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公开(公告)号:DE3680812D1
公开(公告)日:1991-09-19
申请号:DE3680812
申请日:1986-04-22
Applicant: BASF AG
Inventor: GROSSKINSKY OTTO-ALFRED , HERRMANN GUENTER , LOEFFLER ULRICH , SCHNABEL ROLF , STUETZER DIETER
IPC: C07C27/12 , B01F1/00 , B01F3/04 , C01B13/00 , C07C27/00 , C07C35/08 , C07C45/00 , C07C49/403 , C07C67/00
Abstract: Solns. (I) of mol. O2 (II) in liq. hydrocarbons (III) are produced by contacting (III) with (II) under elevated pressure in a vertical absorption zone. The novel features are as follows: (a) there is a water layer (IV) at the lower end of the absorption zone; (b) (II) is passed into (IV); (c) (III) is supplied above (IV); (d) the finely-divided (II) rising from (IV) and (III) are passed upwards at 0-50 deg.C, with thorough mixing in the absorption zone, so that no coherent gas phase develops; and (e) (I) is discharged at the top of the absorption zone. (I) is recirculated in an amt. of 2-50 times the amt. of (III) supplied. The mixt. of (III) and (II) is passed through narrow points in the absorption zone. Absorption is carried out at 10-100 bar, depending on the amt. of (IV). A small amt. of liquid is removed at the top of the absorption zone. (IV) contains salts and surfactants.
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公开(公告)号:CA831399A
公开(公告)日:1970-01-06
申请号:CA831399D
Applicant: BASF AG
Inventor: NAGEL OTTO , HORNBERGER PAUL , SINN RICHARD , SCHEURING HUBERTUS , HERRMANN GUENTER
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公开(公告)号:DE59307513D1
公开(公告)日:1997-11-13
申请号:DE59307513
申请日:1993-07-17
Applicant: BASF AG
Inventor: FETZER THOMAS , BUECHELE WOLFGANG , WISTUBA HERMANN , OTTO BERNHARD , BUERGER GERT , HERRMANN GUENTER
Abstract: The invention concerns an aluminium oxide catalyst containing silver, the catalyst containing in addition copper oxide and, optionally, other promoters and active components. This catalyst is used to decompose pure nitrous oxide (N2O) or nitrous oxide in gas mixtures at elevated temperatures, and exhibits high activity.
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公开(公告)号:NO300918B1
公开(公告)日:1997-08-18
申请号:NO940653
申请日:1994-02-25
Applicant: BASF AG
Inventor: FETZER THOMAS , BUECHELE WOLFGANG , WISTUBA HERMANN , WITTE CLAUS , BUERGER GERT , HERRMANN GUENTER
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15.
公开(公告)号:CZ34494A3
公开(公告)日:1994-12-15
申请号:CS3449492
申请日:1992-08-20
Applicant: BASF AG
Inventor: FETZER THOMAS , BUECHELE WOLFGANG , WISTUBA HERMANN , WITTE CLAUS , BUERGER GERT , HERRMANN GUENTER
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16.
公开(公告)号:SK23194A3
公开(公告)日:1994-11-09
申请号:SK23194
申请日:1992-08-20
Applicant: BASF AG
Inventor: FETZER THOMAS , BUECHELE WOLFGANG , WISTUBA HERMAN , WITTE CLAUS , BUERGER GERT , HERRMANN GUENTER
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公开(公告)号:LT2267B
公开(公告)日:1993-12-15
申请号:LTRP774
申请日:1993-07-09
Applicant: BASF AG
Inventor: BRUNNER ERWIN , GROSSKINSKY OTTO-ALFRED , HERRMANN GUENTER , KROKOSZINSKI ROLAND , MAGNUSSEN PETER
IPC: C07C407/00 , C07C409/00
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公开(公告)号:NO913606A
公开(公告)日:1992-03-16
申请号:NO913606
申请日:1991-09-12
Applicant: BASF AG
Inventor: AICHINGER HEINRICH , BOEHNING KARL-HEINZ , HERZOG KLAUS , WISTUBA HERMANN , BUERGER GERT , SCHWARZMANN MATTHIAS , HERRMANN GUENTER
CPC classification number: B01D53/8628 , B01D2255/104 , B01D2255/9207 , B01D2257/402 , B01J23/50 , B01J35/1014 , Y02C20/10
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公开(公告)号:FI914316A0
公开(公告)日:1991-09-13
申请号:FI914316
申请日:1991-09-13
Applicant: BASF AG
Inventor: AICHINGER HEINRICH , BOEHNING KARL-HEINZ , HERZOG KLAUS , WISTUBA HERMANN , BUERGER GERT , SCHWARZMANN MATTHIAS , HERRMANN GUENTER
Abstract: In a catalyst for the decomposition of nitrous oxide, pure or in gaseous mixtures, metallic silver is applied to an alumina support having a BET surface area of 5 to 25 m /g.
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20.
公开(公告)号:CA1262359A
公开(公告)日:1989-10-17
申请号:CA473196
申请日:1985-01-30
Applicant: BASF AG
Inventor: BRUNNER ERWIN , GROSSKINSKY OTTO-ALFRED , HERRMANN GUENTER , KROKOSZINSKI ROLAND , MAGNUSSEN PETER
IPC: C07C27/12 , C07C27/00 , C07C29/50 , C07C35/08 , C07C45/00 , C07C45/33 , C07C49/403 , C07C67/00 , C07C407/00 , C07C409/06 , C07C409/14 , C07C49/603 , C07C179/03
Abstract: Mixtures containing cyclohexyl hydroperoxide, cyclohexanol and cyclohexanone and having a high cyclohexyl hydroperoxide content are prepared by a continuous process which comprises the oxidation of cyclohexane with molecular oxygen, or with a gas containing this, in the liquid phase, in which 1. in a first stage, molecular oxygen is dissolved in cyclohexane by bringing the latter into contact with molecular oxygen, or with a gas containing this, at from 10 to 110.degree.C and under superatmospheric pressure, and 2. in a second stage, the cyclohexane containing dis solved molecular oxygen is passed through an elongated, tubular reaction zone at from 130 to 250.degree.C and under superatmospheric pressure, virtually with plug flow and without the formation of a gas phase, the residence time being between a) the time required for the consumption of 50% of the amount of dissolved molecular oxygen and b) 1.2 times the time required for the consumption of 99.9% of the dissolved molecular oxygen.
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