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公开(公告)号:DE3130766A1
公开(公告)日:1983-02-24
申请号:DE3130766
申请日:1981-08-04
Applicant: BASF AG
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公开(公告)号:DE3107450A1
公开(公告)日:1982-10-21
申请号:DE3107450
申请日:1981-02-27
Applicant: BASF AG
Inventor: HOENE RICHARD DIPL CHEM DR , DEMMLER KURT DIPL CHEM DR
Abstract: The invention relates to unsaturated polyesters containing oligomers of cyclopentadiene as terminal groups. More than 20% of the cyclopentadiene oligomers have a degree of polymerisation of >/= 3. The unsaturated polyesters can be used in the form of their solutions in ethylenically unsaturated monomers for the production of mouldings and coatings.
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公开(公告)号:DE2657808A1
公开(公告)日:1978-06-29
申请号:DE2657808
申请日:1976-12-21
Applicant: BASF AG
Inventor: HOENE RICHARD DIPL CHEM DR , HESSE ANTON DIPL CHEM DR , DEMMLER KURT DIPL CHEM DR , LAWONN HORST ING GRAD
IPC: C08L51/08 , C08L67/06 , C08F283/00
Abstract: Unsaturated polyester molding compositions which contain ethylenically unsaturated polyesters, copolymerizable ethylenically unsaturated monomeric compounds and a polyalkylene ether copolymer have improved shelf life, can be cured with little shrinkage and after curing give a smooth surface with high gloss.
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公开(公告)号:DE2529433A1
公开(公告)日:1977-01-20
申请号:DE2529433
申请日:1975-07-02
Applicant: BASF AG
Inventor: HASSELMEYER GUENTER DIPL CHEM , BANKOWSKY HEINZ-HILMAR ING GRA , HOENE RICHARD DIPL CHEM DR
IPC: C08F212/06 , C09D11/106 , C08F212/04
Abstract: Toluene-soluble copolymers (I) are prepd. from (A) 70-97 mol. % 8-12C vinyl aromatic hydrocarbons, (B) 3-20 mol. % semi-esters of maleic acid with 1-6C aliphatic or cycloaliphatic alkanols or oxa-alkanols and (C) 0-10 mol. % other ethylenically unsatd. monomers. (I) have no. av. mol. wt. 200-10000 and a Kramer-Sarnow-Nagel softening point 100-220 degrees C. (I) are used as binders for intaglio printing inks. (I) have good pigment-wetting properties; can be blended with standard commercial binders; are odourless and colourless. Pref. prepn. of (I) comprises addn. of at least 30% (B) in course of suspension polymerisation of (A), 0-70% (B) and opt. (C), at 50-100 degrees C. In an example, a toluene-soluble odourless, resinate-miscible copolymer was prepd. 140 parts mono-isobutyl maleate were added in 2 hrs. to aq. suspension, after start of polymerisation of 560 parts styrene, at 80 degrees C.
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