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公开(公告)号:DE2825517A1
公开(公告)日:1979-12-20
申请号:DE2825517
申请日:1978-06-10
Applicant: BASF AG
Inventor: BAUMANN HANS DIPL CHEM DR
IPC: C09B45/20
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公开(公告)号:DE2723155A1
公开(公告)日:1978-12-07
申请号:DE2723155
申请日:1977-05-23
Applicant: BASF AG
Inventor: BAUMANN HANS DIPL CHEM DR , GRYCHTOL KLAUS DIPL CHEM DR
Abstract: Chrome complex dyestuffs of formula (I) are new:- In (I) A is an aliphatic or carbocyclic amine residue D is a diazo; Z is an aliphatic; carbocyclic or heterocyclic gp.; X is an -O- or -CO2- gp; B is as X or >N-L; E is an -O- or >N-L where L is H or alkyl, cycloalkyl, aralkyl or aryl, opt. substd. R1 is H, Cl, Br, an alkyl or alkoxy gp., nitro, acylamino or carboxyl or a carbamoyl or sulphamoyl gp. opt. substd by N1, R2 is H, Cl, Br, an alkyl gp. nitro, and R1 and R2 being also able to form together a condensed phenyl gp. (I) are used for dyeing and printing natural or synthetic materials such as wool, leather, polyamide or polyurethanes. Dyeing with (I) have excellent fastness, partic. wet fastness in washing, gassing, and perspiration. (I) have good powers of migration giving regular, level dyeings despite the size of the molecule and the increased number of anionic charges. Because of their excellent solubility (I) are partic. suited to continuous dyeing e.g. of cloth.
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公开(公告)号:DE3034002A1
公开(公告)日:1982-04-22
申请号:DE3034002
申请日:1980-09-10
Applicant: BASF AG
Inventor: BAUMANN HANS DIPL CHEM DR , GRYCHTOL KLAUS DIPL CHEM DR
Abstract: 1:2 Chromium complexes of arylazo-azamethines of the general formula where A is a naphthalene or benzene radical which may be monosubstituted or polysubstituted by alkyl, alkoxy or halogen.
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公开(公告)号:DE2363458A1
公开(公告)日:1975-07-03
申请号:DE2363458
申请日:1973-12-20
Applicant: BASF AG
IPC: C07B61/00 , C07C47/52 , C07C67/00 , C07C223/06 , C07C229/66 , C07C253/00 , C07C255/58 , C09B11/14 , C09B26/02 , C09B57/00 , C07C131/00 , C07C119/06 , C07C109/12
Abstract: Aminobenzaldehyde compounds and a process for their production by the reaction of an aniline with a formamide in the presence of an acid halide with or without a following reaction with a nitrogen compound. The products are starting materials for the production of optical brighteners, dyes, plant protection agents and medicaments.
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公开(公告)号:DE2323803A1
公开(公告)日:1974-12-05
申请号:DE2323803
申请日:1973-05-11
Applicant: BASF AG
Abstract: Spirodipyrans based on condensed pyrylium salts and 4-dialkylamino-2-hydroxybenzaldehydes, their manufacture and their use as chromogenic materials in pressure-sensitive recording materials, particularly copying papers.
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公开(公告)号:DE2735287A1
公开(公告)日:1979-03-15
申请号:DE2735287
申请日:1977-08-05
Applicant: BASF AG
Inventor: BAUMANN HANS DIPL CHEM DR , GRYCHTOL KLAUS DIPL CHEM DR
Abstract: The dyes have formula (I) in the free acid form in which A is the residue of an aliphatic or carbocyclic amine component, D is the residue of a diazo component, Z is an aliphatic carbocyclic or heterocyclic gp. X is -O- or -COO-, B is X or > N-L, E is -O- or > N-L, L is H or opt. substd. (cyclo)alkyl, aralkyl or aryl gp. R1 is H, Cl, Br, alkyl, alkoxy, nitro, acylamino, carboxy or opt. N-substd carbamoyl or sulphamoyl gp. and R2 is H, Cl, Br alkyl or nitro or R1 and R2 together form a condensed benzene ring. The dyes (I) have good solubility properties and can be obtd. in the form of stable conc. solns. which can be used directly for the prodn. of dye baths and printing pastes. The dyes are esp. useful for dyeing natural and synthetic N-contg. materials such as wool, leather, polyamide and polyurethane fibres. The dyes have good fastness to light, sweat, moisture and washing. Due to the large number of anionic charges they carry, they have good migration properties and give level dyeings. Due to the good solubility properties, they are esp. useful in continuous dyeing processes, e.g. in carpet dyeing.
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公开(公告)号:CH605966A5
公开(公告)日:1978-10-13
申请号:CH628174
申请日:1974-05-08
Applicant: BASF AG
IPC: B41M5/136 , B41M5/15 , C07D493/10 , C09B57/00 , B41M5/12
Abstract: Spirodipyrans based on condensed pyrylium salts and 4-dialkylamino-2-hydroxybenzaldehydes, their manufacture and their use as chromogenic materials in pressure-sensitive recording materials, particularly copying papers.
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公开(公告)号:DE2703811A1
公开(公告)日:1978-08-10
申请号:DE2703811
申请日:1977-01-29
Applicant: BASF AG
IPC: B41M5/136 , B41M5/15 , C07D493/10 , C09B57/00 , B41M5/12
Abstract: A pressure-sensitive recording material which comprises a substrate bearing a dye-forming component and a binder. The dye-forming component is a spirodipyran of the formula where A is the radical of a fused benzene or naphthalene ring (which rings may or may not be substituted), R1 is alkyl of 1 to 16 carbon atoms, substituted or unsubstituted phenyl or phenalkyl of 7 to 10 carbon atoms, R2 is H or together with R1 is a trimethylene or tetramethylene bridge which is unsubstituted or substituted by from 1 to 3 alkyl, R3 is benzyl or beta -phenylethyl and R4 is benzyl, beta -phenylethyl or substituted or unsubstituted phenyl, or R3 is alkyl of 1 to 4 carbon atoms and R4 is substituted or unsubstituted phenyl or R3 is benzyl and R4 is beta -cyanoethyl. The recording materials give violet to bluish green colorations (copies) only on paper coated with an electron acceptor.
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公开(公告)号:DE2850131A1
公开(公告)日:1980-06-04
申请号:DE2850131
申请日:1978-11-18
Applicant: BASF AG
Inventor: BAUMANN HANS DIPL CHEM DR , KAACK HERMANN DIPL CHEM DR
Abstract: New reactive dyes are of formula (I). In (I) A is F, Cl or Br; B is H, Cl, methyl, methoxy, ethoxy, hydroxysulphonyl or COOH; is H, methyl, phenyl, COOH, 1-4C alkoxy-carbonyl, carbamoyl, N-alkyl or N-N-dialkyl or hydroxyalkyl carbamoyl, carbo-piperidide, carbopyrrolidide or carbomorpholide; R' is phenyl substd. with ethyl, F, Br, CN, CF3, methoxy, ethoxy, phenoxy, acetyl, benzoyl, methyl- or phenyl-sulphonyl, acetylamino or carbamoyl. Used for dyeing or printing of wool, silk, synthetic polyamide or esp. cellulose fibres, in greenish-yellow to yellow shades. They provide high strength and very good fastness.
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