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公开(公告)号:JPH1046381A
公开(公告)日:1998-02-17
申请号:JP13368897
申请日:1997-05-23
Applicant: BASF AG
Inventor: HUBER GUENTHER DIPL ING , WEIPER-IDELMANN ANDREAS DR , KRAMER ANDREAS DR , GOLOMBEK ROLF DR , FREDE MARKUS DR , SPISKE LUISE DR , SCHEHLMANN KARL-HEINZ , STEUER VOLKER
Abstract: PROBLEM TO BE SOLVED: To electrochemically reduce an org. compd. in a high space-time yield by bringing the org. compd. into contact with a conductive substrate and a cathode having a conductive polarized layer formed formed on the substrate by deposition. SOLUTION: Adiponitrile is reduced to hexamethylenediamine in a split electrolytic cell divided into a cathode compartment and an anode compartment with a cation-exchange membrane as a separation medium. In this case, a filter plate covered with the longitudinally diagonal woven fabric of steel alloy is used sa the cathode, a Ti plate coated with a Ta-Ir mixed oxide is used as the anode, and 2% sulfuric acid is employed as the anolyte, and the mixture of methanol, water, NaOH, adiponitrile and Raney nickel as the catholyte. Raney nickel is previously deposited on a cathode and then electrolytically reduced at 30-40 deg.C and 1000A/m current density. NaOH is removed by electrolysis, and the product is separated by distillation to recover hexamethylenediamine.
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公开(公告)号:DE4029349A1
公开(公告)日:1992-03-19
申请号:DE4029349
申请日:1990-09-15
Applicant: BASF AG
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公开(公告)号:DE59004325D1
公开(公告)日:1994-03-03
申请号:DE59004325
申请日:1990-11-02
Applicant: BASF AG
Inventor: SPISKE LUISE DR , LUETZOW DIETRICH DR , HERION CHRISTOF DR , KUESSNER KLAUS DR , HEFNER WERNER DR
IPC: B01D61/36 , C07C209/86 , C07C211/51 , C07C273/18 , C07C275/06
Abstract: Water is removed from a mixture containing water, CO2 and one or more amines by pervaporation by bringing the mixture into contact with one side of a membrane and removing the water-containing permeate as a vapor from the other side of the membrane.
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公开(公告)号:AT100436T
公开(公告)日:1994-02-15
申请号:AT90120996
申请日:1990-11-02
Applicant: BASF AG
Inventor: SPISKE LUISE DR , LUETZOW DIETRICH DR , HERION CHRISTOF DR , KUESSNER KLAUS DR , HEFNER WERNER DR
IPC: B01D61/36 , C07C209/86 , C07C211/51 , C07C273/18 , C07C275/06
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公开(公告)号:DE19620861A1
公开(公告)日:1997-11-27
申请号:DE19620861
申请日:1996-05-23
Applicant: BASF AG
Inventor: HUBER GUENTHER DIPL ING , WEIPER-IDELMANN ANDREAS DR , KRAMER ANDREAS DR , GOLOMBEK ROLF DR , FREDE MARKUS DR , SPISKE LUISE DR , SCHEHLMANN KARL-HEINZ , STEUER VOLKER
IPC: C25B3/25 , C25B11/00 , C25B3/04 , C25B11/04 , C07B31/00 , C07C233/09 , C07C211/12 , C07C255/24 , C07C33/22 , C07C35/08 , C07C231/10 , C07C209/48 , C07C253/30 , C07C29/132
Abstract: Electrochemically reducing an organic compound comprises: contacting the compound with a cathode comprising a support of electrically conducting material and an electrically conducting, cathodically polarised layer formed on this by sedimentation in situ.
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公开(公告)号:DE19533214A1
公开(公告)日:1997-03-13
申请号:DE19533214
申请日:1995-09-08
Applicant: BASF AG
Inventor: PUETTER HERMANN DR , HUBER GUENTHER , SPISKE LUISE DR , STARK HANS DR , SCHLAEFER DIETER DR , PFORR GERHARD DR
Abstract: Proposed is an electrolytic method for the production of sodium and aluminium chloride in an electrolytic cell with an aluminium anode and a sodium cathode separated from each other by a sodium-ion-conducting solid electrolyte. In the anode region, molten electrolyte containing essentially sodium tetrachloroaluminate is electrolysed, the aluminium chloride produced being evaporated out of the cell and the sodium produced being tapped off from the cathode region.
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公开(公告)号:ES2146438T3
公开(公告)日:2000-08-01
申请号:ES97108224
申请日:1997-05-21
Applicant: BASF AG
Inventor: HUBER GUNTHER , WEIPER-IDELMANN ANDREAS DR , KRAMER ANDREAS DR , GOLOMBEK ROLF DR , FREDE MARKUS DR , SPISKE LUISE DR
Abstract: Electrochemically reducing an organic compound comprises: contacting the compound with a cathode comprising a support of electrically conducting material and an electrically conducting, cathodically polarised layer formed on this by sedimentation in situ.
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公开(公告)号:DE59107021D1
公开(公告)日:1996-01-18
申请号:DE59107021
申请日:1991-08-27
Applicant: BASF AG
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公开(公告)号:ES2048389T3
公开(公告)日:1994-03-16
申请号:ES90120996
申请日:1990-11-02
Applicant: BASF AG
Inventor: SPISKE LUISE DR , LUETZOW DIETRICH DR , HERION CHRISTOF DR , KUESSNER KLAUS DR , HEFNER WERNER DR
IPC: B01D61/36 , C07C209/86 , C07C211/51 , C07C273/18 , C07C275/06
Abstract: Water is removed from a mixture containing water, CO2 and one or more amines by pervaporation by bringing the mixture into contact with one side of a membrane and removing the water-containing permeate as a vapor from the other side of the membrane.
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公开(公告)号:DE3937796A1
公开(公告)日:1991-05-16
申请号:DE3937796
申请日:1989-11-14
Applicant: BASF AG
Inventor: SPISKE LUISE DR , LUETZOW DIETRICH DR , HERION CHRISTOF DR , KUESSNER KLAUS DR , HEFNER WERNER DR
IPC: B01D61/36 , C07C209/86 , C07C211/51 , C07C273/18 , C07C275/06
Abstract: Water is removed from a mixture containing water, CO2 and one or more amines by pervaporation by bringing the mixture into contact with one side of a membrane and removing the water-containing permeate as a vapor from the other side of the membrane.
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