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公开(公告)号：DE2942185A1
公开(公告)日：1981-04-30
申请号：DE2942185
申请日：1979-10-18
Applicant: BASF AG
Abstract: Compounds of the general formula I A-B-A (I) where A is a radical of the formula and B is a bridge member of the formula and where R1 and R2 independently of one another are unsubstituted or hydroxy-, C1-C4-alkoxy-, cyano-, C1-C4-alkoxycarbonyl-, di-C1-C4-alkylamino-, chlorine- or bromine-substituted C1-C4-alkyl, cyclohexyl, benzyl, phenylethyl or phenyl, or R1 and R2 together with the nitrogen are morpholino, pyrrolidino, piperidino or N-methylpiperazino, R3 is hydrogen, chlorine, bromine, methyl, ethyl, methoxy, ethoxy or nitro, R4 and R5 independently of one another are hydrogen, C1-C4-alkyl or benzyl, X is oxygen or imino and alkylene is of 2 to 6 carbon atoms and is linear or branched. The compounds of the formula I are particularly suitable for coloring paper pulps.
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公开(公告)号：DE2735287A1
公开(公告)日：1979-03-15
申请号：DE2735287
申请日：1977-08-05
Applicant: BASF AG
Inventor： BAUMANN HANS DIPL CHEM DR , GRYCHTOL KLAUS DIPL CHEM DR
Abstract: The dyes have formula (I) in the free acid form in which A is the residue of an aliphatic or carbocyclic amine component, D is the residue of a diazo component, Z is an aliphatic carbocyclic or heterocyclic gp. X is -O- or -COO-, B is X or > N-L, E is -O- or > N-L, L is H or opt. substd. (cyclo)alkyl, aralkyl or aryl gp. R1 is H, Cl, Br, alkyl, alkoxy, nitro, acylamino, carboxy or opt. N-substd carbamoyl or sulphamoyl gp. and R2 is H, Cl, Br alkyl or nitro or R1 and R2 together form a condensed benzene ring. The dyes (I) have good solubility properties and can be obtd. in the form of stable conc. solns. which can be used directly for the prodn. of dye baths and printing pastes. The dyes are esp. useful for dyeing natural and synthetic N-contg. materials such as wool, leather, polyamide and polyurethane fibres. The dyes have good fastness to light, sweat, moisture and washing. Due to the large number of anionic charges they carry, they have good migration properties and give level dyeings. Due to the good solubility properties, they are esp. useful in continuous dyeing processes, e.g. in carpet dyeing.
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公开(公告)号：DE2826981A1
公开(公告)日：1980-01-17
申请号：DE2826981
申请日：1978-06-20
Applicant: BASF AG
Inventor： GRYCHTOL KLAUS DIPL CHEM DR
Abstract: Basic dyes of the general formula A-B-A I where the substituents A independently of one another are a radical of the formula and B is a bridge member, and in the formula for A R1 and R2 independently of one another are C1-C4-alkyl which is unsubstituted or substituted by hydroxyl, C1-C4-alkoxy, cyano, C1-C4-alkoxycarbonyl, di-C1-C4-alkylamino, benzyl-(C1-C4-alkyl)-amino, chlorine or bromine, or are cyclohexyl, benzyl, phenylethyl or phenyl, or R1 and R2 together with the nitrogen are pyrrolidino, piperidino, morpholino or N-methylpiperazino, R3 is hydrogen, chlorine, bromine, methyl, ethyl, methoxy, ethoxy or nitro, X is oxygen, imino or C1-C4-alkylimino and alkylene is of 2 to 6 carbon atoms and is straight or branched. The novel dyes are mainly used for dyeing paper pulps.
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公开(公告)号：DE2754403A1
公开(公告)日：1979-06-13
申请号：DE2754403
申请日：1977-12-07
Applicant: BASF AG
Inventor： DEGEN HANS-JUERGEN DIPL CHEM D , FEICHTMAYR FRANZ DIPL CHEM DR , GRYCHTOL KLAUS DIPL CHEM DR
Abstract: Methine dyes of the general formula where the groups A are identical or different aryl or hetaryl, A(-) is an anion, R is hydrogen, methyl or ethyl and X is a bridge member, and the methine groups are in the alpha - or gamma -position. The compounds are preferably used for dyeing paper.
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公开(公告)号：DE2739953A1
公开(公告)日：1979-03-22
申请号：DE2739953
申请日：1977-09-05
Applicant: BASF AG
Abstract: Compounds of the general formula I where B is a bridge member, the radicals R independently of one another are hydrogen or substituted or unsubstituted alkyl, or two radicals R together with the nitrogen are a heterocyclic saturated 5-membered or 6-membered ring, the radicals R1 independently of one another are hydrogen or C1-C4-alkyl, the radicals R2 independently of one another are hydrogen, C1-C4-alkyl or halogen, the radicals R3 independently of one another are hydrogen or substituted or unsubstituted alkyl or together are an alkylene group, and X(-) is an anion. The compounds of the formula I are particularly suitable for dyeing paper.
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Patent Agency Ranking
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公开(公告)号：DE2723155A1
公开(公告)日：1978-12-07
申请号：DE2723155
申请日：1977-05-23
Applicant: BASF AG
Inventor： BAUMANN HANS DIPL CHEM DR , GRYCHTOL KLAUS DIPL CHEM DR
Abstract: Chrome complex dyestuffs of formula (I) are new:- In (I) A is an aliphatic or carbocyclic amine residue D is a diazo; Z is an aliphatic; carbocyclic or heterocyclic gp.; X is an -O- or -CO2- gp; B is as X or >N-L; E is an -O- or >N-L where L is H or alkyl, cycloalkyl, aralkyl or aryl, opt. substd. R1 is H, Cl, Br, an alkyl or alkoxy gp., nitro, acylamino or carboxyl or a carbamoyl or sulphamoyl gp. opt. substd by N1, R2 is H, Cl, Br, an alkyl gp. nitro, and R1 and R2 being also able to form together a condensed phenyl gp. (I) are used for dyeing and printing natural or synthetic materials such as wool, leather, polyamide or polyurethanes. Dyeing with (I) have excellent fastness, partic. wet fastness in washing, gassing, and perspiration. (I) have good powers of migration giving regular, level dyeings despite the size of the molecule and the increased number of anionic charges. Because of their excellent solubility (I) are partic. suited to continuous dyeing e.g. of cloth.
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公开(公告)号：DE2643399A1
公开(公告)日：1978-03-30
申请号：DE2643399
申请日：1976-09-27
Applicant: BASF AG
Inventor： GRYCHTOL KLAUS DIPL CHEM DR
IPC: C09B29/08 , C09B31/043 , C09B44/04 , C09B39/00
Abstract: Basic monoazo dyes of formula: In the formula, D is a diazo gp.; R1 and R3 are H, cl, 1-2C alkyl or alkoxy; R2 is H, 1-4C alkyl opt. substd. with OH, 1-4C alkoxy, Cl, CN or 1-4C alkanoyloxy, cyclohexyl, benzyl or phenylethyl; R4 is a quaternisable N-contg. gp.). Used for dyeing or printing of anionic-modified fibres, e.g., polyamides, polyesters or esp. polyacrylonitrile in yellow to blue shades. Show good fastness to light and conditions in use, and outstanding colour strength.
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公开(公告)号：DE3205647A1
公开(公告)日：1983-08-25
申请号：DE3205647
申请日：1982-02-17
Applicant: BASF AG
IPC: C09B23/10 , C09B23/14 , D21H21/28 , C07D401/12 , C07D401/14 , D21H1/46 , D21H3/80
Abstract: Methine dyes in which A is identical or different aryl or hetaryl radicals, A is an anion, B is an alkylene radical, R is hydrogen, alkyl, aralkyl or acyl, T is the radical of a quaternised heterocycle and B is a bridge member of the formula where n is 0, 1, 2, 3 or 4, p is 0 or 1, B is a bridge member, Y and Y independently of one another are hydrogen or optionally substituted alkyl, cycloalkyl or aryl and Y is hydrogen or optionally substituted alkyl or benzyl and in which B and R have the given meaning. The compounds according to the invention are very suitable for the dyeing of paper pulps.
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公开(公告)号：DE3136259A1
公开(公告)日：1983-03-24
申请号：DE3136259
申请日：1981-09-12
Applicant: BASF AG
Abstract: The invention relates to compounds of the general formula I where the A radicals are identical or different aryl or hetaryl radicals, A is an anion, B is a bridge member, B is an alkylene radical, R is hydrogen, alkyl, aralkyl or acyl, and T is the radical of a quaternised heterocycle. The compounds of the invention are very highly suitable for dyeing/colouring paper stock.
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