METHOD FOR THE PRODUCTION OF 1-SUBSTITUTED 5-HYDROXYPYRAZOLES
    12.
    发明申请
    METHOD FOR THE PRODUCTION OF 1-SUBSTITUTED 5-HYDROXYPYRAZOLES 审中-公开
    用于生产1-取代-5-羟基吡

    公开(公告)号:WO0031041A3

    公开(公告)日:2000-11-09

    申请号:PCT/EP9908515

    申请日:1999-11-06

    CPC classification number: C07D231/20

    Abstract: The invention relates to a method for the production of 1-substituted 5-hydroxypyrazoles of formula (I) wherein R is C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkinyl, C3-C6-cycloalkyl or C1-C4-alkoxy, whereby these groups can be substituted by halogen, C1-C4-alkoxy, phenoxy, C1-C6-alkoxycarbonyl, C1-C6-alkylthiocarbonyl or a cyclic ring system with 3-14 ring atoms, by reacting a) an alkylvinylether of general formula (III) wherein R is C1-C6-alkyl or C3-C6-cycloalkyl, with phosgene (IVa), "diphosgene" (IVb) or "triphosgene" (IVc) to form acid chlorides of formula (V), b) transforming said acid chlorides by eliminating hydrogen chloride into the corresponding 3-alkoxyacrylic acid chloride of formula (VI) and c) reacting said acid chloride with hydrazines of formula (VII) wherein R has the above cited meaning, to form 5-hydroxypyrazoles of formula (I).

    Abstract translation: 本发明涉及一种制备1-取代的式(I)的5-羟基吡唑,其中R <1> C1-C6-烷基,C2-C6链烯基,C2-C6炔基,C3-C6环烷基,或 C1-C4烷氧基,其中这些基团被卤素,C1-C4烷氧基,苯氧基,C1-C6烷氧羰基,C1-C6烷硫基羰基或具有3-14个环原子的环系中,可以通过a)取代 通式烷基乙烯基醚(III)其中R <2> C 1 -C 6 - 烷基或C 3 -C 6 - 环烷基与光气(IVa)中,“双光气”(IVb)的或“三光气”(IVc)的下式的酰氯 (V),b)使由消除氯化氢转化成相应的式3-alkoxyacryloyl(VI)这和c)VII)其中R <1>具有上述这表明(与式肼至5的含义 式(I)的-Hydroxypyrazolen。

    PROCESS FOR PREPARING 1,3-DISUBSTITUTED IMIDAZOLIDINONES
    13.
    发明申请
    PROCESS FOR PREPARING 1,3-DISUBSTITUTED IMIDAZOLIDINONES 审中-公开
    METHOD FOR PRODUCING 1,3-二取代的咪唑啉酮

    公开(公告)号:WO9602516A2

    公开(公告)日:1996-02-01

    申请号:PCT/EP9502806

    申请日:1995-07-18

    CPC classification number: C07D233/32

    Abstract: In order to prepare imidazolidin-2-ones, 1,3-dioxalan-2-one (ethylene carbonate) is reacted with at least one compound having the formula RNH2, in which R may stand among others for H, alkyl, aryl, heteroalkyl or heteroaryl.

    Abstract translation: 咪唑烷-2-酮是由1,3-二氧戊环-2-酮(碳酸亚乙酯)制备与式RNH 2的至少一种化合物,其中R,除其他外,H,烷基,芳基,杂烷基或杂芳基可以是反应。

    UV- CROSSLINKABLE COPOLYMERS
    15.
    发明申请
    UV- CROSSLINKABLE COPOLYMERS 审中-公开
    UV光固化共聚物

    公开(公告)号:WO03070792A8

    公开(公告)日:2003-10-30

    申请号:PCT/EP0301057

    申请日:2003-02-04

    CPC classification number: C08F246/00

    Abstract: The invention relates to the use of aceto or benzophenone derivatives of general formula (I), wherein R represents optionally substituted C1 - C3-alkyl, C6 - C10-aryl or aralkyl having 6 -10 C-atoms in the aryl part and 1 - 6 C-atoms in the alkyl part, as copolymerisable photoinitiators. The invention further relates to copolymers, which contain aceto or benzophenone derivatives of general formula (I) in a polymerised form. The invention also relates to methods for the production of said copolymers and to the use thereof in UV-cross-linkable materials.

    Abstract translation: 本发明提供了通式I其中R是任选取代的C1-C3烷基的苯乙酮或二苯甲酮衍生物的,C6至C10具有在芳基部分碳原子数为6〜10,1〜6个C的芳基或Arlakyl 指作为共聚光引发剂的烷基部分的原子。 此外,下式的苯乙酮或二苯甲酮衍生物我涉及其中本发明的共聚物包含共聚形式,使得这些共聚物的并在UV交联的组合物中使用这些共聚物的方法。

    METHOD FOR PRODUCING O-CHLOROMETHYL BENZOIC ACID CHLORIDES
    16.
    发明申请
    METHOD FOR PRODUCING O-CHLOROMETHYL BENZOIC ACID CHLORIDES 审中-公开
    制备邻氯甲基苯甲酸氯化物的方法

    公开(公告)号:WO0142182A3

    公开(公告)日:2001-12-06

    申请号:PCT/EP0011810

    申请日:2000-11-27

    CPC classification number: C07C51/60 C07C63/04 C07C63/10

    Abstract: The invention relates to a method for producing o-chloromethyl benzoic acid chlorides of formula (I), in which R to R can be the same or different and represent hydrogen C1-C4 alkyl, halogen or trifluoromethyl, by reacting benzo-condensed lactones of formula (II), in which R to R have the above-mentioned meaning, with thionyl chloride. The inventive method is characterized in that the reaction is carried out in the presence of catalytic quantities of a boric acid, boric acid anhydride, borate, boronic acid or boronic acid ester and in the presence of catalytic quantities of a quaternary ammonia salt.

    Abstract translation: 本发明涉及一种用于制备式(I)的邻 - 氯甲基苯甲酰氯,于R的处理<4>可以<1>是相同的或R不同,并代表氢,C1-C4烷基,卤素或三氟甲基,通过使 苯并稠合的式内酯(II),至R <4>具有R <1>如上所定义,与亚硫酰氯,其特征在于gekennzeichet,在催化量的硼酸,的存在下进行反应硼酸酐,硼酸盐,硼酸或Boronsäureester一个和 催化量的季铵盐。

    CATALYST AND METHOD FOR HYDROGENATING ORGANIC COMPOUNDS CONTAINING HYDROGENABLE GROUPS
    17.
    发明申请
    CATALYST AND METHOD FOR HYDROGENATING ORGANIC COMPOUNDS CONTAINING HYDROGENABLE GROUPS 审中-公开
    钌催化剂和氢化方法来说氢化基团含有机物的

    公开(公告)号:WO2006136541A3

    公开(公告)日:2007-04-12

    申请号:PCT/EP2006063323

    申请日:2006-06-20

    CPC classification number: B01J23/462 B01J21/08 B01J35/1019 B01J37/0205

    Abstract: The invention relates to a shell catalyst containing ruthenium as an active metal, alone or together with at least one other metal of the auxiliary group IB, VIIB or VIII of the periodical system of the elements (CAS version), and applied to a carrier containing silicon dioxide as a carrier material. The invention also relates to a method for producing said shell catalyst, and to a method for hydrogenating an organic compound containing hydrogenable groups, preferably for hydrogenating a carbocyclic aromatic group to form the corresponding carbocyclic aliphatic groups or for hydrogenating aldehydes to form the corresponding alcohols, using the inventive shell catalyst. The invention further relates to the use of the inventive shell catalyst for hydrogenating an organic compound containing hydrogenable groups, preferably for hydrogenating a carbocyclic aromatic group to form the corresponding carbocyclic aliphatic groups or for hydrogenating aldehydes to form the corresponding alcohols.

    Abstract translation: 本发明涉及一种含有壳催化剂作为活性金属钌单独或与过渡族IB,VIIB中的至少一种另外的金属或元素(CAS版本)的周期表第VIII一起施加到载体包括二氧化硅作为载体材料,用于制造这种壳催化剂的方法 含有氢化的有机化合物,可氢化基团,优选为碳环芳族基团的氢化成相应的碳环脂族基团或用于根据本发明和根据本发明的用于氢化的使用涂层催化剂的醛氢化成相应的醇,该涂层催化剂的Verwendüng下的处理 含有氢化的基团,优选为碳环基团aromatichen的氢化成相应的碳环脂族基团或氢化的有机化合物 醛为相应的醇的UNG。

    METHOD FOR PRODUCING 1-SUBSTITUTED 5- OR 3-HYDROXYPYRAZOLES
    19.
    发明申请
    METHOD FOR PRODUCING 1-SUBSTITUTED 5- OR 3-HYDROXYPYRAZOLES 审中-公开
    制备1-取代的5-或3-羟基吡唑的方法

    公开(公告)号:WO0031042A3

    公开(公告)日:2000-10-26

    申请号:PCT/EP9908516

    申请日:1999-11-06

    CPC classification number: C07D231/20

    Abstract: The invention relates to a method for producing 1-substituted 5- and/or 3-hydroxypyrazoles of formulas (I) and (II), wherein R represents C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkinyl, C3-C6-cycloalkyl or C1-C4-alkoxy, whereby these groups can be substituted by halogen, C1-C4-alkoxy, phenoxy, C1-C6-alkoxycarbonyl, C1-C6-alkylthiocarbonyl or a cyclic ring system with 3-14 ring atoms, by reacting a 3-alkoxyacrylic acid alkyl ester of formula (III), wherein R , R independently mean C1-C6-alkyl or C3-C6-cycloalky, with a hydrazine of formula (IV), wherein R has the above cited meaning, a) at a pH value of 6-11 to form 5-hydroxypyrazoles of formula (I), or b) at a pH value of 11-14 to form 3-hydroxypyrazoles of formula (II).

    Abstract translation: 本发明涉及一种制备1-取代的5和/或所述式(I)和(II),其中R <1> C1-C6-烷基,C2-C6链烯基,C2-C6的3-羟基吡 炔基,C3-C6环烷基或C1-C4烷氧基,其中这些基团被卤素,C1-C4烷氧基,苯氧基,C1-C6烷氧羰基,C1-C6烷硫基羰基或具有3-14个环原子的环系 可以由式(III)的烷基3- alkoxyacrylates被取代,其中R <2>,R <3>独立地是C1-C6烷基或C3-C6环烷基与式的肼(Ⅳ) 其中R <1>具有上面给出的含义,a)在pH值下式I)的6-11(约5-羟基吡唑反应而,或b)在pH为11-14,得到3- hydroxypyrazoles 的式(II)。

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