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公开(公告)号：DE59205457D1
公开(公告)日：1996-04-04
申请号：DE59205457
申请日：1992-08-29
Applicant: BASF AG
Inventor： KERSTING MEINOLF , HUNGENBERG KLAUS-DIETER , KOELLE PETER
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公开(公告)号：AU1361295A
公开(公告)日：1995-09-14
申请号：AU1361295
申请日：1995-03-02
Applicant: BASF AG
Inventor： ZOLK RALF , WERNER RAINER ALEXANDER , KERSTING MEINOLF
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公开(公告)号：ZA9206923B
公开(公告)日：1994-03-11
申请号：ZA9206923
申请日：1992-09-11
Applicant: BASF AG
Inventor： KERSTING MEINOLF , KERTH JUERGEN , HUNGERBERG KLAUS-DIETER , KOELLE PETER
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公开(公告)号：AT200785T
公开(公告)日：2001-05-15
申请号：AT97929194
申请日：1997-06-17
Applicant: BASF AG
Inventor： BIDELL WOLFGANG , LANGHAUSER FRANZ , MOLL ULRICH , MC KENZIE IAN DAVID , FISCHER DAVID , HINGMANN ROLAND , SCHWEIER GUENTHER , MARCZINKE BERND LOTHAR , KERSTING MEINOLF , JONES PETER JOHN VAUGHAN , GRASMEDER JOHN RUSSELL
IPC: C08F4/642 , C08F4/16 , C08F4/602 , C08F4/619 , C08F4/6192 , C08F10/00 , C08F110/06
Abstract: A process for preparing a supported transition metal catalyst comprising a particulate organic or inorganic support material, a transition metal complex and a compound capable of forming metallocenium ions comprises the following process steps:a) contacting a solution of a compound capable of forming metallocenium ions with a second solvent in which this compound is only sparingly soluble, in the presence of the support material,b) removing at least part of the solvent from the support material andc) contacting a solution of a mixture of a compound capable of forming metallocenium ions and a transition metal complex with a second solvent in which this mixture is only sparingly soluble, in the presence of the support material obtained as described in a) and b).
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公开(公告)号：ES2117673T3
公开(公告)日：1998-08-16
申请号：ES92918310
申请日：1992-09-02
Applicant: BASF AG
Inventor： SCHLUND RUEGER , KERSTING MEINOLF , HUNGENBERG KLAUS-DIETER
IPC: C08F4/648 , C08F2/40 , C08F4/60 , C08F4/602 , C08F4/609 , C08F4/63 , C08F4/639 , C08F4/6392 , C08F4/65 , C08F4/6592 , C08F4/68 , C08F10/00
Abstract: PCT No. PCT/EP92/02016 Sec. 371 Date Mar. 8, 1994 Sec. 102(e) Date Mar. 8, 1994 PCT Filed Sep. 2, 1992 PCT Pub. No. WO93/05079 PCT Pub. Date Mar. 18, 1993.Metallocene catalyst systems for the polymerization of C2-C10-alkenes are obtainable by deactivation of a preactivated metallocene catalyst system which contains, as active components, a metallocene complex of a metal of subgroup IV or V of the Periodic Table and an oligomeric alumoxane compound and, if required, subsequent reactivation.
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Patent Agency Ranking
公开(公告)号：DE59209397D1
公开(公告)日：1998-08-06
申请号：DE59209397
申请日：1992-09-02
Applicant: BASF AG
Inventor： SCHLUND RUEGER , KERSTING MEINOLF , HUNGENBERG KLAUS-DIETER
IPC: C08F4/648 , C08F2/40 , C08F4/60 , C08F4/602 , C08F4/609 , C08F4/63 , C08F4/639 , C08F4/6392 , C08F4/65 , C08F4/6592 , C08F4/68 , C08F10/00
Abstract: PCT No. PCT/EP92/02016 Sec. 371 Date Mar. 8, 1994 Sec. 102(e) Date Mar. 8, 1994 PCT Filed Sep. 2, 1992 PCT Pub. No. WO93/05079 PCT Pub. Date Mar. 18, 1993.Metallocene catalyst systems for the polymerization of C2-C10-alkenes are obtainable by deactivation of a preactivated metallocene catalyst system which contains, as active components, a metallocene complex of a metal of subgroup IV or V of the Periodic Table and an oligomeric alumoxane compound and, if required, subsequent reactivation.
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公开(公告)号：DE19653079A1
公开(公告)日：1998-06-25
申请号：DE19653079
申请日：1996-12-19
Applicant: BASF AG
Inventor： KERSTING MEINOLF , WERNER RAINER ALEXANDER , LANGHAUSER FRANZ , LUTZ GERALD
IPC: B01J8/00 , B01J8/10 , B01J8/24 , C08F4/64 , B01J19/18 , C08F2/34 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/06 , C08F210/06 , C08F255/02
Abstract: Gas phase homo- or copolymerisation of 2-8C alk-1-enes with a Ziegler-Natta or metallocene catalyst system is carried out in a stirred bed of finely-divided polymer, with addition of the catalyst solid (I) containing transition metal with the alkene. The novelty is that (I) is introduced into the reactor with (part of) the alkene through (almost) vertical pipe(s) projecting down into the gas space and ending above the stirred powder bed. Also claimed is the apparatus used. Preferably the vertical distance between the pipe(s) and the surface of the bed is
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公开(公告)号：ZA9610223B
公开(公告)日：1998-06-05
申请号：ZA9610223
申请日：1996-12-05
Applicant: BASF AG
Inventor： HUEFFER STEPHAN , KERSTING MEINOLF , LANGHAUSER FRANZ , WERNER RAINER ALEXANDER , MUELLER PATRIK , KERTH JUERGEN
IPC: C08F4/658 , C08F4/02 , C08F4/64 , C08F4/654 , C08F210/06 , C08F210/16 , D01F6/06 , C08F , C08L , D01F
Abstract: Statistical propylene copolymers with 2-10C alk-1-ene comonomer (alkene) units are claimed, obtained by polymerisation of propylene and alkene at 50-100 degrees C and 15-40 bar with a mean residence time of 0.5-5 hrs., in presence of a Ziegler-Natta catalyst with: (a) a titanium-containing solid component containing a magnesium compound, a halogen, a silica gel support and a carboxylate ester as electron donor; plus (b) an aluminium compound; and (c) another electron donor as cocatalysts. The silica gel support has an average particle diameter of 5-200 mu m and an average primary particle diameter of 1-10 mu m, and contains 5-20 vol% of pores or channels with an average diameter of 1-10 mu m. Also claimed is a process for the production of propylene copolymers.
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