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公开(公告)号:DE4131028A1
公开(公告)日:1993-03-25
申请号:DE4131028
申请日:1991-09-18
Applicant: BASF AG
Inventor: HURLEY JAMES DR , GOETZ WALTER DR , DORST HANS GEORG DR
IPC: C08L77/00
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公开(公告)号:DE4039420A1
公开(公告)日:1992-06-11
申请号:DE4039420
申请日:1990-12-08
Applicant: BASF AG
Inventor: GOETZ WALTER DR , BETZ WALTER DR , PIPPER GUNTER
Abstract: Thermoplastic molding compositions are obtainable by mixing A) from 0.5 to 5% by weight of a thermoplastic polyester elastomer and B) from 0 to 50% by weight of fibrous or particulate fillers or mixtures thereof into a melt of C) from 40 to 99.5% by weight of a polyamide prepolymer having a viscosity number of from 40 to 80 ml/g and subsequent postcondensation in solid phase.
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公开(公告)号:DE4031724A1
公开(公告)日:1992-04-09
申请号:DE4031724
申请日:1990-10-06
Applicant: BASF AG
Inventor: BLINNE GERD DR , GOETZ WALTER DR , HURLEY JAMES DR , GUTSCHE HERBERT
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公开(公告)号:DE3868838D1
公开(公告)日:1992-04-09
申请号:DE3868838
申请日:1988-10-14
Applicant: BASF AG
Inventor: PLACHETTA CHRISTOPH DR , GOETZ WALTER DR , BLINNE GERD DR
IPC: C08L77/00
Abstract: Thermoplastic moulding compsn.is based on (A) 10-89 (wt.)% copolyamide of (A1) 80-99% recurring units derived from adipic acid and hexamethylene diamine and (A2) 1-20% units derived from epsilon-caprolactam, (B) 10-89% polyhexamethyleneadipamide, (C) 1-40% rubber to modify the impact strength and (D) 0-60% fibrous and/or particulate filler(s). (A) consists of 85-96% (A1) and 4-15% (A2) units.
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公开(公告)号:DE59407873D1
公开(公告)日:1999-04-08
申请号:DE59407873
申请日:1994-11-12
Applicant: BASF AG
Inventor: GOETZ WALTER DR , GOTTSCHALK AXEL DR
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公开(公告)号:DE59504475D1
公开(公告)日:1999-01-21
申请号:DE59504475
申请日:1995-08-17
Applicant: BASF AG
Inventor: GOETZ WALTER DR
Abstract: The prodn. of high-mol. wt. polyamides from nitriles comprises (a) polymerisation of amino-nitriles of formula H2N(CH2)mCN (I) or mixts. of diamines (II) with dinitriles (III) in a mole ratio of (0.98:1)-(1.02:1) to give a prepolymer (A) with a rel. viscosity (1% in conc. H2SO4 at 23 deg.C) of 1.4-2.0: H2N-(CH2)m-CN (I) H2N-(CH2)n-NH2 (II) NC-(CH2)q-CN (III) m, n, p = 2-12; followed by (b) granulation and (c) solid-phase post-condensation at 5-100 deg.C below the m.pt. of the prepolymer in presence of an inert gas contg. at least 50 vol.% superheated steam, to give a high-mol. wt. polyamide (B) with a rel. viscosity of 2.3-5.0, the difference between the rel. viscosities of (A) and (B) being at least 0.4. Also claimed are (i) high-mol. wt. polyamides (B) as obtd. by this process; (ii) mouldings, film and fibres produced from these polyamides.
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公开(公告)号:AT174360T
公开(公告)日:1998-12-15
申请号:AT95112920
申请日:1995-08-17
Applicant: BASF AG
Inventor: GOETZ WALTER DR
Abstract: The prodn. of high-mol. wt. polyamides from nitriles comprises (a) polymerisation of amino-nitriles of formula H2N(CH2)mCN (I) or mixts. of diamines (II) with dinitriles (III) in a mole ratio of (0.98:1)-(1.02:1) to give a prepolymer (A) with a rel. viscosity (1% in conc. H2SO4 at 23 deg.C) of 1.4-2.0: H2N-(CH2)m-CN (I) H2N-(CH2)n-NH2 (II) NC-(CH2)q-CN (III) m, n, p = 2-12; followed by (b) granulation and (c) solid-phase post-condensation at 5-100 deg.C below the m.pt. of the prepolymer in presence of an inert gas contg. at least 50 vol.% superheated steam, to give a high-mol. wt. polyamide (B) with a rel. viscosity of 2.3-5.0, the difference between the rel. viscosities of (A) and (B) being at least 0.4. Also claimed are (i) high-mol. wt. polyamides (B) as obtd. by this process; (ii) mouldings, film and fibres produced from these polyamides.
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公开(公告)号:DE59306949D1
公开(公告)日:1997-08-28
申请号:DE59306949
申请日:1993-01-08
Applicant: BASF AG
Inventor: PIPPER GUNTER , GOETZ WALTER DR , CORDES CLAUS DR , FLOSS JOSEF GEORG DR , MATTERN GUENTER , HILDENBRAND PETER DR , HURLEY JAMES DR , SCHLICHTING KARL DR , MCKEE GRAHAM EDMUND DR , BLINNE GERD DR
Abstract: A process for the preparation of filler-containing thermoplastic moulding compositions by mixing fillers with thermoplastics in the melt, where a) the fillers are mixed in a mixing device in the melt with a low-molecular-weight thermoplastic having a maximum melt viscosity of 30 Pas (measured at a temperature of 20 DEG C above the melting point of the thermoplastic and at a shear gradient of 1 000 s ), b) the resultant product is discharged from the mixing device, cooled and comminuted, and c) the comminuted product in the solid phase is subsequently subjected to post-condensation.
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公开(公告)号:AT140712T
公开(公告)日:1996-08-15
申请号:AT92105178
申请日:1992-03-26
Applicant: BASF AG
Inventor: GOETZ WALTER DR , KOPIETZ MICHAEL DR , BLINNE GERD DR
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公开(公告)号:DE59301225D1
公开(公告)日:1996-02-08
申请号:DE59301225
申请日:1993-02-03
Applicant: BASF AG
Inventor: GOETZ WALTER DR , WEISS HANS-PETER DR
Abstract: The invention relates to a process for producing moulded articles by curing prepregs consisting of fibre-reinforced catalysed resins by the autoclave process, the prepreg laminates being covered with a film of polyamide 66 with a caprolactam content of between 3 and 30% by weight.
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