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11.
公开(公告)号:DE3461367D1
公开(公告)日:1987-01-08
申请号:DE3461367
申请日:1984-05-18
Applicant: BASF AG
Inventor: LINDNER ALFRED DR , BROELLOS KLAUS DR , SANDROCK GERHARD DR , VOLKAMER KLAUS DR , HEFNER WERNER DR
Abstract: A C4-hydrocarbon mixture which essentially contains n-butenes and butanes is separated by a process in which the mixture is reacted with a carboxylic acid in the presence of an acidic catalyst to form a butyl carboxylate, the reaction mixture obtained from the esterification zone is distilled to give, as the top product, a fraction containing the butanes, and, as the bottom product, a fraction containing the resulting butyl carboxylate, the butyl carboxylate is decomposed at elevated temperatures to give the carboxylic acid and n-butenes, and the mixture of n-butenes and carboxylic acid is then distilled, the n-butenes being obtained as the top product, and the carboxylic acid as the bottom product.
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12.
公开(公告)号:AT23706T
公开(公告)日:1986-12-15
申请号:AT84105654
申请日:1984-05-18
Applicant: BASF AG
Inventor: LINDNER ALFRED DR , BROELLOS KLAUS DR , SANDROCK GERHARD DR , VOLKAMER KLAUS DR , HEFNER WERNER DR
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公开(公告)号:DE3427134A1
公开(公告)日:1986-02-06
申请号:DE3427134
申请日:1984-07-24
Applicant: BASF AG
Inventor: VOLKAMER KLAUS DR , HEFNER WERNER DR , WAGNER ECKHART DR , WAGNER ULRICH DR
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公开(公告)号:DE3408851A1
公开(公告)日:1985-09-12
申请号:DE3408851
申请日:1984-03-10
Applicant: BASF AG
Inventor: WAGNER ECKHART DR , VOLKAMER KLAUS DR , HEFNER WERNER DR , WAGNER ULRICH DR
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公开(公告)号:MY124617A
公开(公告)日:2006-06-30
申请号:MYPI9903809
申请日:1999-09-03
Applicant: BASF AG
Inventor: FLICK KLEMENS PROF DR , XDFNER RUPRECHT MEI , HEFNER WERNER DR , FESER RAINER DR , KUNZ FABIAN DR
IPC: B01J23/38 , C07C7/163 , B01J21/08 , B01J23/44 , B01J23/50 , B01J23/72 , B01J23/755 , B01J32/00 , B01J33/00 , B01J35/10 , C07B63/02 , C07C11/04 , C07C11/06 , C10G35/06 , C10G45/40 , C10G70/02
Abstract: A CATALYST COMPRISING,IN ITS ACTIVE COMPOSITION,FROM 0.05 TO 1.0 BY WEIGHT OF AT LEAST ONE METAL OR COMPOUND OF A METAL OF THE 10TH GROUP OF THE PERIODIC TABLE OF THE ELEMENTS AND FROM 0.05 TO 1.0BY WEIGHT OF AT LEAST ONE METAL OR COMPOUND OF A METAL OF THE 11TH GROUP OF THE PERIODIC TABLE OF THE ELEMENTS,WITH THE WEIGHT RATIO OF THE METAL OF THE 11TH GROUP TO THE METAL OF THE 10TH GROUP BEING FROM 0.95 TO 1.05,AND,AS SUPPORT, AN SIO2-CONTAINING CATALYST SUPPORT HAVING A BET SURFACE AREA OF FROM 2 TO 400 M²/G,WHEREIN AT LEAST 20OF THE TOTAL PORE VOLUME OF THE CATALYST IS AMDE UP BY PORES HAVING A DIAMTER GREATER THAN 100 NANOMETERS,CAN BE YSED IN PROCESSES FOR REMOVING ALKYNES,DIENES AND/OR MONOUNSATURATED HYDROCARBONS FROM STREAMS OF MATERIALS.
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公开(公告)号:DE59602040D1
公开(公告)日:1999-07-08
申请号:DE59602040
申请日:1996-03-01
Applicant: BASF AG
Inventor: HEFNER WERNER DR , MACHHAMMER OTTO DR , NEUMANN HANS-PETER DR , TENTEN ANDREAS DR , RUPPEL WILHELM DR , VOGEL HERBERT DR
Abstract: In continuous gas phase oxidn. of C3H6 to acrolein (I) and/or acrylic acid (II) with heterogeneous catalyst in an oxidn. reactor, the charge gas mixt. (III) contains only inert diluent gas(es) (IIIA) in addn. to C3H6 and O2 and (pt. of) (IIIA) is sepd. from the prodn. gas mixt. and recycled to the oxidn. reactor. The novelty is that (IIIA) consists of over 85 vol. % 1-5C satd. hydrocarbon(s).
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公开(公告)号:ES2116795T3
公开(公告)日:1998-07-16
申请号:ES96103128
申请日:1996-03-01
Applicant: BASF AG
Inventor: HEFNER WERNER DR , MACHHAMMER OTTO DR , NEUMANN HANS-PETER DR , TENTEN ANDREAS DR , RUPPEL WILHELM DR , VOGEL HERBERT DR
IPC: C07B35/04 , C07B41/06 , C07B41/08 , C07C27/00 , C07C45/32 , C07C45/35 , C07C47/22 , C07C51/235 , C07C51/25 , C07C51/265 , C07C57/05 , C07D301/08
Abstract: Continuous gas phase partial oxidn. of an organic cpd. (I) with heterogeneous catalyst in an oxidn. reactor uses a charge gas mixt. contg. (I) O2 and an inert diluent gas (II), which consists partly of combustible gases (IIA). The novelty is that the (IIA) fraction of (II) in the prod. gas stream leaving the oxidn. reactor is not recycled to partial oxidn. but used in another chemical reaction.
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公开(公告)号:DE19508532A1
公开(公告)日:1996-09-12
申请号:DE19508532
申请日:1995-03-10
Applicant: BASF AG
Inventor: HEFNER WERNER DR , MACHHAMMER OTTO DR , NEUMANN HANS-PETER DR , TENTEN ANDREAS DR , RUPPEL WILHELM DR , VOGEL HERBERT DR
Abstract: In continuous gas phase oxidn. of C3H6 to acrolein (I) and/or acrylic acid (II) with heterogeneous catalyst in an oxidn. reactor, the charge gas mixt. (III) contains only inert diluent gas(es) (IIIA) in addn. to C3H6 and O2 and (pt. of) (IIIA) is sepd. from the prodn. gas mixt. and recycled to the oxidn. reactor. The novelty is that (IIIA) consists of over 85 vol. % 1-5C satd. hydrocarbon(s).
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公开(公告)号:DE4029349A1
公开(公告)日:1992-03-19
申请号:DE4029349
申请日:1990-09-15
Applicant: BASF AG
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公开(公告)号:DE3578379D1
公开(公告)日:1990-08-02
申请号:DE3578379
申请日:1985-03-01
Applicant: BASF AG
Inventor: WAGNER ECKHART DR , VOLKAMER KLAUS DR , HEFNER WERNER DR , WAGNER ULRICH DR
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