2氢; [R <3>为氢,硝基,氰基,N(R ')2,烷基,卤代烷基,烷氧基,卤代烷氧基,链烯基,卤代烯基,炔基或卤代炔基,其中R' 独立地为氢或烷基; 或R <2>和R <3>一起表示基团= O,= S或= N-O-R <5>,其中R <5>是氢,烷基,卤代烷基,链烯基,卤代烯基,炔基或卤代炔基; R 4是氢,卤素,硝基,氰基,N(R')2,烷基,卤代烷基,COOR',杂芳基或杂环基; 用于控制有害真菌,含有它们的试剂和新的5-羟基吡唑及其制备方法。
Abstract:
The present invention relates to compounds of the general formula (I) and to the salts thereof, wherein the substituents and the n index have the following values: Q represents -C(=CHCH3)-COOCH3, -C(=CHOCH3)-COOCH3, -C(=NOCH3)-COOCH3 or -C(=NOCH3)-CONH(CH3); R represents hydrogen, halogen, C1-C4 alkyl, C1-C2 halogenalkyl, C1-C4 alkoxy or C1-C2 halogenalkoxy; R represents halogen, C1-C4 alkyl, C1-C2 halogenalkyl or C1-C4 alkoxy; n is 0, 1 or 2, wherein the R substituents can be different when n = 2; and R represents phenyl, pyridyle or pyrimidyle. This invention also relates to agents containing these compounds as well as to the use of said compounds (I) and agents against noxious fungi and animal parasites.
Abstract translation:通式(I)和它们的盐,其中取代基和指数n具有以下含义的化合物:Q是-C(= CHCH 3)-COOCH 3,-C(= CHOCH 3)-COOCH 3,C(= NOCH 3) - COOCH 3或-C(= NOCH 3)-CONH(CH 3); R 1是氢,卤素,C 1 -C 4烷基,C 1 -C 2卤代烷基,C 1 -C 4烷氧基或C 1 -C 2卤代烷氧基; R 2是卤素,C 1 -C 4烷基,C 1 -C 2卤代烷基,C 1 -C 4烷氧基; n是0,1或2,其中当n = 2时取代基R 2可以不同; R 3苯基,吡啶基或嘧啶基,含有它们的试剂以及化合物(I)和防治有害真菌和动物害虫的试剂的用途。
Abstract:
Phenyl acetic acid derivatives of formula (I) in which the substituents and index have the following meanings: X is oxygen or sulphur; R is hydrogen and alkyl; R is hydrogen and alkyl; R is cyano, nitro, trifluoromethyl, halogen, alkyl and alkoxy; m is 0, 1 ou 2, in which the radicals R may be different if m is 2; R is hydrogen, cyano, nitro, hydroxy, amino, halogen, alkyl, halogen alkyl, alkoxy, halogen alkoxy, alkylthio, alkylamino or dialkylamino; R is hydrogen, cyano, nitro, hydroxy, amino, halogen, possibly substituted alkyl, alkoxy, alkylthio, alkylamino, dialkylamino, alkenyl, alkenyloxy, alkenylthio, alkenylamino, N-alkenyl-N-alkylamino, alkinyl, alkinyloxy, alkinylthio, alkinylamino, N-alkinyl-N-alkylamino; optionally substituted cycloalkyl, cycloalkyloxy, cycloalkylthio, cycloalkylamino, N-cycloalkyl-N-alkylamino, cycloalkenyl, cycloalkenyloxy, cycloalkenylthio, cycloalkenylamino, N-cycloalkenyl-N-alkylamino, heterocyclyl, heterocyclyloxy, heterocyclylthio, heterocyclylamino, N-heterocylcyl-N-alkylamino, aryl, aryloxy, arylthio, arylamino, n-aryl-n-alkylamino, hetaryl, hetaryloxy, hetarylthio, hetarylamino, N-hetaryl-N-alkylamino; R is hydrogen, optionally substituted alkyl, cycloalkyl, alkenyl, alkinyl, alkylcarbonyl, alkenylcarbonyl, alkinylcarbonyl or alkylsulfonyl; optionally substituted aryl, arylcarbonyl, arylsulfonyl, hetaryl, hetarylcarbonyl or hetarylsulphonyl; and their salts, process and intermediate products for their production, and their use.
Abstract:
The invention relates to substituted phenyl carbamates of formula (I), wherein E represents a group A or B, # characterises the bond with the phenyl ring, and R , R , Y, n, T, and Z have the meanings given in the description.