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公开(公告)号：JP2001114711A
公开(公告)日：2001-04-24
申请号：JP2000307760
申请日：2000-10-06
Applicant: BASF AG
Inventor： KRATZ DETLEF DR , RUST HARALD , KROKOSZINSKI ROLAND , HELF VOLKER
IPC: C07C29/141 , C07C29/16 , C07C31/20 , C07C45/50 , C07C45/72
Abstract: PROBLEM TO BE SOLVED: To provide a method for easily and economically producing an 1,3-diol. SOLUTION: This method comprises the following steps: (a) at least one kind of >=3C alkanal is prepared, (b) the alkanal is heat-treated in the absence of a basic catalyst, (c) the resultant aldol addition product is hydrogenated, and (d) the objective 1,3-diol thus produced is collected. This 1,3-diol has >=6 carbon atoms in the molecule.
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公开(公告)号：JPS62120351A
公开(公告)日：1987-06-01
申请号：JP23639186
申请日：1986-10-06
Applicant: BASF AG
Inventor： ENGELBACH HEINZ , KROKOSZINSKI ROLAND , FRANZISCHKA WOLFGANG , DECKER MARTIN
IPC: C07B61/00 , B01J23/22 , C07C67/00 , C07C253/00 , C07C253/28 , C07C255/50 , C07C255/51
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公开(公告)号：WO0158844A3
公开(公告)日：2002-04-04
申请号：PCT/EP0101582
申请日：2001-02-13
Applicant: BASF AG , WALCZUCH KARL HEINZ , MUELLER ROLF , KROKOSZINSKI ROLAND , GEISSLER BERNHARD
Inventor： WALCZUCH KARL-HEINZ , MUELLER ROLF , KROKOSZINSKI ROLAND , GEISSLER BERNHARD
Abstract: The invention relates to a method for processing a liquid discharge of a continuous hydroformylation that substantially contains aldehydes, high-boiling by-products, a homogeneously dissolved hydroformylation catalyst, non-reacted olefins, low-boiling by-products and dissolved synthesis gases. According to the inventive method a) the liquid hydroformylation discharge is expanded in a first expansion step to a pressure that is 2 to 20 bar below the reactor pressure, while the discharge is separated into a liquid phase and a gaseous phase; and b) expanding the liquid phase obtained in the first expansion step in a second expansion step to a pressure that is lower than the pressure of the first expansion step, while the liquid phase is separated into a liquid phase that substantially contains the high-boiling by-products of the hydroformylation, the homogeneously dissolved hydroformylation catalyst and small quantities of hydroformylation product and non-reacted olefins, and into a gaseous phase that substantially contains the main quantity of the hydroformylation product, non-reacted olefins and low-boiling by-products.
Abstract translation: 本发明涉及一种用于后处理的液体的处理Austrages的连续加氢甲酰化基本上醛，高沸点的副产物，一均匀溶解加氢甲酰化催化剂，未反应的烯烃，低沸点副产物，并溶解合成气含有，其特征在于，a）在第一减压阶段的液体加氢甲酰化以 被释放的压力，其为2至20巴反应器压力的下方，其特征在于，分离成液相和气相; 和b）在第一减压步骤中获得的液相在第二减压阶段的压力比所述第一膨胀阶段的压力下，其中，分离成液相基本上是高沸点的副产物的加氢甲酰化的，均匀溶解的加氢甲酰化催化剂进行减压 和少量的加氢甲酰化产物和未反应的烯烃的，并包含在气相，其基本上包含加氢甲酰化产物，未反应的烯烃和低沸点副产物的主要量。
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4.发明专利
公开(公告)号：ES2233678T3
公开(公告)日：2005-06-16
申请号：ES01967331
申请日：2001-09-11
Applicant: BASF AG
Inventor： ROPER MICHAEL , BLANKERTZ HEINRICH-JOSEF , GRENACHER ARMIN VOLKER , KROKOSZINSKI ROLAND , SCHONMANN WILLI
Abstract: Procedimiento para el hidroformilado continuo de polialquilenos, esencialmente monoinsaturados, con 30 a 700 átomos de carbono, en el que i) se obtiene un catalizador de carbonilo de cobalto con actividad de hidroformilado en ausencia de polialquilenos, a partir de un precursor de catalizador disuelto en una fase acuosa, ii) se hidroformilan los polialquilenos en una zona de reacción en presencia del catalizador de carbonilo de cobalto con gas de síntesis, iii) a partir de la descarga de la zona de reacción se separa el catalizador de carbonilo de cobalto bajo recuperación, al menos parcial, del precursor de catalizador, y se devuelve al precursor de catalizador en el paso i).
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公开(公告)号：AT260232T
公开(公告)日：2004-03-15
申请号：AT01945319
申请日：2001-06-27
Applicant: BASF AG
Inventor： KROKOSZINSKI ROLAND , HAMMON ULRICH , TODD KEVIN
IPC: C07C27/14 , C07B61/00 , C07C45/33 , C07C45/35 , C07C45/50 , C07C47/02 , C07C47/22 , C07C51/215 , C07C51/235 , C07C51/25 , C07C57/05 , C07C57/055
Abstract: A process for preparing hydroformylation products of propylene and for preparing acrylic acid and/or acrolein comprises a) feeding a propylene-containing feed in which from 2 to 40% by weight of propane is present and also carbon monoxide and hydrogen into a reaction zone and reacting this mixture in the presence of a hydroformylation catalyst to form hydroformylation products of propane, b) separating a stream consisting essentially of unreacted propylene and propane from the output from the reaction zone, and c) subjecting the stream consisting essentially of propylene and propane to a catalytic gas-phase oxidation in the presence of molecular oxygen to form acrylic acid and/or acrolein.
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Patent Agency Ranking
公开(公告)号：AT249411T
公开(公告)日：2003-09-15
申请号：AT01911637
申请日：2001-02-13
Applicant: BASF AG
Inventor： WALCZUCH KARL-HEINZ , MUELLER ROLF , KROKOSZINSKI ROLAND , GEISSLER BERNHARD
Abstract: A liquid output from a continuous hydroformylation, which comprises essentially aldehydes, high-boiling by-products, a homogeneously dissolved hydroformylation catalyst, unreacted olefins, low-boiling by-products and dissolved synthesis gas, is worked up by a process in which a) the liquid hydroformylation output is depressurized in a first depressurization stage to a pressure which is from 2 to 20 bar below the reactor pressure, resulting in separation into a liquid phase and a gas phase, and b) the liquid phase obtained in the first depressurization stage is depressurized in a second depressurization stage to a pressure which is lower than the pressure of the first depressurization stage, resulting in separation into a liquid phase comprising essentially high-boiling by-products of the hydroformylation, the homogeneously dissolved hydroformylation catalyst and small amounts of hydroformylation product and unreacted olefin and a gas phase comprising essentially the major part of the hydroformylation product, unreacted olefin and low-boiling by-products.
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公开(公告)号：BR0111821A
公开(公告)日：2003-06-17
申请号：BR0111821
申请日：2001-06-27
Applicant: BASF AG
Inventor： KROKOSZINSKI ROLAND , HAMMON ULRICH , TODD KEVIN
IPC: C07C27/14 , C07B61/00 , C07C45/33 , C07C45/35 , C07C45/50 , C07C47/02 , C07C47/22 , C07C51/215 , C07C51/235 , C07C51/25 , C07C57/05 , C07C57/055
Abstract: A process for preparing hydroformylation products of propylene and for preparing acrylic acid and/or acrolein comprises a) feeding a propylene-containing feed in which from 2 to 40% by weight of propane is present and also carbon monoxide and hydrogen into a reaction zone and reacting this mixture in the presence of a hydroformylation catalyst to form hydroformylation products of propane, b) separating a stream consisting essentially of unreacted propylene and propane from the output from the reaction zone, and c) subjecting the stream consisting essentially of propylene and propane to a catalytic gas-phase oxidation in the presence of molecular oxygen to form acrylic acid and/or acrolein.
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公开(公告)号：AU4061601A
公开(公告)日：2001-08-20
申请号：AU4061601
申请日：2001-02-13
Applicant: BASF AG
Inventor： WALCZUCH KARL-HEINZ , MULLER ROLF , KROKOSZINSKI ROLAND , GEISSLER BERNHARD
Abstract: A liquid output from a continuous hydroformylation, which comprises essentially aldehydes, high-boiling by-products, a homogeneously dissolved hydroformylation catalyst, unreacted olefins, low-boiling by-products and dissolved synthesis gas, is worked up by a process in which a) the liquid hydroformylation output is depressurized in a first depressurization stage to a pressure which is from 2 to 20 bar below the reactor pressure, resulting in separation into a liquid phase and a gas phase, and b) the liquid phase obtained in the first depressurization stage is depressurized in a second depressurization stage to a pressure which is lower than the pressure of the first depressurization stage, resulting in separation into a liquid phase comprising essentially high-boiling by-products of the hydroformylation, the homogeneously dissolved hydroformylation catalyst and small amounts of hydroformylation product and unreacted olefin and a gas phase comprising essentially the major part of the hydroformylation product, unreacted olefin and low-boiling by-products.
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公开(公告)号：DE50109009D1
公开(公告)日：2006-04-27
申请号：DE50109009
申请日：2001-06-27
Applicant: BASF AG
Inventor： WALZ HELMUT , SCHOENMANN WILLI , MUELLER ROLF , KROKOSZINSKI ROLAND
Abstract: Olefins having from 2 to 8 carbon atoms are hydroformylated in a process in which (i) an olefin-containing feed in which a proportion of a saturated hydrocarbon having from 2 to 8 carbon atoms is present and also carbon monoxide and hydrogen are fed into a reaction zone and reacted in the presence of a hydroformylation catalyst, (ii) a stream consisting essentially of unreacted olefin and saturated hydrocarbon is separated off from the output from the reaction zone, (iii) the stream is separated into an olefin-enriched fraction and an olefin-depleted fraction by rectification, and (iv) at least part of the olefin-enriched fraction is recirculated to the reaction zone.
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公开(公告)号：DE50104707D1
公开(公告)日：2005-01-05
申请号：DE50104707
申请日：2001-09-11
Applicant: BASF AG
Inventor： ROEPER MICHAEL , BLANKERTZ HEINRICH-JOSEF , GRENACHER VOLKER , KROKOSZINSKI ROLAND , SCHOENMANN WILLI
Abstract: Essentially monounsaturated polyalkylenes having from 30 to 700 carbon atoms are continuously hydroformylated by a process in which i) a hydroformylation-active cobalt carbonyl catalyst is prepared from a catalyst precursor dissolved in an aqueous phase in the absence of the polyalkylenes, ii) the polyalkylenes are hydroformylated by means of synthesis gas in the presence of the cobalt carbonyl catalyst in a reaction zone, iii) the cobalt carbonyl catalyst is separated from the output from the reaction zone with at least partial reformation of the catalyst precursor and the catalyst precursor is recirculated to step i).
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