EMULSIONES ESTABLES AL ALMACENAMIENTO PARA LA OBTENCION DE ESPUMAS DURAS CON CELUILAS FINAS A BASE DE ISOCIANATO.

    公开(公告)号:ES2234061T3

    公开(公告)日:2005-06-16

    申请号:ES98117893

    申请日:1998-09-22

    Applicant: BASF AG

    Abstract: EMULSIONES QUE CONTIENEN ESPUMANTES, CONTENIENDO A) COMPUESTOS QUE CONTIENEN ATOMOS DE HIDROGENO QUE SON REACTIVOS CON RESPECTO A LOS ISOCIANATOS, B) ESPUMANTES, C) CATALIZADORES USUALES EN LA QUIMICA DEL POLIURETANO, ADYUVANTES Y/O ADITIVOS, CARACTERIZADOS PORQUE LOS ESPUMANTES B) SE PRESENTAN EN EMULSION EN LOS COMPONENTES A) Y C), Y COMO ADYUVANTE DE EMULSION SE UTILIZAN POLIESTERALCOHOLES CON LA SIGUIENTE ESTRUCTURA CON M DE 0 - 15 N DE 0 - 1 O DE 0 - 15 P DE 0 - 1 Q DE 0 - 15 R DE 0 - 1 S DE 0 - 15 T DE 0 - 1 U DE 0 - 10 V DE 0 - 15 X DE 1 - 5 Y DE 1 - 4 O MEZCLAS ENTRE 1 - 3 CON R + N /= 0 Z DE 0 - 3 Z SUB,J DE 0,1 - 3 R 1 ES UNA ESTRUCTURA ALIFATICA SIN GRUP OS OH QUE SE BASA EN LA ESTRUCTURA DE ALCOHOLES POLIVALENTES, PREFERIBLEMENTE ETILENGLICOL, DIETILENGLICOL, TRIETILENGLICOL, 1,2 PROPILENGLICOL Y DIPROPILENGLICOL, 1,4 - BUTANODIOL, 1,6 HEXANODIOL, NEOPENTILGLICOL, 1,3 - BUTANODIOL, TRIMETILOPROPANO, TRIMETILOLETANO, GLICERINA, PENTAERITRITA, PUDIENDO SER UTILIZADOS ESTOS COMPUESTOS EN UNA MEZCLA DE UNOS CON OTROS COMO SE QUIERA EN UNA ESTERIFICACION, Y R 1 PUEDE SIGNIFICAR POR TANTO LAS CORRESPONDIENTES ESTRUCTURAS. R 2 ES EL RADICAL DE UN ACIDO POLICARBOXILICO SIN GRUPOS COOH, P. E. ACIDO ADIPICO,, ACIDO TEREFTALICO, ACIDO O FTALICO, R 3 ES UN RADICAL ALCOHOLICO COMO R 1 .

    STORAGE-STABLE EMULSIONS FOR PRODUCING FINE-CELLED RIGID FOAMS BASED ON ISOCYANATE

    公开(公告)号:CA2245319A1

    公开(公告)日:1999-03-24

    申请号:CA2245319

    申请日:1998-09-23

    Applicant: BASF AG

    Abstract: Blowing agent-containing emulsions comprise a) compounds containing hydrogen atoms which are reactive toward isocyanates, b) blowing agents, c) catalysts, auxiliaries and/or additives which are customary in polyurethane chemistry, wherein the blowing agents b) are present as an emulsion in the components a) and c), and polyester alcohols having the following structure are used as emulsification aids: where m = 0 - 15 n = 0 - 1 o = 0 - 15 p = 0 - 1 q = 0 - 15 r = 0 - 1 s = 0 - 15 t = 0 - 1 u = 0 - 10 v = 0 - 15 x = 1 - 5 y = 1 - 4 or mixtures of 1-3 where r + n ~ 0 z = 0 - 3 Z i = 0.1 - 3 R1 is an aliphatic structure without OH groups, based on the structure of polyhydric alcohols, preferably ethylene glycol, diethylene glycol, triethylene glycol, 1,2-propylene glycol and dipropylene glycol, 1,4-butanediol, 1,6-hexanediol, neopentyl glycol, 1,3-butanediol, trimethylolpropane, trimethylol ethane, glycerol, pentaerythritol, where these substances can also be used as any mixture with one another in the esterification and R1 can therefore also be a mixture of the corresponding structures, R2 is the radical of a polycarboxylic acid without COOH groups, eg. adipic acid, terephthalic acid, o-phthalic acid, R3 is an alcohol radical like R1.

    20.
    发明专利
    未知

    公开(公告)号:AT290558T

    公开(公告)日:2005-03-15

    申请号:AT98117895

    申请日:1998-09-22

    Applicant: BASF AG

    Abstract: Emulsions containing polyether alcohols are used in the production of hard foams based on isocyanates to improve the temperature stability of the foams. Storage-stable halogen-free emulsions used in the production of hard foams based on isocyanates contain: (a) compounds containing hydrogen atoms reactive towards isocyanate groups; (b) water; (c) halogen-free propellants; and optionally (d) usual auxiliary aids and/or additives. (a) is used in an amount of 0.2-80 wt.% and has a functionality of more than 1.5, and an OH number of 10-100 mg KOH/g. (c) consists of 3-10 C hydrocarbons. Independent claims are also included for: (1) the production of the hard foams described; (2) the foams, and (3) the use of the polyether alcohols described.

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