14.
    发明专利
    未知

    公开(公告)号:DE2529433A1

    公开(公告)日:1977-01-20

    申请号:DE2529433

    申请日:1975-07-02

    Applicant: BASF AG

    Abstract: Toluene-soluble copolymers (I) are prepd. from (A) 70-97 mol. % 8-12C vinyl aromatic hydrocarbons, (B) 3-20 mol. % semi-esters of maleic acid with 1-6C aliphatic or cycloaliphatic alkanols or oxa-alkanols and (C) 0-10 mol. % other ethylenically unsatd. monomers. (I) have no. av. mol. wt. 200-10000 and a Kramer-Sarnow-Nagel softening point 100-220 degrees C. (I) are used as binders for intaglio printing inks. (I) have good pigment-wetting properties; can be blended with standard commercial binders; are odourless and colourless. Pref. prepn. of (I) comprises addn. of at least 30% (B) in course of suspension polymerisation of (A), 0-70% (B) and opt. (C), at 50-100 degrees C. In an example, a toluene-soluble odourless, resinate-miscible copolymer was prepd. 140 parts mono-isobutyl maleate were added in 2 hrs. to aq. suspension, after start of polymerisation of 560 parts styrene, at 80 degrees C.

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