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公开(公告)号:DE2230225A1
公开(公告)日:1974-01-10
申请号:DE2230225
申请日:1972-06-21
Applicant: BASF AG
Inventor: OBERLINNER ANDREAS DR , BAUMANN HANS DR , GRYCHTOL KLAUS DR
IPC: B41M5/136 , B41M5/15 , C07D491/10 , C07D491/107 , C09B57/00 , C07D51/78
Abstract: 1424886 Spiropyrans for copying processes BADISCHE ANILIN- & SODA-FABRIK AG 20 June 1973 [21 June 1972] 29228/73 Heading C4P [Also in Division D2] Spiropyrans have the formula in which R 1 is H, alkyl, cyanoalkyl, carboxyalkyl, methoxyalkyl or cycloalkyl each of 1 - 6C, and phenyl, R 2 is alkyl of 1 - 4C, A is a benzene nucleus opt. subs. by Me, Cl, Br, or alkoxy of from 1 - 4C, and B is a benzene or naphthalene nucleus opt. substd. by Cl, Br, nitro, C 1-5 alkyl, C 1-5 , alkoxy, di-(C 1-5 )-alkylamino or C 1-5 -alkoxy-substituted carbonyl. Some ten compounds are described. They are prepared by condensing the heterocyclic bases with o-hydroxybenzaldehydes or o-hydroxynaphthaldehydes in a cyclization reaction. The spiropyrans formed may be dissolved in non-polar or weakly polar solvents, and give intense red to blue colorations when acid substances, including kaolin and similar materials. The spiropyrans may be used as dye-forming components, possibly encapsulated, for pressure-sensitive recording materials, particularly copying papers.
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公开(公告)号:DE3433951A1
公开(公告)日:1986-03-27
申请号:DE3433951
申请日:1984-09-15
Applicant: BASF AG
Inventor: GRYCHTOL KLAUS DR
Abstract: Compounds of the formula I I where K(+) is a cation, R is methyl or is phenyl which is unsubstituted or substituted by chlorine, bromine, methyl, methoxy or ethoxy, R1 is hydrogen, chlorine, bromine or nitro, R2 is hydrogen, chlorine, bromine, nitro, sulfamyl or hydroxysulfonyl, X and Y are each -O- or -COO-, Z is -O- or -NH-, D is a radical of a diazo component of the aniline or naphthylamine series and K is a radical of a coupling component, are very useful for dyeing natural and synthetic polyamide textile fibers and leather.
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公开(公告)号:DE3168387D1
公开(公告)日:1985-02-28
申请号:DE3168387
申请日:1981-10-24
Applicant: BASF AG
Inventor: GRYCHTOL KLAUS DR , LACH DIETRICH DR
Abstract: Mixtures of two or more cobalt 1:2 complexes of azo dyes of the formula I I where R is where R1 is hydrogen, C1-C18-alkyl, or hydroxyalkyl or alkoxyalkyl which may be interrupted by oxygen, and X and Y are hydrogen, fluorine, chlorine, bromine, C1-C4-alkyl or C1-C4-alkoxy. The mixtures according to the invention are particularly useful for dyeing leather.
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公开(公告)号:DE3161735D1
公开(公告)日:1984-02-02
申请号:DE3161735
申请日:1981-03-11
Applicant: BASF AG
Inventor: BAUMANN HANS DR , GRYCHTOL KLAUS DR
Abstract: Compounds which in the form of the free acids correspond to the formula where A is a radical of a diazo component or of an amine, B is a radical of a coupling component or of an aldehyde, R1 is chlorine or bromine, R2 is methoxy or ethoxy, X is =N- or =CH-, Y is -O- or -COO- and Z is -O- or -NH-, are dyes which are very suitable for dyeing nylons and natural polyamides.
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公开(公告)号:CH637676A5
公开(公告)日:1983-08-15
申请号:CH824278
申请日:1978-08-02
Applicant: BASF AG
Inventor: GRYCHTOL KLAUS DR , BAUMANN HANS DR
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公开(公告)号:DE3063378D1
公开(公告)日:1983-07-07
申请号:DE3063378
申请日:1980-12-09
Applicant: BASF AG
Inventor: BRUDER HORST DR , DEGEN HANS-JUERGEN DR , FEICHTMAYR FRANZ DR , GRYCHTOL KLAUS DR , MAYER UDO DR
Abstract: Compounds of the general formula I where the radicals A, A1 and B are identical or different and A is unsubstituted or substituted benzene or heteroaromatic, A1, if n=1, is unsubstituted or substituted heteroaromatic or is aryl which is unsubstituted or substituted by alkyl, aryl, cycloalkyl, chlorine, bromine, hydroxyl, alkoxy, aryloxy, nitro, hydroxycarbonyl, alkoxycarbonyl, or aminocarbonyl, and, if n>1, A1 may also be aryl substituted by unsubstituted or substituted amino, B is a bridge member of the formula B1 is a bridge member which may or may not be quaternized, R1 and R2 are hydrogen, unsubstituted or substituted alkyl, cycloalkyl, aryl, alkoxy or amino, n is an integer equal to or greater than 1 and X theta is an anion. The compounds according to the invention are preferably used for coloring paper pulp.
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公开(公告)号:DE2244371A1
公开(公告)日:1974-04-04
申请号:DE2244371
申请日:1972-09-09
Applicant: BASF AG
Inventor: GRYCHTOL KLAUS DR
IPC: C07D307/85 , C09B57/00 , C07D49/36 , C07D5/40
Abstract: A benzofuran compound of the formula WHERE X denotes HSO4 , CH3SO4 , Cl , Br , 1/2 2ZnCl 4 or CH3COO . The said compounds are dyes for synthetic textile material.
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公开(公告)号:DE4227743A1
公开(公告)日:1994-02-24
申请号:DE4227743
申请日:1992-08-21
Applicant: BASF AG
Abstract: Electrostatic toner containing a polymeric binder and, as the charge stabiliser, a 1:2 chromium, iron, cobalt or zirconium complex of azo colorants of the formula: D-N=N-K, where D is derived from a diazo component D-NH2, which arises from the group consisting of 2-amino-4-nitrophenol, anthranilic acid and picramic acid, and K is derived from coupling components K-H which arise from the group consisting of beta -naphthol, diacetic acid anilide and 1-phenyl-3-methyl pyrazol-5-one, and the use of the aforementioned metal complexes as charge stabilisers in electrostatic toners.
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