17.
    发明专利
    未知

    公开(公告)号:DE2702371A1

    公开(公告)日:1978-08-03

    申请号:DE2702371

    申请日:1977-01-21

    Applicant: BASF AG

    Abstract: Uniformly dyed water-swellable cellulosic fibers obtained by dyeing cellulosic fibers, in the swollen state, with a dye of the formula where X is hydrogen, chlorine, bromine, cyano, nitro, alkylsulfonyl of 1 to 4 carbon atoms, phenylsulfonyl, methoxy or ethoxy, Y is hydrogen, chlorine, bromine, cyano or nitro, Z is a radical of the formula Q is oxygen or sulfur, R1 is alkyl of 1 to 4 carbon atoms, methoxymethyl, phenoxymethyl or phenyl which is unsubstituted or substituted by chlorine, bromine, nitro, methyl, methoxy or ethoxy, R2 is hydrogen, methyl, ethyl, phenyl or phenyl substituted by chlorine, bromine or methyl, R3 is hydrogen, methyl or, if R2 is methyl, is C1 to C4 alkoxycarbonyl, R2 and R3 together with the linking carbon atoms are phenylene or phenylene substituted by chlorine, methyl, methoxy or ethoxy and K is a radical of a coupling component selected from the pyrazolone, pyrazole, indole, quinolone or homophthalimide series.

    Green-black trisazo dyes for leather, cellulosics, etc. - contg. amino-hydroxynaphthalene-sulphonic acid gps

    公开(公告)号:DE2416670A1

    公开(公告)日:1975-10-23

    申请号:DE2416670

    申请日:1974-04-05

    Applicant: BASF AG

    Abstract: The tris-azo dyes of formula (I) in the free acid from: (where A is the radical of an aromatic diazotisable component; B is the radical of an aromatic hydroxylated and/or aminated coupling component; n = 1 or 2; one X is OH and the other is NH2; Z is a radical of formula (II): in which Y is -SO2-NR; R is H, opt. substd.alkyl, or benzyl; R1 is H, Cl, Br, 1-4C alkyl, CN, COOH, MeO, EtO or NO2; R2 is H, Cl or 1-4C alkyl; R3 is H, Cl, Br, 1-4C alkyl, CN, MeO, EtOH, OH, COOH, NO2 or sulpho; R4 is H, Cl or Br; the azo gps. linked to Z are not in posn. 4:41 when both benzene rings are unsubstd. or monosubstd.), are used as green-black dyes for leather and also for natural or synthetic fibres contg. OH gps. e.g., cellulose, cotton, regenerated cellulose, wool, silk, nylon, and paper.

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